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1.发明授权Production of nitriles via hydrocyanation of ethylenically unsaturated organic compounds 失效通过烯属不饱和有机化合物的氢氰化生产腈公开(公告)号：US06469194B2
公开(公告)日：2002-10-22
申请号：US09886288
申请日：2001-06-22
申请人： Paolo Burattin , Pierre Coqueret , Marc Huser
发明人： Paolo Burattin , Pierre Coqueret , Marc Huser
IPC分类号： C07C25300
CPC分类号： B01J31/2404 , B01J31/24 , B01J31/403 , B01J31/4053 , B01J2231/343 , B01J2231/52 , B01J2531/847 , B01J2531/96 , C07C253/10 , C07C253/30 , Y02P20/584 , C07C255/07
摘要： Ethylenically unsaturated organic compounds, for example diolefins, olefinic nitriles and monoolefins, are noncontaminatingly hydrocyanated into corresponding nitriles by (a) reacting such ethylenically unsaturated organic compounds with hydrogen cyanide in the presence of an aqueous solution containing a catalytically effective amount of a catalyst which comprises at least one nickel compound and at least one water-soluble phosphine, (b) thereafter separating the organic phase from the aqueous phase which result, the separated aqueous phase comprising a solid phase formed during hydrocyanation, and (c) thence treating the separated aqueous phase, or a solid phase removed therefrom, with hydrogen cyanide to thus at least partially dissolve said solid phase contained therein or removed therefrom.
摘要翻译： 烯键式不饱和有机化合物，例如二烯烃，烯属腈和单烯烃，通过（a）在含有催化有效量的催化剂的水溶液存在下，使这种烯属不饱和有机化合物与氰化氢反应，将其非氰化氢氰化成相应的腈， 至少一种镍化合物和至少一种水溶性膦，（b）此后从水相中分离出有机相，导致分离的水相包括在氢氰化期间形成的固相，和（c）然后处理分离的水溶液 相或其中除去的固相，与氰化氢反应，从而至少部分溶解其中所含的固相或从其中除去。
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2.发明授权公开(公告)号：US07105696B2
公开(公告)日：2006-09-12
申请号：US10250477
申请日：2001-12-21
IPC分类号： C07C253/00
CPC分类号： C07C253/10 , C07C255/04
摘要： The invention concerns a method for hydrocyanation of ethylenically unsaturated organic compounds comprising at least a nitrile function. The invention provides a method for hydrocyanation of an ethylenically unsaturated hydrocarbon compound by reacting in liquid medium the hydrogen cyanide in the presence of a catalyst comprising a metal element selected among transition metals and an organophosphorous ligand, characterised in that the organophosphorous ligand is a furylphosphine. The invention is in particular useful for synthesizing adiponitrile from butadiene.
摘要翻译： 本发明涉及一种含有至少一个腈官能团的烯属不饱和有机化合物的氢氰化方法。 本发明提供了一种通过在液体介质中在含有选自过渡金属和有机磷配体的金属元素的催化剂存在下，使氰化氢反应的方法，其特征在于有机磷配体是呋喃基膦。 本发明特别适用于从丁二烯合成己二腈。
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公开(公告)号：US06884751B2
公开(公告)日：2005-04-26
申请号：US09886289
申请日：2001-06-22
申请人： Paolo Burattin , Pierre Coqueret , Marc Huser
发明人： Paolo Burattin , Pierre Coqueret , Marc Huser
IPC分类号： B01J31/28 , B01J23/755 , B01J27/26 , B01J31/24 , B01J37/00 , B01J37/04 , B01J37/16 , B01J37/24 , C07B61/00 , C07C253/08 , C07C253/10 , C07C255/01 , B01J31/00 , B01J27/189
CPC分类号： B01J31/2404 , B01J27/26 , B01J37/16 , B01J2531/847 , B01J2540/32
摘要： Hydrocyanation catalysts comprising aqueous solutions of at least one water-soluble phosphine and nickel values, well suited for the hydrocyanation of ethylenically unsaturated organic compounds such as diolefins, olefinic nitrites and monolefins, are produced by (a) admixing an aqueous solution of such at least one water-soluble phosphine with a nickel hydroxide, (b) adding hydrogen cyanide or a compound which generates hydrogen cyanide to the mixture thus formed, (c) stirring the resulting mixture until the nickel values have at least partially dissolved, and (d) reducing at least a portion of said nickel values having an oxidation state of greater than zero to the zero oxidation state.
摘要翻译： 包含至少一种水溶性膦和镍值的水溶液的氢氰化催化剂通过以下方法制备：（a）将至少一种水溶液至少混合到水溶液中，所述水溶液非常适合于烯属不饱和有机化合物如二烯烃，烯属亚硝酸盐和单烯烃的氢化， 一种与氢氧化镍的水溶性膦，（b）向如此形成的混合物中加入氰化氢或产生氰化氢的化合物，（c）搅拌所得混合物直到镍值至少部分溶解，和（d） 将至少一部分具有大于零的氧化态的所述镍值还原为零氧化态。
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4.发明授权Vanadium/antimony/titanium mixed oxide and process of use in vapor phase ammoxidation of an alkane 失效钒/锑/钛混合氧化物及其在烷烃气相氨氧化中的应用
公开(公告)号：US6072070A
公开(公告)日：2000-06-06
申请号：US848484
申请日：1997-05-08
IPC分类号： B01J23/00 , B01J23/18 , B01J23/22 , B01J37/03 , B01J37/08 , C01G31/00 , C07B61/00 , C07C253/24 , C07C255/08 , C07F9/90 , B01J23/14 , B01J23/16 , C07C253/26
CPC分类号： C01G31/006 , B01J23/002 , B01J23/18 , B01J23/22 , C07C253/24 , B01J2523/00 , B01J37/033 , C01P2002/72 , Y02P20/52
摘要： Mixed oxide vanadium/antimony/titanium ammoxidation catalysts, particularly suited for the ammoxidation of alkanes and exhibiting X-ray diffraction spectra which are characteristic of a crystallographic phase of rutile TiO.sub.2, are prepared by (a) dissolving respective soluble compounds of vanadium, of antimony and of titanium in at least one saturated alcohol, (b) contacting the alcoholic solution thus obtained with water and precipitating the mixed oxide therefrom, and (c) separating and calcining the mixed oxide thus precipitated.
摘要翻译： 通过（a）溶解各种可溶性钒化合物锑，制备特别适用于烷烃氨氧化和表现出金红石TiO 2结晶相特征的X射线衍射光谱的混合氧化钒/锑/钛氨氧化催化剂 和至少一种饱和醇中的钛，（b）使所得到的醇溶液与水接触并使其混合氧化物沉淀，（c）分离和煅烧所沉淀的混合氧化物。
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公开(公告)号：US06492525B1
公开(公告)日：2002-12-10
申请号：US09700768
申请日：2001-06-21
申请人： Guy Bertrand , Lutz Stelzig , Olivier Guerret , Christophe Buron , Heinz Gornitzka , Paolo Burattin
发明人： Guy Bertrand , Lutz Stelzig , Olivier Guerret , Christophe Buron , Heinz Gornitzka , Paolo Burattin
IPC分类号： C07F1900
CPC分类号： C07F15/045 , C07C45/50 , C07F1/005 , C07F3/003 , C07F15/0066 , C07F15/008 , C07C47/228
摘要： The invention concerns novel organometallic complexes comprising cationic heterocyclic carbenes. It also concerns a method for preparing said complexes from dicationic heterocyclic precursor compounds. It further concerns the use as catalysts of said organometallic complexes for a certain number of chemical reactions.
摘要翻译： 本发明涉及包含阳离子杂环卡宾的新型有机金属络合物。 它还涉及从双折化杂环前体化合物制备所述络合物的方法。 它还涉及作为所述有机金属配合物的催化剂用于一定数量的化学反应。
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公开(公告)号：US06417375B1
公开(公告)日：2002-07-09
申请号：US09700750
申请日：2001-04-13
IPC分类号： C07F928
CPC分类号： C07F15/008 , C07C45/50 , C07C231/14 , C07C253/30 , C07F9/65515 , C07C47/228 , C07C233/47 , C07C255/07
摘要： The present invention relates to novel water-soluble furylphosphines. It also relates to organometallic complexes comprising these furylphosphines and to the use of such complexes. It also relates to the process for the preparation of the water-soluble furylphosphines.
摘要翻译： 本发明涉及新的水溶性呋喃基膦。它还涉及包含这些呋喃基膦的有机金属络合物和这种络合物的用途。它还涉及制备水溶性呋喃基膦的方法。
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公开(公告)号：US5686381A
公开(公告)日：1997-11-11
申请号：US494185
申请日：1995-06-23
IPC分类号： B01J23/14 , B01J23/18 , B01J23/22 , C01G31/00 , C07B61/00 , C07C253/24 , C07C255/08
CPC分类号： B01J23/22 , B01J23/14 , B01J23/18 , C01G31/006 , C01P2002/72
摘要： Vanadium/antimony/tin mixed oxides having the empirical formula (I): VSb.sub.a Sn.sub.b O.sub.x (I) exhibit an X-ray diffraction pattern characteristic of a crystallographic phase of rutile SnO.sub.2, are well suited as catalysts for the vapor phase ammoxidation of alkanes, and are conveniently prepared by (a) dissolving respective compounds of vanadium, antimony and tin in at least one saturated alcohol, (b) intimately contacting the alcoholic solution thus obtained with an aqueous solution containing an ammonium salt, thus precipitating the mixed oxides therefrom, and (c) separating and calcining these mixed oxides.
摘要翻译： 具有经验式（I）：VSbaSnbOx（I）的钒/锑/锡混合氧化物表现出金红石型SnO2的结晶相的X射线衍射图，特别适用于烷烃气相氨氧化催化剂， 通过（a）将各种化合物的钒，锑和锡溶解在至少一种饱和醇中，（b）使由此获得的醇溶液与含有铵盐的水溶液紧密接触，从而沉淀其混合的氧化物，并且（ c）分离和煅烧这些混合氧化物。
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公开(公告)号：US5663392A
公开(公告)日：1997-09-02
申请号：US590577
申请日：1996-01-24
IPC分类号： B01J23/00 , B01J23/18 , B01J23/22 , B01J37/03 , B01J37/08 , C01G31/00 , C07B61/00 , C07C253/24 , C07C255/08 , C07F9/90
CPC分类号： C01G31/006 , B01J23/002 , B01J23/18 , B01J23/22 , C07C253/24 , B01J2523/00 , B01J37/033 , C01P2002/72 , Y02P20/52
摘要： Mixed oxide vanadium/antimony/titanium ammoxidation catalysts, particularly suited for the ammoxidation of alkanes and exhibiting X-ray diffraction spectra which are characteristic of a crystallographic phase of rutile TiO.sub.2, are prepared by (a) dissolving respective soluble compounds of vanadium, of antimony and of titanium in at least one saturated alcohol, (b) contacting the alcoholic solution thus obtained with water and precipitating the mixed oxide therefrom, and (c) separating and calcining the mixed oxide thus precipitated.
摘要翻译： 通过（a）溶解各种可溶性钒化合物锑，制备特别适用于烷烃氨氧化和表现出金红石TiO 2结晶相特征的X射线衍射光谱的混合氧化钒/锑/钛氨氧化催化剂 和至少一种饱和醇中的钛，（b）使所得到的醇溶液与水接触并使其混合氧化物沉淀，（c）分离和煅烧所沉淀的混合氧化物。
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公开(公告)号：US07098358B2
公开(公告)日：2006-08-29
申请号：US10399237
申请日：2001-10-03
IPC分类号： C07C253/00
CPC分类号： C07C253/30 , C07C253/10 , C07C255/04 , C07C255/07
摘要： The invention concerns a method for hydrocyanation of ethylenically unsaturated organic compounds into compounds comprising at least a nitrile function. More particularly, it concerns a method for hydrocyanation of organic compounds comprising at least a ethylenical bond by reacting hydrogen cyanide, in the presence of a catalytic system comprising a transition metal and an organophosphorus ligand. The organophosphorus ligand is a compound with monophosphanorbornadiene structure. The invention concerns in particular hydrocyanation of butadiene into adiponitrile.
摘要翻译： 本发明涉及将烯属不饱和有机化合物氢化成至少包含腈官能团的化合物的方法。 更具体地说，本发明涉及在包含过渡金属和有机磷配体的催化体系存在下，使氰化氢与氰化氢反应至少包含乙烯键的有机化合物的氢氰化方法。 有机磷配体是具有单磷酰二氢呋喃结构的化合物。 本发明特别涉及丁二烯氢化成己二腈。
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10.发明授权公开(公告)号：US06613939B2
公开(公告)日：2003-09-02
申请号：US09887043
申请日：2001-06-25
申请人： Larbi Aouni , Paolo Burattin , Pierre Coqueret , Marc Huser
发明人： Larbi Aouni , Paolo Burattin , Pierre Coqueret , Marc Huser
IPC分类号： C07C30932
CPC分类号： B01J31/2404 , B01J31/24 , B01J31/26 , B01J31/4015 , B01J2231/32 , B01J2231/321 , B01J2231/343 , B01J2231/52 , B01J2231/70 , B01J2531/16 , B01J2531/17 , B01J2531/18 , B01J2531/26 , B01J2531/27 , B01J2531/28 , B01J2531/80 , B01J2531/847 , B01J2531/96 , C07C253/10 , C07F9/025 , C07F9/5095 , Y02P20/584 , C07C255/04
摘要： Water-soluble sulfonated organophosphorus compounds are purified by at least partially removing contaminating sulfite values therefrom, by decreasing the pH of a solution of such sulfonated organophosphorus compounds to a value of less than or equal to 4, and maintaining the pH of the solution at this value of 4 or less for such period of time as to reduce the weight concentration of sulfite in the solution to less than 100 ppm; the organophosphorus compounds thus purified are well suited for the two-phase cocatalysis of a wide variety of organic reactions.
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