公开(公告)号：US08552234B2

公开(公告)日：2013-10-08

申请号：US12311497

申请日：2007-10-04

Applicant: Nicholas John Gudde

Inventor： Nicholas John Gudde

IPC: C10G1/00

CPC classification number: B01J8/025 ,  B01J8/0457 ,  B01J2208/00274 ,  B01J2208/00548 ,  B01J2208/00628 ,  B01J2219/0004 ,  C01B17/16 ,  C01B17/165 ,  C10G3/46 ,  C10G3/50 ,  C10G2300/1011 ,  C10G2300/1033 ,  C10G2300/202 ,  C10G2300/207 ,  C10G2300/4043 ,  C10G2300/4081 ,  C10G2400/04 ,  Y02P30/20 ,  Y02P30/446

Abstract: Process for producing hydrocarbons from a carboxylic acid by feeding hydrogen and a reaction composition containing a carboxylic acid to a reactor, maintaining reaction conditions such that the hydrogen reacts with the carboxylic acid to produce a C1 compound including CO, CO2 and CH4, and one or more product hydrocarbons derived from the carboxylic acid. The reaction between hydrogen and the carboxylic acid is catalysed. A product stream is removed from the reactor including unreacted hydrogen, at least one C1 compound, and at least one product hydrocarbon. One or more parameters of the reaction are controlled such that the molar ratio of C1 compounds produced by the reaction to the carboxylate groups present in the carboxylic acid in the reaction composition is maintained above a value of 0.37:1, and the mole ratio of carbon dioxide to the sum of carbon monoxide and methane is maintained above a value of 0.58:1.

Abstract translation: 通过将氢气和含有羧酸的反应组合物输送到反应器中从羧酸生产烃的方法，保持反应条件使得氢与羧酸反应产生包括CO，CO 2和CH 4的C 1化合物，以及一种或 更多的来自羧酸的产物烃。 氢和羧酸之间的反应被催化。 将产物流从反应器中除去，包括未反应的氢，至少一种C1化合物和至少一种产物烃。 控制反应的一个或多个参数使得通过反应产生的C1化合物与存在于反应组合物中的羧酸中的羧酸酯基团的摩尔比保持在0.37:1以上，并且碳的摩尔比 二氧化碳与一氧化碳和甲烷的总和保持在0.58:1以上。

公开(公告)号：US08742184B2

公开(公告)日：2014-06-03

申请号：US12311494

申请日：2007-10-04

Applicant: Nicholas John Gudde ,  James Adam Townsend

Inventor： Nicholas John Gudde ,  James Adam Townsend

IPC: C07C1/22

CPC classification number: C10L1/023 ,  C10G3/45 ,  C10G3/46 ,  C10G3/47 ,  C10G3/50 ,  C10G2300/1018 ,  C10G2300/1033 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/026 ,  Y02E50/13 ,  Y02P30/20 ,  Y02T50/678

Abstract: Process for hydrogenating a carboxylic acid or derivative thereof by feeding a carboxylic acid or derivative thereof and hydrogen to a reactor, maintaining conditions therein such that hydrogen reacts with the carboxylic acid and/or derivative thereof to form a product stream including one or more hydrocarbons and one or more oxides of carbon and feeding the product stream to a flash separator. A vapor fraction including the one or more oxides of carbon is separated from a liquid fraction having the one or more hydrocarbons. The concentration of carbon oxides in the flash separator is at or below a predetermined value.

Abstract translation: 通过将羧酸或其衍生物和氢气加入到反应器中来氢化羧酸或其衍生物的方法，保持其中的条件使得氢与羧酸和/或其衍生物反应形成包含一种或多种烃的产物流， 一种或多种碳的氧化物并将产物流输送到闪蒸分离器。 包含一种或多种碳的氧化物的蒸气馏分与具有一种或多种烃的液体馏分分离。 闪光分离器中的碳氧化物的浓度等于或低于预定值。

公开(公告)号：US07984643B2

公开(公告)日：2011-07-26

申请号：US11791607

申请日：2005-12-12

Applicant: Graham Butler ,  John William Couves ,  Paul Greenough ,  Nicholas John Gudde ,  Michael Graham Hodges

Inventor： Graham Butler ,  John William Couves ,  Paul Greenough ,  Nicholas John Gudde ,  Michael Graham Hodges

IPC: G01N33/00

CPC classification number: G01N17/043 ,  B01J19/0046 ,  B01J2219/00389 ,  B01J2219/00536 ,  B01J2219/00585 ,  B01J2219/0059 ,  B01J2219/00596 ,  B01J2219/00605 ,  B01J2219/00659 ,  B01J2219/00691 ,  B01J2219/00707 ,  B01J2219/00745 ,  B01J2219/0075 ,  B01J2219/00752 ,  B01J2219/00756 ,  C40B40/18 ,  C40B60/14 ,  G01N17/008

Abstract: The fouling caused by a refinery feedstock on one or more refinery processes, said process comprising: (i) providing a plurality of refinery feedstocks and/or a plurality of fractions of one or more refinery feedstocks, (ii) providing an array comprising a plurality of metal samples representative of metallurgy present in a refinery, (iii) contacting each of the plurality of metal samples with one or more of said (iv) refinery feedstocks or fractions under non-static conditions, and determining the fouling of said refinery feedstock or fraction thereof. Preferably, the metal samples are in the form of a microfabricated array and the testing is carried out in parallel using high throughput experimentation.

Abstract translation: 由炼油原料在一个或多个炼油工艺上造成的结垢，所述方法包括：（i）提供多个炼油原料和/或一个或多个炼油原料的多个馏分，（ii）提供包括多个 代表存在于炼油厂中的冶金的金属样品，（iii）使所述多个金属样品中的每一个在非静态条件下与一种或多种所述（iv）炼油原料或馏分接触，并确定所述炼油原料的结垢或 分数。 优选地，金属样品是微制造阵列的形式，并且使用高通量实验并行进行测试。

公开(公告)号：US20080102529A1

公开(公告)日：2008-05-01

申请号：US11662893

申请日：2005-09-14

Applicant: Graham Butler ,  John William Couves ,  Paul Greenough ,  Nicholas John Gudde ,  Michael Graham Hodges

Inventor： Graham Butler ,  John William Couves ,  Paul Greenough ,  Nicholas John Gudde ,  Michael Graham Hodges

IPC: G01N33/26

CPC classification number: G01N33/2829 ,  C10G49/26 ,  Y10T436/12

Abstract: The invention provides a process for evaluating the effect of a refinery feedstock on a refinery process, said process comprising (i) providing a refinery feedstock; (ii) treating said refinery feedstock to produce a plurality of fractions each representative of the typical feedstock for the refinery process of interest, said plurality of fractions comprise at least two fractions with different properties; (iii) treating each of the plurality of fractions under experimental conditions representative of those in the refinery process, said treatments being carved out in an essentially parallel manner; and (iv) determining one or more performance criteria in respect of each fraction for the refinery process.

Abstract translation: 本发明提供了一种用于评估炼油厂原料对炼油工艺的影响的方法，所述方法包括（i）提供炼油原料; （ii）处理所述炼油原料以产生多个馏分，每个馏分代表所述炼油方法的典型原料，所述多个馏分包含至少两个具有不同性质的馏分; （iii）在代表炼油工艺中的实验条件下处理多个级分中的每一个，所述处理以基本上平行的方式雕刻; 和（iv）确定炼油厂过程的每个馏分的一个或多个性能标准。

公开(公告)号：US07589539B2

公开(公告)日：2009-09-15

申请号：US11662895

申请日：2005-09-14

Applicant: Graham Butler ,  John William Couves ,  Paul Greenough ,  Nicholas John Gudde ,  Michael Graham Hodges

Inventor： Graham Butler ,  John William Couves ,  Paul Greenough ,  Nicholas John Gudde ,  Michael Graham Hodges

IPC: G01R27/08

CPC classification number: G01N27/041 ,  G01N17/00 ,  G01N17/006

Abstract: Process for evaluating the corrosive effect of a refinery feedstock on the metallurgy of one or more refinery processes, by (i) providing a plurality of refinery feedstocks and/or a plurality of fractions of one or more refinery feedstocks, (ii) providing an array having a plurality of metal samples representative of metallurgy present in a refinery, (iii) contacting each of the plurality of metal samples with one or more of the refinery feedstocks or fractions under non-static conditions, and (iv) determining the corrosive effect of the feedstock and/or fraction on the metal sample.

Abstract translation: 通过（i）提供多个炼油原料和/或一个或多个炼油原料的多个馏分来评估炼油原料对一个或多个炼油工艺的冶金的腐蚀作用的方法，（ii）提供阵列 具有表示炼油厂中存在的冶金的多个金属样品，（iii）在非静态条件下使多个金属样品中的每一个与一种或多种炼油原料或级分接触，以及（iv）确定腐蚀效应 金属样品上的原料和/或部分。

公开(公告)号：US20090107033A1

公开(公告)日：2009-04-30

申请号：US12227214

申请日：2007-05-18

Applicant: Nicholas John Gudde ,  James Adam Townsend

Inventor： Nicholas John Gudde ,  James Adam Townsend

IPC: C10L1/188

CPC classification number: C10G3/50 ,  C10G3/46 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1048 ,  C10G2300/202 ,  C10G2400/04 ,  Y02P30/20

Abstract: A process for the production of a fuel composition comprising hydrocarbons derived from carboxylic acids and/or carboxylic acid esters, which process comprises feeding hydrogen and a hydrocarbon-containing stream to a first reactor to reduce levels of olefins and/or heteroatom-containing compounds in the hydrocarbon-containing stream, and feeding the so-treated hydrocarbon-containing stream to a second reactor together with hydrogen and a carboxylic acid and/or ester to produce a second hydrocarbon-containing stream in which at least some of the hydrocarbons are derived from the carboxylic acid and/or ester.

Abstract translation: 一种用于生产包含衍生自羧酸和/或羧酸酯的烃的燃料组合物的方法，该方法包括将氢气和含烃物流进料到第一反应器中以降低烯烃和/或含杂原子的化合物的含量 含烃流，以及将如此处理的含烃流与氢气和羧酸和/或酯一起进料到第二反应器以产生第二含烃流，其中至少一些烃衍生自 羧酸和/或酯。

公开(公告)号：US20080116907A1

公开(公告)日：2008-05-22

申请号：US11662895

申请日：2005-09-14

Applicant: Graham Butler ,  John William Couves ,  Paul Greenough ,  Nicholas John Gudde ,  Michael Graham Hodges

Inventor： Graham Butler ,  John William Couves ,  Paul Greenough ,  Nicholas John Gudde ,  Michael Graham Hodges

IPC: G01R27/08

CPC classification number: G01N27/041 ,  G01N17/00 ,  G01N17/006

Abstract: A process for evaluating the corrosive effect of a refinery feedstock on the metallurgy of one or more refinery processes, said process comprising: (i) providing a plurality of refinery feedstocks and/or a plurality of fractions of one or more refinery feedstocks, (ii) providing an array comprising a plurality of metal samples representative of metallurgy present in a refinery, (iii) contacting each of the plurality of metal samples with one or more of said refinery feedstocks or fractions under non-static conditions, and (iv) determining the corrosive effect of said feedstock and/or fraction on the metal sample.

Abstract translation: 一种用于评估炼油原料对一个或多个炼油工艺的冶金的腐蚀作用的方法，所述方法包括：（i）提供多个炼油原料和/或一个或多个炼油原料的多个馏分，（ii ）提供包括代表炼油厂中存在的冶金的多个金属样品的阵列，（iii）使所述多个金属样品中的每一个与非静态条件下的一种或多种所述炼油原料或级分接触，以及（iv）确定 所述原料和/或部分对金属样品的腐蚀作用。

公开(公告)号：US08546146B2

公开(公告)日：2013-10-01

申请号：US11662947

申请日：2005-09-14

Applicant: Graham Butler ,  John William Couves ,  Paul Greenough ,  Nicholas John Gudde ,  Michael Graham Hodges

Inventor： Graham Butler ,  John William Couves ,  Paul Greenough ,  Nicholas John Gudde ,  Michael Graham Hodges

IPC: C40B30/10 ,  C40B30/00

CPC classification number: G01N33/2829 ,  C10G49/26 ,  Y10T436/21

Abstract: Process for evaluating a plurality of refinery feedstocks, by providing an array of refinery feedstocks, the array having at least a plurality of different refinery feedstocks, and fractionating each of the refinery feedstocks in the array, either in parallel or in a rapid serial fashion, to produce a further array having a plurality of fractions with different chemical and/or physical properties, each fraction being representative of a process stream that might be present in a refinery. Each of the plurality of fractions is analyzed to determine one or more chemical and/or physical properties of the fractions, the analyzes being performed at least partially in parallel.

Abstract translation: 通过提供一系列炼油原料来评估多个炼油原料的方法，该排列具有至少多个不同的炼油原料，并且以平行或快速连续的方式对阵列中的每个炼油原料进行分馏， 以产生具有不同化学和/或物理性质的多个级分的另外的阵列，每个馏分代表可能存在于炼油厂中的工艺流。 分析多个级分中的每一个以确定馏分的一种或多种化学和/或物理性质，分析至少部分地并行进行。

公开(公告)号：US08502004B2

公开(公告)日：2013-08-06

申请号：US11662893

申请日：2005-09-14

Applicant: Graham Butler ,  John William Couves ,  Paul Greenough ,  Nicholas John Gudde ,  Michael Graham Hodges

Inventor： Graham Butler ,  John William Couves ,  Paul Greenough ,  Nicholas John Gudde ,  Michael Graham Hodges

IPC: G01N33/26

CPC classification number: G01N33/2829 ,  C10G49/26 ,  Y10T436/12

Abstract: Process for evaluating the effect of a refinery feedstock on a refinery process by (i) providing a refinery feedstock (ii) treating the refinery feedstock to produce a plurality of fractions each representative of a feedstock for the refinery process, the plurality of fractions having at least two fractions with different properties; (iii) treating each of the plurality of fractions under experimental conditions representative of those in the refinery process, the treatments being carried out in an essentially parallel manner; and (iv) determining one or more performance criteria for each fraction for the refinery process by analyzing the respective product streams produced from each fraction at least partially in parallel.

Abstract translation: 用于通过（i）提供炼油原料来评估炼油厂原料对炼油工艺的影响的方法（ii）处理炼油原料以产生多个馏分，每个馏分代表炼油工艺的原料，多个馏分具有 至少两个具有不同性质的级分; （iii）在代表炼油厂过程的实验条件下处理多个级分中的每一个，处理以基本上平行的方式进行; 以及（iv）通过分析至少部分平行地从每个部分产生的各个产物流来确定炼油工艺的每个馏分的一个或多个性能标准。

公开(公告)号：US20080260584A1

公开(公告)日：2008-10-23

申请号：US11575367

申请日：2005-09-15

Applicant: Nicholas John Gudde ,  Michael Hodges ,  Graham Butler ,  Joachim Voelkening

Inventor： Nicholas John Gudde ,  Michael Hodges ,  Graham Butler ,  Joachim Voelkening

IPC: G01N30/00 ,  B01J19/00 ,  G01N21/01 ,  G01N27/00 ,  G01N33/26

CPC classification number: G01N33/2876 ,  G01N25/08 ,  G01N35/00871

Abstract: The present invention provides a portable apparatus for analysis of a refinery feedstock or a product of a refinery process, said apparatus comprising: (a) a first analytical device for determination of the boiling point profile of a refinery feedstock or a product of a refinery process, and (b) at least two further analytical devices each of which contains or is associated with a database and an algorithm, at least one of said devices being adapted for determination of the density of the refinery feedstock or product of a refinery process, and at least one of said devices being adapted for determination of the total acid number of the refinery feedstock or product of a refinery process.

Abstract translation: 本发明提供了一种用于分析炼油厂原料或炼油工艺产品的便携式设备，所述设备包括：（a）用于测定炼油原料或炼油工艺产物的沸点曲线的第一分析装置 ，和（b）至少两个其他分析装置，每个分析装置包含数据库和算法，其中至少一个装置适用于确定炼油工艺的炼油原料或产品的密度，以及 所述装置中的至少一个适于确定炼油工艺的炼油原料或产物的总酸值。