公开(公告)号：US20130040069A1

公开(公告)日：2013-02-14

申请号：US13634366

申请日：2011-04-19

Applicant: Michele A. Craton ,  Kelly S. Anderson ,  Belma Erdogan-Haug ,  Jayshree Seth

Inventor： Michele A. Craton ,  Kelly S. Anderson ,  Belma Erdogan-Haug ,  Jayshree Seth

IPC: C09J183/06 ,  B05D5/10

CPC classification number: C09J133/08 ,  C09J133/10 ,  C08K9/06

Abstract: Pressure sensitive adhesives comprising an acrylate polymer and surface-modified nanoparticles are described. The surface-modified nanoparticles comprise a nanoparticle having a silica surface and surface modifying groups covalently attached to the silica surface. At least one surface-modifying group is a polymeric silane surface modifying group. At least one surface-modifying group is a non-polymeric silane surface modifying group. Methods of preparing such adhesives, including their exposure to UVA and UVC radiation are also described.

Abstract translation: 描述了包含丙烯酸酯聚合物和表面改性的纳米颗粒的压敏粘合剂。 表面改性的纳米颗粒包含具有二氧化硅表面和共价连接到二氧化硅表面的表面改性基团的纳米颗粒。 至少一个表面改性基团是聚合物硅烷表面改性基团。 至少一个表面改性基团是非聚合硅烷表面改性基团。 还描述了制备这种粘合剂的方法，包括它们暴露于UVA和UVC辐射。

公开(公告)号：US07250611B2

公开(公告)日：2007-07-31

申请号：US10726257

申请日：2003-12-02

Applicant: Francis M. Aguirre ,  Michele A. Craton ,  Jack W. Lai ,  David L. Phillips ,  Peter T. Benson ,  Gordon D. Henson ,  Michael A. Meis

Inventor： Francis M. Aguirre ,  Michele A. Craton ,  Jack W. Lai ,  David L. Phillips ,  Peter T. Benson ,  Gordon D. Henson ,  Michael A. Meis

IPC: G01N21/00 ,  G01N21/33

CPC classification number: G02B6/4249 ,  A61C19/003 ,  A61C19/004 ,  F21K9/69 ,  F21V29/80 ,  G02B6/06 ,  G02B6/4201 ,  G02B6/4206 ,  G02B6/423 ,  G02B6/4231 ,  G02B6/4269 ,  G02B6/4298

Abstract: A radiation curing apparatus comprises a plurality of solid state radiation sources to generate radiation that cures a first material. The solid state radiation sources can be disposed in an array pattern. Optical concentrators, arranged in a corresponding array pattern, receive radiation from corresponding solid state radiation sources. The concentrated radiation is received by a plurality of optical waveguides, also arranged in a corresponding array pattern. Each optical waveguide includes a first end to receive the radiation and a second end to output the radiation. The curing apparatus can be utilized for continuous substrate, sheet, piece part, spot curing, and/or 3D radiation-cure processes.

Abstract translation: 辐射固化装置包括多个固态辐射源，以产生固化第一材料的辐射。 固态辐射源可以以阵列图案布置。 以相应的阵列图案布置的光学聚光器接收来自相应固态辐射源的辐射。 集中辐射由多个光波导接收，光波导也以相应的阵列图形排列。 每个光波导包括用于接收辐射的第一端和用于输出辐射的第二端。 固化装置可以用于连续的基材，片，片部分，点固化和/或3D辐射固化过程。

公开(公告)号：US07189983B2

公开(公告)日：2007-03-13

申请号：US10869237

申请日：2004-06-16

Applicant: Francis M. Aguirre ,  Peter T. Benson ,  Michele A. Craton ,  Gordon D. Henson ,  David L. Hofeldt ,  Jack W. Lai ,  Michael A. Meis ,  David L. Phillips

Inventor： Francis M. Aguirre ,  Peter T. Benson ,  Michele A. Craton ,  Gordon D. Henson ,  David L. Hofeldt ,  Jack W. Lai ,  Michael A. Meis ,  David L. Phillips

IPC: G01N21/33 ,  G01N21/00 ,  G02B6/43

CPC classification number: G02B6/4249 ,  A61C19/003 ,  A61C19/004 ,  F21K9/69 ,  F21V29/80 ,  G02B6/06 ,  G02B6/4201 ,  G02B6/4206 ,  G02B6/423 ,  G02B6/4231 ,  G02B6/4269 ,  G02B6/4298

Abstract: A radiation modifying apparatus comprises a plurality of solid state radiation sources to generate radiation that modifies a first material such as by curing or creating alignment through polarization. The solid state radiation sources can be disposed in an array pattern. Optical concentrators, arranged in a corresponding array pattern, receive radiation from corresponding solid state radiation sources. The concentrated radiation is received by a plurality of optical waveguides, also arranged in a corresponding array pattern. Each optical waveguide includes a first end to receive the radiation and a second end to output the radiation. The radiation modifying apparatus can be utilized for continuous substrate, sheet, piece part, spot curing, and/or 3D radiation-cure processes.

公开(公告)号：US08596799B2

公开(公告)日：2013-12-03

申请号：US12401294

申请日：2009-03-10

Applicant: Kenneth L. Smith ,  Gerald M. Benson ,  Michele A. Craton ,  Michael P. Daniels ,  Roger E. Luehrs

Inventor： Kenneth L. Smith ,  Gerald M. Benson ,  Michele A. Craton ,  Michael P. Daniels ,  Roger E. Luehrs

IPC: G02B5/122

CPC classification number: B29D11/00605 ,  G02B5/124 ,  Y10S428/913 ,  Y10T428/14 ,  Y10T428/1471 ,  Y10T428/1476 ,  Y10T428/24521 ,  Y10T428/24545 ,  Y10T428/24612

Abstract: Retroreflective sheeting includes a body layer having a structured surface with recessed faces forming cube corner cavities. A reflective film is disposed at least on the recessed faces, and a fill material fills the cube corner cavities. The fill material comprises radiation-curable materials, adhesives, or both, and preferably transparent radiation-curable pressure-sensitive adhesives. The fill material preferably forms a continuous layer covering both the recessed faces and upper portions of the structured surface. A transparent cover layer preferably contacts the fill material layer.

Abstract translation: 回射片包括具有形成立体角腔的凹面的结构化表面的主体层。 反射膜至少设置在凹面上，填充材料填充立体角空腔。 填充材料包括可辐射固化材料，粘合剂或两者，优选透明的可辐射固化的压敏粘合剂。 填充材料优选地形成覆盖结构化表面的凹面和上部的连续层。 透明覆盖层优选地接触填充材料层。

公开(公告)号：US20130101841A1

公开(公告)日：2013-04-25

申请号：US13807344

申请日：2011-06-27

Applicant: Yu Yang ,  Michael A. Semonick ,  George G.I. Moore ,  Larry D. Boardman ,  Michele A. Craton

Inventor： Yu Yang ,  Michael A. Semonick ,  George G.I. Moore ,  Larry D. Boardman ,  Michele A. Craton

IPC: C09D183/06 ,  C09J7/02

CPC classification number: C08L83/06 ,  C07F9/065 ,  C07F9/572 ,  C07F9/6584 ,  C07F9/65846 ,  C08G77/12 ,  C08G77/16 ,  C08K5/5399 ,  C08L83/00 ,  C08L83/04 ,  C09D183/04 ,  C09D183/06 ,  C09J7/38 ,  C09J183/04 ,  Y10T428/2809

Abstract: A curable composition comprises (a) at least one polydiorganosiloxane, fluorinated polydiorganosiloxane, or combination thereof comprising reactive silane functionality comprising at least two hydroxysilyl moieties; (b) at least one polydiorganosiloxane, fluorinated polydiorganosiloxane, or combination thereof comprising reactive silane functionality comprising at least two hydrosilyl moieties; and (c) at least one photoactivatable composition that, upon exposure to radiation, generates at least one base selected from amidines, guanidines, phosphazenes, proazaphosphatranes, and combinations thereof; wherein at least one of the components (a) and (b) has an average reactive silane functionality of at least three.

Abstract translation: 可固化组合物包含（a）至少一种聚二有机硅氧烷，氟化聚二有机硅氧烷或其组合，其包含至少两个羟基甲硅烷基部分的反应性硅烷官能团; （b）至少一种聚二有机硅氧烷，氟化聚二有机硅氧烷或其组合，其包含至少两个氢化甲硅烷基部分的反应性硅烷官能团; 和（c）至少一种可光活化的组合物，其在暴露于辐射之后产生至少一种选自脒，胍，磷腈，前药磷酰胺及其组合的碱; 其中组分（a）和（b）中的至少一种具有至少三个的平均反应性硅烷官能度。

公开(公告)号：US20130101840A1

公开(公告)日：2013-04-25

申请号：US13807326

申请日：2011-06-21

Applicant: Yu Yang ,  Michael A. Semonick ,  George G.I. Moore ,  Larry D. Boardman ,  Michele A. Craton ,  Kanta Kumar

Inventor： Yu Yang ,  Michael A. Semonick ,  George G.I. Moore ,  Larry D. Boardman ,  Michele A. Craton ,  Kanta Kumar

IPC: C09D183/06

CPC classification number: C09D183/06 ,  C07C267/00 ,  C07C279/04 ,  C07F9/065 ,  C07F9/572 ,  C07F9/6584 ,  C07F9/65846 ,  C08G77/24 ,  C08K5/5399 ,  C08L83/04 ,  C09D183/04 ,  Y10T428/2809 ,  C08L83/00

Abstract: A curable composition comprises (a) at least one polydiorganosiloxane, fluorinated polydiorganosiloxane, or combination thereof comprising reactive silane functionality comprising at least two hydroxysilyl moieties; (b) at least one polydiorganosiloxane, fluorinated polydiorganosiloxane, or combination thereof comprising reactive silane functionality comprising at least two hydrosilyl moieties; and (c) at least one base selected from amidines, guanidines, phosphazenes, proazaphosphatranes, and combinations thereof; wherein at least one of the components (a) and (b) has an average reactive silane functionality of at least three.

Abstract translation: 可固化组合物包含（a）至少一种聚二有机硅氧烷，氟化聚二有机硅氧烷或其组合，其包含至少两个羟基甲硅烷基部分的反应性硅烷官能团; （b）至少一种聚二有机硅氧烷，氟化聚二有机硅氧烷或其组合，其包含至少两个氢化甲硅烷基部分的反应性硅烷官能团; 和（c）至少一种选自脒，胍，磷腈，前氮磷酰胺及其组合的碱; 其中组分（a）和（b）中的至少一种具有至少三个的平均反应性硅烷官能度。

公开(公告)号：US06280822B1

公开(公告)日：2001-08-28

申请号：US09228367

申请日：1999-01-11

Applicant: Kenneth L. Smith ,  Gerald M. Benson ,  James C. Coderre ,  Cheryl M. Frey ,  Bruce B. Wilson ,  Michele A. Craton ,  Michael P. Daniels ,  Roger E. Luehrs

Inventor： Kenneth L. Smith ,  Gerald M. Benson ,  James C. Coderre ,  Cheryl M. Frey ,  Bruce B. Wilson ,  Michele A. Craton ,  Michael P. Daniels ,  Roger E. Luehrs

IPC: B32B300

CPC classification number: B29D11/00605 ,  G02B5/124 ,  Y10S428/913 ,  Y10T428/14 ,  Y10T428/1471 ,  Y10T428/1476 ,  Y10T428/24521 ,  Y10T428/24545 ,  Y10T428/24612

Abstract: Retroreflective sheeting includes a body layer having a structured surface with recessed faces forming cube corner cavities. A reflective film is disposed at least on the recessed faces, and a fill material fills the cube corner cavities. The fill material comprises radiation-curable materials, adhesives, or both, and preferably transparent radiation-curable pressure-sensitive adhesives. The fill material preferably forms a continuous layer covering both the recessed faces and upper portions of the structured surface. A transparent cover layer preferably contacts the fill material layer.

Abstract translation: 回射片包括具有形成立体角腔的凹面的结构化表面的主体层。 反射膜至少设置在凹面上，填充材料填充立体角空腔。 填充材料包括可辐射固化材料，粘合剂或两者，优选透明的可辐射固化的压敏粘合剂。 填充材料优选地形成覆盖结构化表面的凹面和上部的连续层。 透明覆盖层优选地接触填充材料层。

公开(公告)号：US07202489B2

公开(公告)日：2007-04-10

申请号：US10869235

申请日：2004-06-16

Applicant: Francis M. Aguirre ,  Michele A. Craton ,  Jack W. Lai ,  David L. Phillips ,  Peter T. Benson

Inventor： Francis M. Aguirre ,  Michele A. Craton ,  Jack W. Lai ,  David L. Phillips ,  Peter T. Benson

IPC: G01N21/00 ,  G01N21/33 ,  G02B6/43

CPC classification number: G02B6/4249 ,  A61C19/003 ,  A61C19/004 ,  F21K9/69 ,  F21V29/80 ,  G02B6/06 ,  G02B6/4201 ,  G02B6/4206 ,  G02B6/423 ,  G02B6/4231 ,  G02B6/4269 ,  G02B6/4298

Abstract: A radiation modifying apparatus comprises a plurality of solid state radiation sources to generate radiation that modifies a first material such as by curing or creating alignment through polarization. The solid state radiation sources can be disposed in an array pattern. Optical concentrators, arranged in a corresponding array pattern, receive radiation from corresponding solid state radiation sources. The concentrated radiation is received by a plurality of optical waveguides, also arranged in a corresponding array pattern. Each optical waveguide includes a first end to receive the radiation and a second end to output the radiation. The radiation modifying apparatus can be utilized for continuous substrate, sheet, piece part, spot curing, and/or 3D radiation-cure processes.

公开(公告)号：US06599602B2

公开(公告)日：2003-07-29

申请号：US09324148

申请日：1999-06-02

Applicant: Richard E. Bennett ,  Greggory S. Bennett ,  Michele A. Craton ,  Shih-Hung Chou

Inventor： Richard E. Bennett ,  Greggory S. Bennett ,  Michele A. Craton ,  Shih-Hung Chou

IPC: B32B1508

CPC classification number: B32B7/12 ,  B32B15/09 ,  B32B27/08 ,  B32B27/365 ,  B32B2307/414 ,  B32B2307/714 ,  B32B2369/00 ,  B32B2429/02 ,  C08L33/08 ,  C08L39/04 ,  C09J4/00 ,  C09J5/00 ,  C09J2400/163 ,  C09J2433/00 ,  C09J2469/006 ,  G11B7/24 ,  G11B7/2534 ,  G11B7/2535 ,  G11B7/256 ,  G11B7/2585 ,  G11B7/259 ,  G11B7/2595 ,  G11B7/26 ,  Y10T428/21 ,  Y10T428/31507 ,  Y10T428/31551 ,  Y10T428/31663 ,  Y10T428/31678 ,  Y10T428/31681 ,  Y10T428/31797 ,  Y10T428/31935 ,  C08F220/18 ,  C08F226/06

Abstract: An article is disclosed that includes a) a first polycarbonate substrate; b) a second polycarbonate substrate; and c) an adhesive composition disposed between the first polycarbonate substrate and the second polycarbonate substrate such that the first polycarbonate substrate is bonded to said second polycarbonate substrate through the adhesive composition; the adhesive composition includes an adhesive polymer that includes the reaction product of 1) an N-vinyl containing monomer selected from the group consisting of N-vinyl caprolactam, N-vinyl pyrrolidone, and N-vinyl imidazole, and combinations thereof, and 2) an acrylic acid ester monomer of a non-tertiary alcohol having an alkyl group that includes 4 to 20 carbon atoms.

Abstract translation: 公开了一种制品，其包括：a）第一聚碳酸酯基材; b）第二聚碳酸酯基材; 以及c）粘合剂组合物，其设置在所述第一聚碳酸酯基材和所述第二聚碳酸酯基材之间，使得所述第一聚碳酸酯基材通过所述粘合剂组合物结合到所述第二聚碳酸酯基材; 粘合剂组合物包括粘合剂聚合物，其包含1）选自N-乙烯基己内酰胺，N-乙烯基吡咯烷酮和N-乙烯基咪唑的含N-乙烯基单体及其组合的反应产物，和2） 具有含有4〜20个碳原子的烷基的非叔醇的丙烯酸酯单体。

公开(公告)号：US06544643B1

公开(公告)日：2003-04-08

申请号：US09670068

申请日：2000-09-26

Applicant: Patrick D. Hyde ,  Michele A. Craton

Inventor： Patrick D. Hyde ,  Michele A. Craton

IPC: B32B2732

CPC classification number: C09J123/20 ,  C09J4/06 ,  C09J7/38 ,  C09J11/06 ,  C09J2423/00 ,  C09J2433/00 ,  Y10S525/903 ,  Y10T428/2878 ,  Y10T428/2891 ,  Y10T428/2982 ,  C08F255/00

Abstract: The invention relates to a pressure sensitive adhesive composition comprising a poly(1-alkene) elastomer and a multifunctional (meth)acrylate component. The invention also relates to articles comprising the composition and a method of making the composition.

Abstract translation: 本发明涉及包含聚（1-烯烃）弹性体和多官能（甲基）丙烯酸酯组分的压敏粘合剂组合物。 本发明还涉及包含组合物的制品和制备该组合物的方法。