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公开(公告)号：US07156887B1
公开(公告)日：2007-01-02
申请号：US10304564
申请日：2002-11-26
申请人： Michael Ian Petch , David Thompsett , Suzanne Rose Ellis , David Wails , Jillian Elaine Bailie , Mark Robert Feaviour , Paul James Millington
发明人： Michael Ian Petch , David Thompsett , Suzanne Rose Ellis , David Wails , Jillian Elaine Bailie , Mark Robert Feaviour , Paul James Millington
IPC分类号： C01B3/24
CPC分类号： C01B3/382 , B01J8/0438 , B01J19/2485 , B01J23/63 , B01J2208/025 , C01B3/48 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/042 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/1023 , C01B2203/1029 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C01B2203/1094 , C01B2203/1276 , Y02P20/52
摘要： Methods and apparatus for producing hydrogen are provided. The methods and apparatus utilize reforming catalysts in order to produce hydrogen gas. The reforming catalysts may be platinum group metals on a support material, and they may be located in a reforming reaction zone of a primary reactor. The support material may an oxidic support having a ceria zirconia promoter. The support material may be an oxidic support and a neodymium stabilizer. The support material may also be an oxidic support material and at least one Group IA, Group IIA, manganese, or iron metal promoter. The primary reactor may have a first and second reforming reaction zones. Upstream reforming catalysts located in the first reforming reaction zone may be selected to perform optimally under the conditions in the first reforming reaction zone. Downstream reforming catalysts located in the second reforming reaction zone may be selected to perform optimally under the conditions in the second reforming reaction zone.
摘要翻译： 提供了生产氢的方法和装置。 该方法和装置利用重整催化剂以产生氢气。 重整催化剂可以是载体材料上的铂族金属，并且它们可以位于初级反应器的重整反应区中。 载体材料可以是具有二氧化铈氧化锆促进剂的氧化载体。 载体材料可以是氧化载体和钕稳定剂。 载体材料还可以是氧化载体材料和至少一种IA族，IIA族，锰或铁金属促进剂。 初级反应器可以具有第一和第二重整反应区。 可以选择位于第一重整反应区中的上游重整催化剂，以在第一重整反应区的条件下最佳地进行。 可以选择位于第二重整反应区中的下游重整催化剂，以在第二重整反应区的条件下最佳地进行。
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公开(公告)号：US09127182B2
公开(公告)日：2015-09-08
申请号：US11914696
申请日：2006-05-17
申请人： Dharshini Chryshantha Fongalland , Pamela Kapila , Chandresh Nemchand Malde , Michael Ian Petch
发明人： Dharshini Chryshantha Fongalland , Pamela Kapila , Chandresh Nemchand Malde , Michael Ian Petch
CPC分类号： C09D11/52 , H01M4/8652 , H01M4/8663 , H01M4/881 , H01M4/8828 , H01M8/1004 , H01M8/1023 , H01M8/1039 , H01M8/1081 , Y02E60/521 , Y02P70/56
摘要： A polymer dispersion comprising one or more proton-conducting polymer materials in a liquid medium, and an electrocatalyst ink comprising one or more electrocatalyst materials and one or more proton-conducting polymer materials in a liquid medium are disclosed. The polymer dispersion and the electrocatalyst ink further comprise a protic acid. Electrocatalyst layers, gas diffusion electrodes, catalyzed membranes and membrane electrode assemblies prepared using the dispersion and/or the ink are also disclosed.
摘要翻译： 公开了一种在液体介质中包含一种或多种质子传导性聚合物材料的聚合物分散体，以及包含一种或多种电催化剂材料和液体介质中的一种或多种质子传导性聚合物材料的电催化剂油墨。 聚合物分散体和电催化剂油墨还包含质子酸。 还公开了使用分散体和/或油墨制备的电催化剂层，气体扩散电极，催化膜和膜电极组件。
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公开(公告)号：US20150086902A1
公开(公告)日：2015-03-26
申请号：US14384506
申请日：2013-03-28
申请人： Graham Alan Hards , Ian Roy Harkness , Michael Ian Petch , Jonathan David Brereton Sharman , Edward Anthony Wright , Alexander Martin Willcocks
发明人： Graham Alan Hards , Ian Roy Harkness , Michael Ian Petch , Jonathan David Brereton Sharman , Edward Anthony Wright , Alexander Martin Willcocks
CPC分类号： H01M4/8652 , H01M4/8657 , H01M4/8814 , H01M4/9041 , H01M4/9075 , H01M4/92 , H01M4/925 , H01M8/1004 , H01M2008/1095
摘要： A catalytic material includes (i) a support material and (ii) a thin film catalyst coating having an inner face adjacent to the support material and an outer face, the thin film catalyst coating having a mean thickness of ≦8 nm, and wherein at least 40% of the support material surface area is covered by the thin film catalyst coating; and wherein the thin film catalyst coating includes a first metal and one or more second metals, and wherein the atomic percentage of first metal in the thin film catalyst coating is not uniform through the thickness of the thin film catalyst coating.
摘要翻译： 催化材料包括（i）支撑材料和（ii）具有与支撑材料相邻的内表面和外表面的薄膜催化剂涂层，所述薄膜催化剂涂层的平均厚度为＆lt; NE; 8nm，并且其中 至少40％的载体材料表面积被薄膜催化剂涂层所覆盖; 并且其中所述薄膜催化剂涂层包括第一金属和一种或多种第二金属，并且其中所述薄膜催化剂涂层中的第一金属的原子百分比通过所述薄膜催化剂涂层的厚度不均匀。
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公开(公告)号：US07867299B2
公开(公告)日：2011-01-11
申请号：US11070919
申请日：2005-03-03
申请人： Michael Ian Petch , Jonathan Charles Frost , Suzanne Rose Ellis , Jessica Grace Reinkingh , Mark Robert Feaviour , Jillian Elaine Bailie , David Wails , Paul James Millington
发明人： Michael Ian Petch , Jonathan Charles Frost , Suzanne Rose Ellis , Jessica Grace Reinkingh , Mark Robert Feaviour , Jillian Elaine Bailie , David Wails , Paul James Millington
IPC分类号： B01J8/00
CPC分类号： H01M8/0631 , B01J19/2485 , B01J2208/025 , C01B3/382 , C01B2203/0244 , C01B2203/066 , C01B2203/0844 , C01B2203/1023 , C01B2203/1064 , C01B2203/142 , C01B2203/82 , Y02P20/52
摘要： Methods and apparatus for producing hydrogen with reforming catalysts. The reforming catalysts may be platinum group metals on a support material, and they may be located in a reforming reaction zone of a primary reactor. The support material may be an oxidic support having a ceria and zirconia promoter, or may include a neodymium stabilizer. The support material may also include at least one Group IA, Group IIA, manganese, or iron metal promoter. The primary reactor may have a first and second reforming reaction zones, where upstream catalysts located in the first reforming reaction zone and downstream catalysts located in the second reforming reaction zone may be selected to perform optimally under the conditions in their respective reforming reaction zone.
摘要翻译： 用重整催化剂生产氢的方法和装置。 重整催化剂可以是载体材料上的铂族金属，并且它们可以位于初级反应器的重整反应区中。 载体材料可以是具有二氧化铈和氧化锆助催化剂的氧化载体，或者可以包括钕稳定剂。 载体材料还可以包括至少一种IA族，IIA族，锰或铁金属促进剂。 初级反应器可以具有第一和第二重整反应区，其中可以选择位于第一重整反应区中的上游催化剂和位于第二重整反应区中的下游催化剂，以在它们各自的重整反应区内的条件下进行最佳的反应。
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公开(公告)号：US06927189B1
公开(公告)日：2005-08-09
申请号：US09857315
申请日：1999-11-22
IPC分类号： B05D7/14 , B01J23/89 , B01J29/08 , B01J29/40 , B01J29/70 , B01J32/00 , B01J35/04 , B01J37/02 , B32B9/00 , B01J23/00
CPC分类号： B01J29/084 , B01J29/082 , B01J29/70 , B01J35/04 , B01J37/0217 , B01J37/0219 , B01J37/0246 , B01J2229/42
摘要： A substrate, such as a plate or catalyst monolith, may be coated with a metal oxide, particularly with a zeolite, by treating the substrate with a polyectrolyte to form a coating, and then depositing the coating of metal oxide from an aqueous slurry. A continuous coating, which may incorporate many layers, can easily be formed. In the examples polyacrylamide is used as polyelectrolyte.
摘要翻译： 可以用金属氧化物，特别是用沸石涂覆基材，例如用多孔共聚物处理基材以形成涂层，然后从含水浆料沉积金属氧化物涂层。 可以容易地形成可以并入多层的连续涂层。 在实施例中，聚丙烯酰胺用作聚电解质。
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公开(公告)号：US20130052563A1
公开(公告)日：2013-02-28
申请号：US13580793
申请日：2011-02-23
CPC分类号： H01M8/1097 , C25B13/00 , H01M8/0289 , H01M8/1044 , H01M8/1053 , H01M8/106 , H01M8/1062 , H01M8/1065 , H01M2008/1095 , Y02E60/366
摘要： A reinforced membrane comprises:(I) a planar reinforcing component made from metal, carbon, polymer or a composite thereof, and(ii) an ion-conducting material,wherein the planar reinforcing component is a cellular structure, comprising a plurality of discrete cells, wherein the wall of each cell extends through the thickness of the component such that the cell wall is impermeable to the proton-conducting material and wherein the proton-conducting material fills the cells of the planar reinforcing component. Such a membrane is of use in a fuel cell or an electrolyser.
摘要翻译： 增强膜包括：（I）由金属，碳，聚合物或其复合材料制成的平面增强部件，和（ii）离子传导材料，其中所述平面增强部件是细胞结构，包括多个离散细胞 ，其中每个电池的壁延伸穿过该部件的厚度，使得电池壁对质子传导材料是不可渗透的，并且其中质子传导材料填充该平面增强部件的电池。 这种膜在燃料电池或电解槽中是有用的。
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公开(公告)号：US20080292943A1
公开(公告)日：2008-11-27
申请号：US11914696
申请日：2006-05-16
申请人： Dharshini Chryshantha Fongalland , Pamela Kapila , Chandresh Nemchand Malde , Michael Ian Petch
发明人： Dharshini Chryshantha Fongalland , Pamela Kapila , Chandresh Nemchand Malde , Michael Ian Petch
CPC分类号： C09D11/52 , H01M4/8652 , H01M4/8663 , H01M4/881 , H01M4/8828 , H01M8/1004 , H01M8/1023 , H01M8/1039 , H01M8/1081 , Y02E60/521 , Y02P70/56
摘要： A polymer dispersion comprising one or more proton-conducting polymer materials in a liquid medium, and an electrocatalyst ink comprising one or more electrocatalyst materials and one or more proton-conducting polymer materials in a liquid medium are disclosed. The polymer dispersion and the electrocatalyst ink further comprise a protic acid. Electrocatalyst layers, gas diffusion electrodes, catalysed membranes and membrane electrode assemblies prepared using the dispersion and/or the ink are also disclosed.
摘要翻译： 公开了一种在液体介质中包含一种或多种质子传导性聚合物材料的聚合物分散体，以及包含一种或多种电催化剂材料和液体介质中的一种或多种质子传导性聚合物材料的电催化剂油墨。 聚合物分散体和电催化剂油墨还包含质子酸。 还公开了使用分散体和/或油墨制备的电催化剂层，气体扩散电极，催化的膜和膜电极组件。
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公开(公告)号：US09577269B2
公开(公告)日：2017-02-21
申请号：US14384506
申请日：2013-03-28
申请人： Graham Alan Hards , Ian Roy Harkness , Michael Ian Petch , Jonathan David Brereton Sharman , Edward Anthony Wright , Alexander Martin Willcocks
发明人： Graham Alan Hards , Ian Roy Harkness , Michael Ian Petch , Jonathan David Brereton Sharman , Edward Anthony Wright , Alexander Martin Willcocks
CPC分类号： H01M4/8652 , H01M4/8657 , H01M4/8814 , H01M4/9041 , H01M4/9075 , H01M4/92 , H01M4/925 , H01M8/1004 , H01M2008/1095
摘要： A catalytic material includes (i) a support material and (ii) a thin film catalyst coating having an inner face adjacent to the support material and an outer face, the thin film catalyst coating having a mean thickness of ≦8 nm, and wherein at least 40% of the support material surface area is covered by the thin film catalyst coating; and wherein the thin film catalyst coating includes a first metal and one or more second metals, and wherein the atomic percentage of first metal in the thin film catalyst coating is not uniform through the thickness of the thin film catalyst coating.
摘要翻译： 催化材料包括（i）支撑材料和（ii）具有与支撑材料相邻的内表面和外表面的薄膜催化剂涂层，薄膜催化剂涂层具有≤8nm的平均厚度，并且其中在 至少40％的支撑材料表面积被薄膜催化剂涂层覆盖; 并且其中所述薄膜催化剂涂层包括第一金属和一种或多种第二金属，并且其中所述薄膜催化剂涂层中的第一金属的原子百分比通过所述薄膜催化剂涂层的厚度不均匀。
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公开(公告)号：US07459224B1
公开(公告)日：2008-12-02
申请号：US10304563
申请日：2002-11-26
申请人： Michael Ian Petch , Mark Robert Feaviour , Suzanne Rose Ellis , Jillian Elaine Bailie , David Wails , Paul James Millington
发明人： Michael Ian Petch , Mark Robert Feaviour , Suzanne Rose Ellis , Jillian Elaine Bailie , David Wails , Paul James Millington
CPC分类号： H01M8/0618 , C01B3/382 , C01B3/48 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/042 , C01B2203/044 , C01B2203/047 , C01B2203/066 , C01B2203/1023 , C01B2203/1064 , C01B2203/107 , C01B2203/1094 , H01M2250/20 , Y02T90/32
摘要： Methods and apparatus for producing hydrogen are provided. The methods and apparatus utilize reforming catalysts in order to produce hydrogen gas. The reforming catalysts may be platinum group metals on a support material, and they may be located in a reforming reaction zone of a primary reactor. The support material may an oxidic support having a ceria zirconia promoter. The support material may be an oxidic support and a neodymium stabilizer. The support material may also be an oxidic support material and at least one Group IA, Group IIA, manganese, or iron metal promoter. The primary reactor may have a first and second reforming reaction zones. Upstream reforming catalysts located in the first reforming reaction zone may be selected to perform optimally under the conditions in the first reforming reaction zone. Downstream reforming catalysts located in the second reforming reaction zone may be selected to perform optimally under the conditions in the second reforming reaction zone.
摘要翻译： 提供了生产氢的方法和装置。 该方法和装置利用重整催化剂以产生氢气。 重整催化剂可以是载体材料上的铂族金属，并且它们可以位于初级反应器的重整反应区中。 载体材料可以是具有二氧化铈氧化锆促进剂的氧化载体。 载体材料可以是氧化载体和钕稳定剂。 载体材料还可以是氧化载体材料和至少一种IA族，IIA族，锰或铁金属促进剂。 初级反应器可以具有第一和第二重整反应区。 可以选择位于第一重整反应区中的上游重整催化剂，以在第一重整反应区的条件下最佳地进行。 可以选择位于第二重整反应区中的下游重整催化剂，以在第二重整反应区的条件下最佳地进行。
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公开(公告)号：US07375049B2
公开(公告)日：2008-05-20
申请号：US10486622
申请日：2002-07-15
申请人： Martin John Hayes , Chandresh Malde , Michael Ian Petch , Stephen David Pollington , Brian Ronald Charles Theobald
发明人： Martin John Hayes , Chandresh Malde , Michael Ian Petch , Stephen David Pollington , Brian Ronald Charles Theobald
CPC分类号： B01J37/0205 , B01J21/005 , B01J21/04 , B01J23/626 , B01J23/63 , C07C5/02 , C07C5/325 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/18 , C07C2523/06 , C07C2523/08 , C07C2523/12 , C07C2523/14 , C07C2523/18 , C07C2523/40 , C07C2523/72 , C07C2527/22
摘要： A catalyst suitable for the dehydrogenation and hydrogenation of hydrocarbons comprises at least one first metal and at least one second metal bound to a support material. The at least one first metal comprises at least one transition metal, suitably a platinum group metal. The support material is provided with an overlayer such that acidic sites on the support material are substantially blocked. In a preferred embodiment the catalyst is also substantially chloride free. Method of preparing catalyst are also disclosed.
摘要翻译： 适用于烃的脱氢和氢化的催化剂包括至少一种第一金属和至少一种与载体材料结合的第二金属。 所述至少一种第一金属包含至少一种过渡金属，合适的是铂族金属。 支撑材料设置有覆盖层，使得支撑材料上的酸性位点基本上被阻挡。 在优选的实施方案中，催化剂也基本上不含氯。 还公开了制备催化剂的方法。
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