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    METAL FREE BLEACHING COMPOSITION
    5.
    发明申请
    METAL FREE BLEACHING COMPOSITION 有权
    无金属漂白组合物

    公开(公告)号：US20130117941A1

    公开(公告)日：2013-05-16

    申请号：US13703385

    申请日：2011-06-21

    申请人： Markus Frey ,  Hauke Rohwer ,  Frédérique Wendeborn ,  Menno Hazenkamp

    发明人： Markus Frey ,  Hauke Rohwer ,  Frédérique Wendeborn ,  Menno Hazenkamp

    IPC分类号： D06L3/02

    CPC分类号： D06L4/15 ,  C07C225/06 ,  C07C225/22 ,  C07C317/32 ,  C07C323/32 ,  C07C381/12 ,  C07C2601/14 ,  C11D3/30 ,  C11D3/349 ,  C11D3/3902 ,  C11D3/3905 ,  C11D3/3915 ,  C11D3/3917 ,  C11D7/3236 ,  C11D7/3281 ,  C11D7/34 ,  D06L4/12

    摘要： The present invention relates to the use of a composition comprising specific a-amino-ketones, H2O2, a H2O2 precursor or a peracid and optionally an activator as a bleaching mixture for textile materials or dishes either manually or in an automatic washing machine or dish washer. Further aspects of the invention are the composition comprising specific a-aminoketones and H2O2, a H2O2 precursor or a peracid and a process for bleaching of stains or of soiling on textile materials or dishes in the context of a washing process either manually or in an automatic washing machine or dish washer. Also aspects of the invention are detergent formulations comprising such a composition and novel compounds.

    摘要翻译： 本发明涉及包含特定的α-氨基酮，H 2 O 2，H 2 O 2前体或过酸和任选的活化剂的组合物作为纺织材料或盘子的漂白混合物的手段或者在自动洗衣机或洗碗机中的用途 。 本发明的其它方面是包含特定的α-氨基酮和H 2 O 2，H 2 O 2前体或过酸的组合物，以及在洗涤过程中手动或自动地漂洗污渍或污染纺织品材料或菜肴的方法 洗衣机或洗碗机。 本发明的另外方面是包含这种组合物和新化合物的洗涤剂制剂。

    Use of metal complex compounds as oxidation catalysts
    8.
    发明申请
    Use of metal complex compounds as oxidation catalysts 失效

    公开(公告)号：US20060100123A1

    公开(公告)日：2006-05-11

    申请号：US10520841

    申请日：2003-07-03

    申请人： Gunther Schlingloff ,  Torsten Wieprecht ,  Frank Bachmann ,  Josef Dannacher ,  Marie-Josee Dubs ,  Menno Hazenkamp ,  Uwe Heinz ,  Markus Frey ,  Albert Schneider

    发明人： Gunther Schlingloff ,  Torsten Wieprecht ,  Frank Bachmann ,  Josef Dannacher ,  Marie-Josee Dubs ,  Menno Hazenkamp ,  Uwe Heinz ,  Markus Frey ,  Albert Schneider

    IPC分类号： C11D3/00

    CPC分类号： C11D3/168 ,  C07D213/68 ,  C07D213/74 ,  C11D3/3932

    摘要： Use of metal complex compounds of formula (1) [LnMcmXp]zYq wherein Mc is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q=z/(charge Y), and L is a ligand of formula (2) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen: unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; —COOR12 or —SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl: —SR13, —SO12R13 or —OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; —NR14R15; —(C1-C6alkylene)-NR14R15; —NoR14R15R16; —(C1-C6alkylene)-NoR14R15R16; —N(R)15)—(C1-C6alkylene)-NR1R15; —N[(C1-C6alkylene)-NR14R15]2; —N(R13)—(C1-C6alkylene)-NoR14R15R16, —N[C1-C6alkylene)-NoR14R15R16]2; —N(R13)—N—R14R15 or —N(R13)—NoR14R15R16: wherein R13 is as defined above and R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further heterotatoms; with the proviso that (i) at least one of the substituents R1—R11 contains a quaternized atom which is not directly bonded to one of the three pyridine A, B or C and that (ii) Y is neither I′ nor Cl′ in the case that Me is Mn(II), R1—R5 and R7—R11 are hydrogen and R6 is formula (III) as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1), the novel ligands of formula (2) and their starting materials.