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    Insecticidal and/or acaricidal composition exhibiting low toxicity to mammals and fish
    1.
    发明授权
    Insecticidal and/or acaricidal composition exhibiting low toxicity to mammals and fish 失效
    对哺乳动物和鱼类具有低毒性的杀虫和/或杀螨成分

    公开(公告)号：US4443438A

    公开(公告)日：1984-04-17

    申请号：US406014

    申请日：1982-08-06

    申请人： Kiyoshi Kasamatsu ,  Masachika Hirano ,  Takeshi Okuno

    发明人： Kiyoshi Kasamatsu ,  Masachika Hirano ,  Takeshi Okuno

    IPC分类号： A01N53/00 ,  A01N57/00 ,  A01N37/34 ,  A01N57/26

    CPC分类号： A01N53/00

    摘要： The present invention relates to insecticidal compositions of low toxicity to fishes and mammals characterized by containing m-(p-bromophenoxy)-.alpha.-cyanolbenzyl trans- or trans-rich-2,2-dimethyl-3-(2,2-dichlorovinyl)cyclopropanecarboxylate of the formula (I), ##STR1## and at least one of the organo-phosphoric esters of the formula (II), ##STR2## wherein R.sub.1 and R.sub.2 are each a C.sub.1 -C.sub.3 alkyl group, X.sub.1, X.sub.2 and X.sub.3 are each an oxygen or sulfur atom, Y.sub.1 and Y.sub.2, which may be the same or different, are each a C.sub.1 -C.sub.3 lower alkyl, methylmercapto, cyano or nitro group or a halogen atom, Z is a carbon or nitrogen atom and n is 0 or 1, in a ratio of 1 to 1-100 (part by weight) of the former to the latter, and insecticides obtained by mixing said compositions with a carrier or a diluent and if necessary an additive. The term "trans-rich" shows the ratio of trans/cis is not less than 75/25.

    摘要翻译： 本发明涉及对鱼类和哺乳动物具有低毒性的杀虫组合物，其特征在于含有反式或反式富含2,2-二甲基-3-（2,2-二氯乙烯基）丙基间苯二酚的间 - （对溴苯氧基） 式（I）的环丙烷羧酸酯，（I）和至少一种式（II）的有机磷酸酯，其中R 1和R 2各自是C 1 -C 3烷基， X1，X2和X3各自为氧或硫原子，Y1和Y2可以相同或不同，分别为C1-C3低级烷基，甲基巯基，氰基或硝基或卤素原子，Z为碳或 氮原子，n为0或1，前者与前者的比例为1〜1-100（重量份），通过将所述组合物与载体或稀释剂混合而得到的杀虫剂，根据需要添加剂。 术语“富含”表示反式/顺式的比例不小于75/25。

    Novel cyclopropanecarboxylates
    3.
    发明授权
    Novel cyclopropanecarboxylates 失效
    新型环丙烷羧酸酯

    公开(公告)号：US4003945A

    公开(公告)日：1977-01-18

    申请号：US461029

    申请日：1974-04-15

    申请人： Shigeyoshi Kitamura ,  Nobushige Itaya ,  Yoshitoshi Okuno ,  Nobuo Ohno ,  Takashi Matsuo ,  Masachika Hirano ,  Toshio Mizutani ,  Hisami Takeda

    发明人： Shigeyoshi Kitamura ,  Nobushige Itaya ,  Yoshitoshi Okuno ,  Nobuo Ohno ,  Takashi Matsuo ,  Masachika Hirano ,  Toshio Mizutani ,  Hisami Takeda

    IPC分类号： C07C69/743 ,  A01N53/10 ,  C07C69/74 ,  C07D307/28 ,  C07D307/45 ,  C07D309/06 ,  C07D309/22 ,  C07D317/54 ,  C07D333/16

    CPC分类号： C07D307/42 ,  C07C403/12 ,  C07D307/28 ,  C07D309/06 ,  C07D309/22 ,  C07D317/54 ,  C07D333/16 ,  C07C2101/02 ,  C07C2101/08 ,  C07C2101/14 ,  C07C2101/16 ,  Y10S514/937 ,  Y10S514/952 ,  Y10S514/953 ,  Y10S514/957

    摘要： Novel alkynylcyclopropanecarboxylic acid esters represented by the formula, ##STR1## wherein R.sub.1 represents hydrogen, halogen, lower alkyl having up to 5 carbon atoms, lower alkenyl having up to 5 carbon atoms, lower alkynyl having up to 5 carbon atoms, C.sub.1 -C.sub.4 alkoxy C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkylthio C.sub.1 -C.sub.4 alkyl, aryl, aryl C.sub.1 -C.sub.4 alkyl, furyl, substituted furyl, thienyl, substituted thienyl, furfuryl, substituted furfuryl, thenyl, substituted thenyl, cyclo C.sub.3 -C.sub.6 alkyl, substituted cyclo C.sub.3 -C.sub.6 alkyl, cyclo C.sub.3 -C.sub.6 alkenyl or substituted cyclo C.sub.3 -C.sub.6 alkenyl; R.sub.2 and R.sub.3 individually represent hydrogen, halogen, lower alkyl having up to 5 carbon atoms, lower alkenyl having up to 5 carbon atoms, lower alkynyl having up to 5 carbon atoms, aryl, aryl C.sub.1 -C.sub.4 alkyl or may form a carbon-carbon bond; or R.sub.1 and R.sub.3 are bonded to each other at the ends to form a polymethylene chain containing or not containing an oxygen or a sulfur atom, or R.sub.1 and R.sub.2 are bonded to each other at the ends to form a polymethylene chain containing or not containing an oxygen or a sulfur atom; R.sub.4 represents hydrogen or methyl; R.sub.5 represents hydrogen, methyl, vinyl, 1-propenyl, 2-methyl-1-propenyl, 2-methoxymethyl-1-propenyl, 2-methoxycarbonyl-1-propenyl, 2,2-dichlorovinyl or cyclopentyl-idenemethyl when R.sub.4 is hydrogen, and R.sub.5 represents methyl when R.sub.4 is methyl; and R.sub.6 and R.sub.7 represent hydrogen or methyl. These novel esters are produced by reacting an alcohol or its halide or arylsulfonate of the formula, ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.6 are defined above, and A is hydroxy, halogen or arylsulfoxy, with a cyclopropane-carboxylic acid of the formula, ##STR3## wherein R.sub.4, R.sub.5 and R.sub.7 are as defined above, or its reactive derivative. These esters are useful as an insecticide harmless to mammals.

    摘要翻译： 由式表示的新型炔基环丙烷羧酸酯，其中R 1表示氢，卤素，具有至多5个碳原子的低级烷基，具有至多5个碳原子的低级链烯基，低至5个碳原子的低级炔基，C1-C4烷氧基 C 1 -C 4烷基，C 1 -C 4烷硫基C 1 -C 4烷基，芳基，芳基C 1 -C 4烷基，呋喃基，取代的呋喃基，噻吩基，取代的噻吩基，糠基，取代的糠基，噻吩基，取代的芳基，环C 3 -C 6烷基，取代的环 C 3 -C 6烷基，环C 3 -C 6烯基或取代的环C 3 -C 6烯基; R 2和R 3各自表示氢，卤素，具有至多5个碳原子的低级烷基，具有至多5个碳原子的低级链烯基，具有至多5个碳原子的低级炔基，芳基，芳基C 1 -C 4烷基或可形成碳 - 碳 键; 或者R 1和R 3在末端彼此键合以形成含有或不含有氧原子或硫原子的多亚甲基链，或者R 1和R 2在末端彼此结合形成含有或不含有 氧或硫原子; R4代表氢或甲基; 当R4为氢时，R5代表氢，甲基，乙烯基，1-丙烯基，2-甲基-1-丙烯基，2-甲氧基甲基-1-丙烯基，2-甲氧基羰基-1-丙烯基，2,2-二氯乙烯基或环戊基 - 当R 4为甲基时，R 5表示甲基; 并且R 6和R 7表示氢或甲基。 这些新型酯通过使下式的醇或其卤化物或芳基磺酸盐与其中R1，R2，R3和R6定义如上，A是羟基，卤素或芳基磺酰基的醇或其卤化物或芳基磺酸酯与 式，其中R 4，R 5和R 7如上所定义，或其反应性衍生物。 这些酯可用作对哺乳动物无害的杀虫剂。

    Thio(dithio)phosphorates
    5.
    发明授权
    Thio(dithio)phosphorates 失效
    硫（二硫）磷酸盐

    公开(公告)号：US3953546A

    公开(公告)日：1976-04-27

    申请号：US487670

    申请日：1974-07-11

    申请人： Masachika Hirano ,  Kunio Mukai ,  Hisami Takeda

    发明人： Masachika Hirano ,  Kunio Mukai ,  Hisami Takeda

    IPC分类号： A01N57/14 ,  C07F9/18 ,  A01N9/36

    CPC分类号： A01N57/14 ,  C07F9/18

    摘要： Thio(dithio)-phosphorate of the formula, ##SPC1##Wherein A represents an alkyl having up to 6 carbon atoms; B represents lower alkyl having up to 4 carbon atoms; Y represents halogen, methoxy or ethoxy; X represents oxygen or sulfur; R.sub.1 represents alkyl having up to 6 carbon atoms, phenyl, phenyl substituted by halogen or phenyl substituted by lower alkyl having up to 4 carbon atoms; R.sub.2 represents hydrogen or alkyl having up to 6 carbon atoms; R.sub.3 represents hydrogen or alkyl having up to 6 carbon atoms; and n represents 0, 1 or 2, which is useful as a pesticide.

    摘要翻译： 硫代（二硫代） - 磷酸酯，其中A代表具有至多6个碳原子的烷基; B代表具有至多4个碳原子的低级烷基; Y表示卤素，甲氧基或乙氧基; X表示氧或硫; R 1表示具有至多6个碳原子的烷基，苯基，被卤素取代的苯基或被具有至多4个碳原子的低级烷基取代的苯基; R2代表氢或具有至多6个碳原子的烷基; R3表示氢或具有至多6个碳原子的烷基; n表示0,1或2，可用作农药。

    Amide phosphorothiolate derivatives and their use as pesticides
    9.
    发明授权
    Amide phosphorothiolate derivatives and their use as pesticides 失效
    酰胺二硫代磷酸衍生物及其作为农药的用途

    公开(公告)号：US4394379A

    公开(公告)日：1983-07-19

    申请号：US113133

    申请日：1980-01-17

    申请人： Osamu Kirino ,  Masachika Hirano ,  Hisami Takeda ,  Toshiro Kato

    发明人： Osamu Kirino ,  Masachika Hirano ,  Hisami Takeda ,  Toshiro Kato

    IPC分类号： A01N57/14 ,  A01N57/30 ,  C07F9/165 ,  C07F9/24 ,  C07F9/40

    CPC分类号： C07F9/1651 ,  A01N57/14 ,  A01N57/30 ,  C07F9/2408

    摘要： Amide phosphorothiolate derivatives of the formula, ##STR1## wherein X is an oxygen or sulfur atom, Y is an oxygen or sulfur atom or imino group, R.sub.1 and R.sub.2, which may be the same or different, are each a C.sub.1 -C.sub.3 alkyl group, R.sub.3 is a C.sub.1 -C.sub.4 alkyl group, R.sub.4 is a hydrogen atom or methyl group, R.sub.5 is a C.sub.1 -C.sub.3 alkyl, methoxy or ethoxy group, Z is a hydrogen atom, a methyl group or chlorine atom and n is 1 or 2, a process for producing said derivatives characterized by reacting the salt of thiophosphoric ester represented by the formula, ##STR2## wherein X, Y, R.sub.1 and R.sub.2 are as defined above and M is a sodium or potassium atom or ammonium group, with a haloacetamide derivative of the formula, ##STR3## wherein R.sub.3, R.sub.4, R.sub.5, Z and n are as defined above and W is a halogen atom, and a combined insecticide, acaricide, nematocide and/or fungicide containing said derivatives as an active ingredient.

    摘要翻译： 下式的酰亚胺硫代衍生物，其中X是氧或硫原子，Y是氧或硫原子或亚氨基，可以相同或不同的R 1和R 2各自为C 1 -C 3烷基 R3为C1-C4烷基，R4为氢原子或甲基，R5为C1-C3烷基，甲氧基或乙氧基，Z为氢原子，甲基或氯原子，n为1或2 制备所述衍生物的方法，其特征在于使由下式表示的硫代磷酸酯的盐，其中X，Y，R 1和R 2如上所定义，M是钠或钾原子或铵基，与卤代乙酰胺 衍生物，其中R3，R4，R5，Z和n如上所定义，W是卤素原子，以及含有所述衍生物作为活性成分的杀虫剂，杀螨剂，杀线虫剂和/或杀真菌剂的组合物。

    Insecticidal and acaricidal 3,5-dioxo-2,3,4,5-triazine compounds
    10.
    发明授权
    Insecticidal and acaricidal 3,5-dioxo-2,3,4,5-triazine compounds 失效
    杀虫剂和杀螨剂3,5-二氧代-2,3,4,5-三嗪化合物

    公开(公告)号：US4327094A

    公开(公告)日：1982-04-27

    申请号：US225749

    申请日：1981-01-16

    申请人： Masato Mizutani ,  Kazunori Tsushima ,  Yuzuru Sanemitsu ,  Masachika Hirano

    发明人： Masato Mizutani ,  Kazunori Tsushima ,  Yuzuru Sanemitsu ,  Masachika Hirano

    IPC分类号： A01N43/707 ,  A01N53/00 ,  A01N53/04 ,  C07D253/075 ,  C07D253/06 ,  A01N43/64

    CPC分类号： C07D253/075 ,  A01N43/707 ,  A01N53/00

    摘要： A carboxylate of the formula, ##STR1## wherein R.sub.1 is an allyl or propargyl group, R.sub.2 is a group of ##STR2## in which R.sub.3 is a hydrogen atom or a methyl group, and when R.sub.3 is a hydrogen atom, R.sub.4 is a group of ##STR3## (in which R.sub.7 is a chlorine, bromine or fluorine atom, or a methyl, vinyl, methoxycarbonyl or methoxymethyl group, R.sub.8 is a hydrogen, chlorine, bromine or fluorine atom or a methyl group), and when R.sub.3 is a methyl group, R.sub.4 is a methyl group, R.sub.5 is an isopropyl or cyclopropyl group, R.sub.6 is an alkyl group having 1 to 3 carbon atoms or alkoxy group having 1 to 3 carbon atoms, or a chlorine, bromine or fluorine atom, n is 1 or 2, and --(R.sub.6).sub.n may include a 3,4-methylenedioxy group, and its use as an insecticide and/or acaricide.

    摘要翻译： 下式的羧酸酯，其中R 1是烯丙基或炔丙基，R 2是其中R 3是氢原子或甲基的“IMAGE”基团，当R 3是氢原子时，R 4是基团 的化合物（其中R 7为氯，溴或氟原子，或甲基，乙烯基，甲氧基羰基或甲氧基甲基，R 8为氢，氯，溴或氟原子或甲基），当R 3为 甲基，R4为甲基，R5为异丙基或环丙基，R6为碳原子数1〜3的烷基或碳原子数1〜3的烷氧基，或氯，溴或氟原子，n为1 或（2）， - （R6）n可以包括3,4-亚甲二氧基，以及其作为杀虫剂和/或杀螨剂的用途。