摘要:
Aromatic amines and iron oxide pigment are produced by reacting a ferrous salt, a reduceable aromatic nitrogen compound chosen from nitroderivatives with a single nitro-group or with two nitro-groups and azoderivatives, and a basic compound, chosen from hydroxides and carbonates of ammonium, alkali metals and alkaline earth metals, operating at 25.degree.-200.degree. C. in an aqueous medium. The color of the pigment can be varied from yellow to black by increasing the reaction temperature and the molar ratio between ferrous salt and aromatic nitrogen compound.
摘要:
A soil modifier comprising from 80 to 95% by weight of a mixture of ferric oxide and ferric sulphate in an oxide/sulphate weight ratio of from 0.25:1 to 1:1, is prepared by calcining at 500.degree.-600.degree. C in an oxidizing atmosphere a blend of by-product obtained in the manufacture of titanium oxide by the sulphate process, with at least 20% by weight with respect to said by-product, of a material based on ferric sulphate and/or ferric oxide. Calcining is then continued under the same conditions, replacing said material in the blend continuously fed in by a recycle fraction of the product continuously discharged.
摘要:
Method of extracting magnesium sulphate from mixtures constituted essentially of magnesium sulphate heptahydrate and sodium chloride by means of heat treatment, grinding and dry grading.
摘要:
Novel compositions for use in agriculture as soil improvers and fertilizers comprising as essential components ammonium sulfate and ferric oxide hydrate. By-products obtained in the production of titanium dioxide from ilmenite or ilmenite slag in the sulfate process and substantially consisting of ferrous sulfate heptahydrate are reacted with ammonia and that the reaction product obtained, consisting substantially of ammonium sulfate and ferrous hydrate, is subsequently oxidized until a composition is obtained which substantially consists of ammonium sulfate and ferric oxide hydrate.
摘要:
Ferrous sulphate heptahydrate obtained as a by-product of the production of titanium dioxide by the sulphate process is converted into a non-polluting, free-flowing particulate neutralization product by contacting said sulphate with calcium hydroxide as a neutralizing agent in a molar ratio between said neutralizing agent and said ferrous sulphate of at least 1:1, and reacting the resulting mixture under agitation at a temperature not exceeding 60.degree. C. and for a contact time not exceeding five minutes.
摘要:
Process for the purification of titanium tetrachloride, in which the said titanium tetrachloride is brought into contact with a purifying agent consisting of an inert support in granular form on which metallic sodium or other reducing metal has been deposited in sub-divided form, the said contact taking place either on crude liquid titanium tetrachloride with subsequent distillation to recover the purified titanium tetrachloride or on crude vaporised titanium tetrachloride with subsequent condensation to recover the purified titanium tetrachloride.
摘要:
A soil modifying composition and a concentrated solution of ammonium sulphate with a high purity degree are obtained from by-products consisting essentially of ferrous sulphate heptahydrate, obtained in the production of titanium dioxide from ilmenites by the sulphate process, by contacting solid particles of said by-products with gaseous ammonia, lixiviating the resulting product with water, thereby to recover said concentrated solution of ammonium sulphate, the dried residual solid yielding said soil modifying composition.
摘要:
Titanium dioxide is post-treated by flowing it in a tubular zone as a suspension in a stream of carrier gas, injecting a gaseous stream of halides of Si, Ti and Al in said stream and then steam in the resulting mixture, once the latter is homogenized.
摘要:
Soil modifiers comprising from 80 to 95% by weight of a mixture of ferric oxide and ferric sulphate in an oxide/sulphate weight ratio of from 0.2:1 to 2:1 are prepared by calcining at 500.degree.-600.degree. C in the presence of an oxidizing gas a material consisting essentially of ferrous sulphate with an average number of molecules of crystallization of from 1 to 5 obtained by partial dehydration of the waste materials, consisting essentially of ferrous sulphate heptahydrate, obtained in the manufacture of titanium dioxide from ilmenites or ilmenite slags by the sulphate process. These modifiers are particularly suitable for clay soils.