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公开(公告)号：US4430247A
公开(公告)日：1984-02-07
申请号：US837935
申请日：1977-09-29
CPC分类号： C08G18/50 , C08G18/48 , C08G65/2612 , C08G65/2639 , C08G65/269
摘要： An oxyalkylated product useful for making polyurethane foams is prepared by reacting an alkylene oxide with a heated mixture of a phenol and a non-phenolic active hydrogen compound, at least one of which can be halogenated, in the presence of a catalyst complex of a phenol and an iron or aluminum substance. The mixture can also include a neutral phosphorus compound and/or acid anhydrides to enhance flame retardant properties. Optionally, also, the oxyalkylation reaction can be terminated by adding a tri (lower alkyl) amine and alkylene oxide to react with residual phenolic hydrogen in the mixture.
摘要翻译： 可用于制备聚氨酯泡沫的烷氧基化产物是通过使烯化氧与苯酚和非酚类活性氢化合物的加热混合物（其中至少一种可以被卤化）在酚的催化剂络合物 和铁或铝物质。 混合物还可以包括中性磷化合物和/或酸酐以增强阻燃性能。 任选地，也可以通过加入三（低级烷基）胺和烯化氧与混合物中残留的酚氢反应来终止烷氧基化反应。
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公开(公告)号：US4187357A
公开(公告)日：1980-02-05
申请号：US895989
申请日：1978-04-13
CPC分类号： C07F9/08 , C08G18/48 , C08G18/50 , C08G65/2612 , C08G65/2639
摘要： An oxyalkylated product useful for making polyurethane foams is prepared by reacting an alkylene oxide with a heated mixture of a phenol and a non-phenolic active hydrogen compound, at least one of which can be halogenated, in the presence of a catalyst complex of a phenol and an iron or aluminum substance. The mixture can also include a neutral phosphorus compound and/or acid anhydrides to enhance flame retardant properties. Optionally, also, the oxyalkylation reaction can be terminated by adding a tri (lower alkyl) amine and alkylene oxide to react with residual phenolic hydrogen in the mixture.
摘要翻译： 可用于制备聚氨酯泡沫的烷氧基化产物是通过使烯化氧与苯酚和非酚类活性氢化合物的加热混合物（其中至少一种可以被卤化）在酚的催化剂络合物 和铁或铝物质。 混合物还可以包括中性磷化合物和/或酸酐以增强阻燃性能。 任选地，也可以通过加入三（低级烷基）胺和烯化氧与混合物中残留的酚氢反应来终止烷氧基化反应。
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公开(公告)号：US4144395A
公开(公告)日：1979-03-13
申请号：US857072
申请日：1977-12-05
申请人： John R. Murphy , Louis C. Pizzini
发明人： John R. Murphy , Louis C. Pizzini
IPC分类号： C07C67/08 , C08G63/676 , C08G65/28 , C07C69/60
CPC分类号： C08G63/676 , C07C67/08
摘要： Polyether-ester polyols are prepared in the presence of from 0.005 percent to 0.01 percent by weight (50-100 ppm) of a trialkylamine. The resulting polyols have improved color and are obtained in markedly reduced reaction times.
摘要翻译： 聚醚酯多元醇在0.005％至0.01％（重量）（50-100ppm）三烷基胺的存在下制备。 所得多元醇具有改善的颜色，并且在显着缩短的反应时间中获得。
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公开(公告)号：US4105597A
公开(公告)日：1978-08-08
申请号：US824279
申请日：1977-08-15
CPC分类号： C08G18/48 , C08G18/50 , C08G65/2612 , C08G65/269
摘要： An oxyalkylated product useful for making polyurethane foams is prepared by reacting an alkylene oxide with a heated mixture of a phenol and a non-phenolic active hydrogen compound, at least one of which can be halogenated, in the presence of a catalyst complex of a phenol and an iron or aluminum substance. The mixture can also include a neutral phosphorus compound and/or acid anhydrides to enhance flame retardant properties. Optionally, also, the oxyalkylation reaction can be terminated by adding a tri (lower alkyl) amine and alkylene oxide to react with residual phenolic hydrogen in the mixture.
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5.发明授权
公开(公告)号：US3957922A
公开(公告)日：1976-05-18
申请号：US425524
申请日：1973-12-17
CPC分类号： C07F9/08 , C08G18/48 , C08G18/50 , C08G65/2612 , C08G65/2639
摘要： An oxyalkylated product useful for making polyurethane foams is prepared by reacting an alkylene oxide with a heated mixture of a phenol and a non-phenolic active hydrogen compound, at least one of which can be halogenated, in the presence of a catalyst complex of a phenol and an iron or aluminum substance. The mixture can also include a neutral phosphorus compound and/or acid anhydrides to enhance flame retardant properties. Optionally, also, the oxyalkylation reaction can be terminated by adding a tri (lower alkyl) amine and alkylene oxide to react with residual phenolic hydrogen in the mixture.
摘要翻译： 可用于制备聚氨酯泡沫的烷氧基化产物是通过使烯化氧与苯酚和非酚类活性氢化合物的加热混合物（其中至少一种可以被卤化）在酚的催化剂络合物 和铁或铝物质。 混合物还可以包括中性磷化合物和/或酸酐以增强阻燃性能。 任选地，也可以通过加入三（低级烷基）胺和烯化氧与混合物中残留的酚氢反应来终止烷氧基化反应。
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公开(公告)号：US3931092A
公开(公告)日：1976-01-06
申请号：US465234
申请日：1974-04-29
IPC分类号： C08F2/00 , C08F2/04 , C08F2/06 , C08F2/08 , C08F4/00 , C08F246/00 , C08F290/00 , C08F299/00 , C08F216/02 , C08F2/12 , C08F267/06
CPC分类号： C08F246/00 , C08F299/00
摘要： Finely-divided dispersed solids are prepared by polymerizing in the presence of a free radical catalyst and an organic solvent a major amount of an ethylenically unsaturated monomer or mixture of monomers and a minor amount of a hydroxy-terminated organic compound having from one to eight hydroxyl groups, an equivalent weight of from 500 to 10,000 and containing a polymerizable carbon-to-carbon double bond. The resulting polymeric solids are particularly useful in the preparation of reinforced polymer compositions.
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7.再颁专利Highly-stable graft copolymer dispersions in polyols containing unsaturation and polyurethanes prepared therefrom 失效高度稳定的接枝共聚物分散体含有不饱和的多元醇和由其制备的聚氨酯
公开(公告)号：USRE29014E
公开(公告)日：1976-10-26
申请号：US607134
申请日：1975-08-25
IPC分类号： C08F290/14
CPC分类号： C08F290/14
摘要： Highly-stable graft copolymer dispersions are prepared by the in situ polymerization in the presence of a free radical catalyst of a vinyl monomer in a polyol containing an essential amount of unsaturation. The dispersions are low-viscous liquids which may be advantageously employed in the preparation of flexible urethane foams having enhanced load-bearing properties.
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公开(公告)号：US3966521A
公开(公告)日：1976-06-29
申请号：US587476
申请日：1975-06-16
CPC分类号： B32B27/40 , C08G18/63 , C08G18/635 , C08G18/638 , C08G18/6795 , C08J5/121 , Y10S521/918 , Y10T428/249992
摘要： Composites based on polyurethane foams heat sealed to a substrate are prepared from polyurethane foams employing a graft polyol as a component of the foam-forming reaction mixture. The resulting composites possess exceptional bonding strength.
摘要翻译： 使用热塑性密封于基材的聚氨酯泡沫的复合材料由聚氨酯泡沫塑料制成，该聚氨酯泡沫使用接枝多元醇作为泡沫形成反应混合物的组分。 所得复合材料具有优异的粘结强度。
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9.发明授权
公开(公告)号：US3953393A
公开(公告)日：1976-04-27
申请号：US431081
申请日：1974-01-07
CPC分类号： C08G18/635 , C08F290/14
摘要： Graft copolymer dispersions of improved viscosity and superior particle size distribution are prepared by the in situ polymerization of vinyl monomers in unsaturation-containing polyols in the presence of a free-radical catalyst and certain chain transferring agents at temperatures below 100.degree. C. The dispersions are low viscous liquids which may be advantageously employed in the preparation of polyurethanes.
摘要翻译： 在自由基催化剂和某些链转移剂存在下，在低于100℃的温度下，通过乙烯基单体在不饱和含量的多元醇中的原位聚合制备了改进的粘度和优异的粒度分布的接枝共聚物分散体。 可以有利地用于制备聚氨酯的低粘度液体。
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10.发明授权Polyurethane foams prepared from condensation products of amines, epihalohydrins and alkylene oxides 失效由胺，表卤代醇和烯化氧的缩合产物制备的聚氨酯泡沫
公开(公告)号：US4133780A
公开(公告)日：1979-01-09
申请号：US806567
申请日：1977-06-14
CPC分类号： C08G18/5021
摘要： Oxyalkylated condensation products prepared from aliphatic and aromatic amines, epihalohydrin and alkylene oxides are used in the preparation of polyurethane foams.
摘要翻译： 由脂族和芳族胺，表卤代醇和环氧烷制备的烷基化缩合产物用于制备聚氨酯泡沫体。
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