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    Catalysts for reaction between an isocyanate and an alcohol
    3.
    发明授权
    Catalysts for reaction between an isocyanate and an alcohol 有权
    异氰酸酯与醇反应的催化剂

    公开(公告)号：US08816036B2

    公开(公告)日：2014-08-26

    申请号：US13123972

    申请日：2009-10-12

    申请人： Christian Maliverney ,  Laurent Saint-Jalmes

    发明人： Christian Maliverney ,  Laurent Saint-Jalmes

    IPC分类号： C08G18/22 ,  C08G18/42 ,  C07C269/02 ,  C08J9/04 ,  C08J9/08

    CPC分类号： C08G18/48 ,  B01J31/1805 ,  B01J31/2234 ,  B01J2231/34 ,  B01J2531/26 ,  C08G18/10 ,  C08G18/222 ,  C08G18/2825

    摘要： Catalysts, which are free of tin, are described which are useful in the reaction between an isocyanate and an alcohol, which is a key step for preparing polyurethane polymers. The catalyst is a metal complex or salt of formula (1): [Zn(L1)l1(L2)l2(Y)x]  (1) in which: l1≧1 and l2=0 or 1; with l1+l2=2, x=1 or 2, the symbol L1 represents a ligand which is a β-dicarbonylato anion or the enolate anion of a β-dicarbonyl compound or an acetylacetato anion derived from a β-ketoester, when l1=2, the symbols L1 are identical or different, the symbol L2 represents an anionic ligand which is different from L1, and the symbol Y represents a neutral ligand; where the metal complex or salt C of formula (1) is not zinc diacetylacetonate.

    摘要翻译： 描述了不含锡的催化剂，其可用于异氰酸酯和醇之间的反应，这是制备聚氨酯聚合物的关键步骤。 催化剂是式（1）的金属络合物或盐：[Zn（L1）11（L2）12（Y）x]（1）其中：l1≥1和l2 = 0或1; 其中l1 + l2 = 2，x = 1或2，符号L1表示一种配体，它是一种“二羰基”阴离子，或者是衍生自α-酮基的二羰基化合物或乙酰乙酰阴离子的烯醇化物阴离子， 当l1 = 2时，符号L1相同或不同，符号L2表示与L1不同的阴离子配体，符号Y表示中性配体; 其中式（1）的金属络合物或盐C不是二乙酰丙酮酸锌。

    Method For Preparation Of A Fluoroaromatic Compound From An Aminoaromatic Compound
    8.
    发明申请
    Method For Preparation Of A Fluoroaromatic Compound From An Aminoaromatic Compound 审中-公开
    从氨基芳香化合物制备氟芳族化合物的方法

    公开(公告)号：US20070276168A1

    公开(公告)日：2007-11-29

    申请号：US10588471

    申请日：2005-02-03

    申请人： Laurent Garel ,  Laurent Saint-Jalmes

    发明人： Laurent Garel ,  Laurent Saint-Jalmes

    IPC分类号： C07C25/13

    CPC分类号： C07B39/00 ,  C07C17/093 ,  C07C25/13 ,  C07D213/61 ,  C07D215/18 ,  C07D215/20

    摘要： The invention relates to a method for preparation of fluorinated aromatic compounds from the corresponding amines by replacement of the amino group with a fluorine atom. The method of preparation of a fluoroaromatic compound from an aromatic compound with at least one amino group on the aromatic ring is characterized by the reaction of said aromatic amine compound with a nitrosating agent in the presence of a source of boron trifluoride in an organic medium, and carrying out a thermal treatment of the reaction medium comprising the diazonium salt thus obtained to give the fluoroaromatic compound directly by decomposition of the diazonium salt without intermediate isolation thereof.

    摘要翻译： 本发明涉及通过用氟原子取代氨基从相应的胺制备含氟芳族化合物的方法。 芳族化合物与芳族化合物在芳环上具有至少一个氨基的氟代芳族化合物的制备方法的特征在于，在有机介质中存在三氟化硼的情况下，所述芳族胺化合物与亚硝化剂反应， 并对由此获得的包含重氮盐的反应介质进行热处理，直接通过分解重氮盐直接得到氟代芳族化合物，而无需中间分离。

    Chlorination of an aniline in a hydrofluoric medium
    9.
    发明授权
    Chlorination of an aniline in a hydrofluoric medium 失效
    在氢氟酸介质中氯化苯胺

    公开(公告)号：US06747175B2

    公开(公告)日：2004-06-08

    申请号：US10204942

    申请日：2002-10-21

    申请人： Hubert Kempf ,  Gilbert Guidot ,  Laurent Saint-Jalmes

    发明人： Hubert Kempf ,  Gilbert Guidot ,  Laurent Saint-Jalmes

    IPC分类号： C07C20974

    CPC分类号： C07D231/12 ,  C07C209/74 ,  C07C211/52

    摘要： The invention concerns a method for the synthesis of chlorinated aniline on the ring and comprising at least a sp3 hybridization carbon atom both perhalogenated and bearing a fluorine atom. Said method is characterized in that it comprises a step which consists in chlorinating a precursor aniline of said chlorinated aniline, said chlorination being carried out in a hydrofluoric medium capable of exchanging chlorine and fluorine in benzyl position. The invention is useful for the synthesis of organofluorinated and/or chlorinated compounds.

    摘要翻译： 本发明涉及一种在环上合成氯化苯胺的方法，它包含至少一个全卤代和带有氟原子的sp3杂交碳原子。 所述方法的特征在于它包括将所述氯化苯胺的前体苯胺氯化的步骤，所述氯化在能够在苄基位置交换氯和氟的氢氟酸介质中进行。 本发明可用于合成有机氟化和/或氯化化合物。

    Reagent and process for the synthesis of oxysulphide-containing fluorine-containing organic derivatives
    10.
    发明授权
    Reagent and process for the synthesis of oxysulphide-containing fluorine-containing organic derivatives 失效
    用于合成含氧硫化物的含氟有机衍生物的试剂和方法

    公开(公告)号：US5859288A

    公开(公告)日：1999-01-12

    申请号：US620359

    申请日：1996-03-22

    申请人： Gerard Forat ,  Jean-Manuel Mas ,  Laurent Saint-Jalmes

    发明人： Gerard Forat ,  Jean-Manuel Mas ,  Laurent Saint-Jalmes

    IPC分类号： C07B45/04 ,  C07C303/02 ,  C07C303/14 ,  C07C309/06 ,  C07C309/39 ,  C07C309/80 ,  C07C313/02 ,  C07C313/04

    CPC分类号： C07C303/02 ,  C07C313/04

    摘要： The invention relates to a reagent which is useful for the synthesis of oxysulphide-containing fluorine-containing organic derivatives by reacting with an oxide of sulphur, especially sulphur dioxide, characterized in that it comprises:a) a fluorocarboxylic acid of formula E.sub.w --CF.sub.2 --COOH where E.sub.w is an electron-withdrawing group or atom which is at least partially salified by an organic or inorganic cation, andb) an aprotic polar solvent; andin that the content of releasable protons carried by its various components, including their impurities, is at most equal to half the initial molar concentration of the said fluorocarboxylic acid.This reagent can be used by heating in order to form fluorine-containing sulphinic or sulphonic acids.

    摘要翻译： 本发明涉及一种用于通过与硫的氧化物，特别是二氧化硫反应来合成含氧硫化物的含氟有机衍生物的试剂，其特征在于它包括：a）式Ew-CF2-的氟代羧酸， COOH，其中Ew是吸电子基团或至少部分由有机或无机阳离子盐化的原子，和b）非质子极性溶剂; 并且由其各种组分（包括它们的杂质）携带的可释放质子的含量最多等于所述氟代羧酸的初始摩尔浓度的一半。 该试剂可以通过加热使用，以形成含氟亚磺酸或磺酸。