公开(公告)号：US4978789A

公开(公告)日：1990-12-18

申请号：US376929

申请日：1989-07-10

Applicant: Katsuo Taniguchi ,  Shigeki Fujikawa ,  Yoshito Kurano

Inventor： Katsuo Taniguchi ,  Shigeki Fujikawa ,  Yoshito Kurano

IPC: C07C37/00 ,  C07C209/68

CPC classification number: B01J23/862 ,  B01J23/825 ,  B01J23/835 ,  B01J23/8472 ,  B01J37/031 ,  C07C209/68 ,  C07C37/001 ,  B01J2523/00

Abstract: A process for producing an alkenyl substituted aromatic compound having the general formula (I): ##STR1## wherein Ar represents an aromatic ring, R.sup.1 represents an alkenyl group having 2 to 8 carbon atoms, p is 1, 2, or 3 provided that R.sup.1 may be the same or different when p is 2 or 3, R.sup.2 represents an alkyl group having 1 to 8 carbon atoms, q is 0, 1, or 2 provided that R.sup.2 may be the same or different when q is 2, X represents --OH or --NR.sup.3 R.sup.4 wherein R.sup.3 and R.sup.4 independently represent hydrogen or an alkyl group having 1 to 2 carbon atoms, n is 1 or 2, provided that the sum of p and q is 1, 2, or 3 comprising the step of catalytically dehydrogenating an alkyl substituted aromatic compound having the general formula (III): ##STR2## wherein R.sup.5 represents an alkyl group having 2 to 8 carbon atoms and Ar, R.sup.2, X, p, q, and n are the same as defined above, n is 1 or 2, provided that R.sup.5 may be the same or different when p is 2 or 3 in the presence of a catalyst comprising (a) at least one iron oxide as a main component and (b) at least one oxide of metals belonging to the group III, IV or V of the periodic table of atoms.This catalyst can produce an alkenyl substituted aromatic compound having a hydroxyl or amino group in the aromatic ring thereof from the dehydrogenation of the corresponding alkyl substituted aromatic compound at a high yield and high selectivity and has a prolonged catalyst life.

Abstract translation: 一种制备具有通式（I）的烯基取代的芳族化合物的方法：其中Ar表示芳族环，R 1表示具有2至8个碳原子的链烯基，p是1,2或3 条件是当p为2或3时，R 1可以相同或不同，R 2表示具有1至8个碳原子的烷基，q为0,1或2，条件是当q为2时，R 2可以相同或不同， X表示-OH或-NR 3 R 4，其中R 3和R 4独立地表示氢或具有1至2个碳原子的烷基，n为1或2，条件是p和q之和为1,2或3，包括步骤 催化脱氢具有通式（III）的烷基取代的芳族化合物：其中R 5表示具有2至8个碳原子的烷基，Ar，R 2，X，p，q和n与 n为1或2，条件是当催化剂存在时p为2或3时，R 5可以相同或不同，所述催化剂包含（a）至少一种i 氧化物作为主要成分，和（b）属于元素周期表第III，IV或V族的金属的至少一种氧化物。 该催化剂可以以高产率和高选择性从相应的烷基取代的芳族化合物的脱氢产生其芳环中具有羟基或氨基的烯基取代的芳族化合物，并具有延长的催化剂寿命。

公开(公告)号：US4891465A

公开(公告)日：1990-01-02

申请号：US221246

申请日：1988-07-06

Applicant: Katsuo Taniguchi ,  Michio Tanaka ,  Kazunori Takahata ,  Naoya Sakamoto ,  Toshihiro Takai ,  Yoshito Kurano ,  Masayasu Ishibashi

Inventor： Katsuo Taniguchi ,  Michio Tanaka ,  Kazunori Takahata ,  Naoya Sakamoto ,  Toshihiro Takai ,  Yoshito Kurano ,  Masayasu Ishibashi

IPC: B01J29/18 ,  B01J29/00 ,  C07B61/00 ,  C07C1/00 ,  C07C2/66 ,  C07C2/86 ,  C07C15/00 ,  C07C15/02 ,  C07C15/14 ,  C07C15/16 ,  C07C15/24 ,  C07C37/08 ,  C07C39/15 ,  C07C43/263 ,  C07C67/00 ,  C07C67/08

CPC classification number: C07C39/15 ,  C07C2/66 ,  C07C2/861 ,  C07C2/864 ,  C07C2529/18

Abstract: In a process for producing an alkyl group-substituted aromatic hydrocarbon according to the present invention, (i) an aromatic hydrocarbon is reacted with (ii) an alkylating agent selected from the group consisting of olefins, lower aliphatic alcohols and alkyl halides in the presence of a mordenite-type zeolite catalyst treated with a fluorine-containing compound, and therefore the conversion of the aromatic compound can be increased and further it is possible to introduce the specific number of alkyl groups into the specific position of the aromatic compound.In particular, when biphenyl is used as the aromatic hydrocarbon and propylene is used as the alkylating agent, p,p'-diisopropylbiphenyl can be obtained in a high yield and high selectivity.

公开(公告)号：US4675307A

公开(公告)日：1987-06-23

申请号：US826489

申请日：1986-01-23

Applicant: Katsuo Taniguchi ,  Tadaaki Fujimoto ,  Kenji Saeki

Inventor： Katsuo Taniguchi ,  Tadaaki Fujimoto ,  Kenji Saeki

IPC: B01J23/04 ,  B01J27/236 ,  C01F7/00 ,  C01G37/00 ,  C01G49/00 ,  C07C5/22 ,  C07C5/25 ,  B01J21/04 ,  B01J23/02 ,  B01J23/26 ,  B01J23/78

CPC classification number: C07C5/2556 ,  B01J23/04 ,  B01J27/236 ,  C01F7/005 ,  C01G37/006 ,  C01G49/009 ,  C07C5/226 ,  C01P2002/22 ,  C07C2523/04

Abstract: An alkali metal-supported substance comprising a calcination product of a hydrotalcite-like compound having Mg as a divalent metal and a carbonate ion as an anion and an alkali metal supported on the calcination product. When this substance is treated with a gas containing molecular oxygen, part of the alkali metal is converted to its oxide to give a more stable substance. These substances act, for example, as an isomerization catalyst for olefins.

Abstract translation: PCT No.PCT / JP85 / 00291 Sec。 371日期1986年1月23日 102（e）日期1986年1月23日PCT提交1985年5月28日PCT公布。 出版物WO85 / 05562 日本1985年12月19日。一种碱金属负载物质，其包含具有作为二价金属的Mg和作为阴离子的碳酸根离子的水滑石样化合物的煅烧产物和负载在煅烧产物上的碱金属。 当用含有分子氧的气体处理该物质时，将部分碱金属转化成其氧化物，得到更稳定的物质。 这些物质例如作为烯烃的异构化催化剂起作用。

公开(公告)号：US3931348A

公开(公告)日：1976-01-06

申请号：US427342

申请日：1973-12-21

Applicant: Katsuo Taniguchi ,  Shizunori Miyamoto ,  Hideto Matsuoka

Inventor： Katsuo Taniguchi ,  Shizunori Miyamoto ,  Hideto Matsuoka

IPC: B01J23/26 ,  B01J23/36 ,  C07C5/41 ,  C07C15/24

CPC classification number: C07C15/24 ,  B01J23/26 ,  B01J23/36 ,  C07C5/412

Abstract: A process for preparing dimethyl naphthalenes, which comprises heating a compound, such as methyl-4-(p-tolyl) butane, methyl-4-(p-tolyl)butene or methyl-4-(p-tolyl)butadiene, in the presence of a cyclization-dehydrogenation catalyst.

Abstract translation: 一种制备二甲基萘的方法，其包括将化合物如甲基-4-（对甲苯基）丁烷，甲基-4-（对甲苯基）丁烯或甲基-4-（对甲苯基）丁二烯）加热到 存在环化脱氢催化剂。

公开(公告)号：US4902837A

公开(公告)日：1990-02-20

申请号：US219151

申请日：1988-06-13

Applicant: Michio Tanaka ,  Yoshito Kurano ,  Katsuo Taniguchi

Inventor： Michio Tanaka ,  Yoshito Kurano ,  Katsuo Taniguchi

IPC: C07B61/00 ,  B01J23/02 ,  B01J31/00 ,  C07C27/00 ,  C07C37/11 ,  C07C39/15 ,  C07C41/00 ,  C07C43/295 ,  C07C67/00

CPC classification number: C07C37/11 ,  C07C37/07

Abstract: Processes for preparing biphenols by oxidation coupling of phenols, to which the present invention is directed, are characterized in that said oxidation coupling reaction is carried out under such conditions that the same diphenoquinones as those produced as by-products at the time when said oxidation coupling is effected are added to the reaction system. According to a preferred embodiment of the invention, moreover, the yield of biphenols can be enhanced by the reuse in the abovementioned reaction of diphenoquinones recovered from the reaction mixture containing the same.

公开(公告)号：US4351958A

公开(公告)日：1982-09-28

申请号：US297166

申请日：1981-08-28

Applicant: Kazunori Takahata ,  Katsuo Taniguchi

Inventor： Kazunori Takahata ,  Katsuo Taniguchi

IPC: C07C209/68 ,  C07C85/24

CPC classification number: C07C209/68

Abstract: An orthoalkylated aromatic amine is produced at a high selectivity from the reaction of an aromatic amine having at least one hydrogen atom at the ortho-positions and a primary or secondary alcohol under heating in the presence of a catalyst containing, as a main constituent, iron oxides.

Abstract translation: 在邻位上具有至少一个氢原子的芳族胺与原醇或仲醇在加热下，在含有作为主要成分的铁的催化剂存在下，以高选择性制备原烷基化芳族胺 氧化物。

公开(公告)号：US4900861A

公开(公告)日：1990-02-13

申请号：US254838

申请日：1988-10-07

Applicant: Keiichi Yokoyama ,  Katsuo Taniguchi ,  Yoshihisa Kiso

Inventor： Keiichi Yokoyama ,  Katsuo Taniguchi ,  Yoshihisa Kiso

IPC: C08G77/60

CPC classification number: C08G77/60

Abstract: A method of producing polysilane compounds which comprises: polymerizing a monomeric silane compound represented by the general formula of ##STR1## wherein R independently represents hydrogen or hydrocarbon group, but not both R's are hydrogen at the same time, in the presence of an organometallic complex of Ni, Co, Ru, Pd or Ir.

公开(公告)号：US4582944A

公开(公告)日：1986-04-15

申请号：US606611

申请日：1984-05-03

Applicant: Katsuo Taniguchi ,  Hideo Nakamura ,  Terunori Fujita

Inventor： Katsuo Taniguchi ,  Hideo Nakamura ,  Terunori Fujita

IPC: B01J27/00 ,  B01J27/12 ,  C07B61/00 ,  C07C41/00 ,  C07C41/09 ,  C07C43/295 ,  C07C67/00

CPC classification number: C07C41/09

Abstract: A process for producing a hydroxydiphenyl ether, which comprises reacting at least one hydroquinone compound with itself or with a monohydric phenol compound in the presence of a catalyst composed essentially of a synthetic mica in which at least 10 mole % of cation-exchangeable interlayer cations are made up of a metal ion other than alkali metal ions, and/or a proton.

Abstract translation: 一种生产羟基二苯醚的方法，其包括使至少一种氢醌化合物与其自身或与一元酚化合物在催化剂存在下反应，所述催化剂基本上由合成云母组成，其中至少10摩尔％的可阳离子交换的层间阳离子是 由除金属离子以外的金属离子和/或质子组成。

公开(公告)号：US5356561A

公开(公告)日：1994-10-18

申请号：US813032

申请日：1991-12-24

Applicant: Toyoji Shimizu ,  Shinichi Nishiyama ,  Nobuyuki Doi ,  Shoichi Miyakoshi ,  Tooru Yamanaka ,  Katsuo Taniguchi ,  Hideo Hama

Inventor： Toyoji Shimizu ,  Shinichi Nishiyama ,  Nobuyuki Doi ,  Shoichi Miyakoshi ,  Tooru Yamanaka ,  Katsuo Taniguchi ,  Hideo Hama

IPC: C07C69/757 ,  C07C69/773 ,  C07C69/90 ,  C09K19/02 ,  C09K19/32 ,  C07C69/76

CPC classification number: C09K19/0266 ,  C07C69/757 ,  C07C69/90 ,  C09K19/322 ,  C09K2019/325

Abstract: In accordance with the present invention, there are provided carboxylate compounds represented by the following formula [A] and liquid crystal material comprising said compounds ##STR1## wherein R is a group selected from the group consisting of alkyl, alkoxy and halogenated alkyl group of 3-20 carbon atoms, X and Y represent each a group selected from the group consisting of --COO--, --OCO--, --CH.sub.2 CH.sub.2 --, --CH.sub.2 O--, --OCH.sub.2 --, --S--S--, ##STR2## or a single bond, A and B represent each a group selected from the group consisting of specific divalent aromatic and alicyclic group such as phenylene, cyclohexylene and tetrahydronaphthalene and R* is an optically active group of 4-20 carbon atoms containing at least one asymmetric carbon atom (hydrogen atoms attached to the carbon atoms of said optically active group may be substituted with halogen atoms), and m and n are each an integer of 0-2, with the proviso that both m and n do not become 0 at the same time.

Abstract translation: 根据本发明，提供由下式[A]表示的羧酸酯化合物和包含所述化合物[A]的液晶材料，其中R是选自烷基，烷氧基和卤代烷基 3-20个碳原子的基团，X和Y各自表示选自-COO - ， - OCO - ， - CH 2 CH 2 - ， - CH 2 O - ， - OCH 2 - ，-SS-，或 单键，A和B分别表示选自亚苯基，亚环己基和四氢萘中的特定二价芳族和脂环族的基团，R *是含有至少一个不对称碳原子的4-20个碳原子的光学活性基团 （与所述光学活性基团的碳原子连接的氢原子可以被卤素原子取代），m和n分别为0-2的整数，条件是m和n两者不同时成为0 。

公开(公告)号：US5246622A

公开(公告)日：1993-09-21

申请号：US731978

申请日：1991-07-18

Applicant: Toyoji Shimizu ,  Katsuo Taniguchi ,  Shinichi Nishiyama ,  Shoichi Miyakoshi ,  Tooru Yamanaka ,  Nobuyuki Doi ,  Hideo Hama

Inventor： Toyoji Shimizu ,  Katsuo Taniguchi ,  Shinichi Nishiyama ,  Shoichi Miyakoshi ,  Tooru Yamanaka ,  Nobuyuki Doi ,  Hideo Hama

IPC: C09K19/02 ,  C09K19/28 ,  C09K19/30 ,  C09K19/32

CPC classification number: C09K19/0266 ,  C09K19/28 ,  C09K19/3068 ,  C09K19/322 ,  C09K2019/325

Abstract: The liquid crystal racemic mixture of the invention is represented by the formula [I]:Z--(X.A).sub.m (Y.B).sub.n COOR.sup.1 [I]wherein R1 is a specific group of alkyl, alkoxy or halogenated alkyl, X and Y are either one of the following group: --COO--, --OCO--, --CH.sub.2 CH.sub.2 --, --CH.sub.2 O--, --OCH.sub.2 --, --COCH.sub.2 --, --CH.sub.2 CO-- and --S--S--, or a single bond, A and B are each a specific bivalent group such as 1,4-phenylene group, Z is a group selected from the group consisting of ##STR1## (wherein R.sub.2 is an alkyl group, an alkoxy group or a halogenated alkyl group), and m and n are an integer of 0 to 2 (m and N not being simultaneously 0). The liquid crystal composition of the invention comprises the racemic mixture as described above. Moreover, the liquid crystal element of the invention comprises a liquid crystal material containing the liquid crystal racemic mixture as described above.