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公开(公告)号：US5266680A
公开(公告)日：1993-11-30
申请号：US905077
申请日：1992-06-24
申请人： Jerry O. Reed
发明人： Jerry O. Reed
CPC分类号： C08G75/0259 , C08G75/0281 , C08G75/0295 , Y10T428/31504 , Y10T428/31533
摘要： A method is provided for the production of poly(arylene sulfide) compositions comprisinga) contacting under suitable conditions a sulfur source, a dihalogenated aromatic compound and optionally other halogenated aromatic compounds, a polar organic compound, a base, and an alkali metal carboxylate in order to form a substantially liquid mixture comprising poly(arylene sulfide) polymer, polar organic compound and water;b) slowly cooling to form a slurry comprising solid poly(arylene sulfide) particles and liquid comprising the polar organic compound and water and adding an effective amount of at least one extraction agent;c) contacting the poly(arylene sulfide) particles with an aqueous solution containing calcium ions; andd) recovering the poly(arylene sulfide) composition.The poly(arylene sulfide) compositions prepared according to the invention method are especially useful for the preparation of fibers and monofilaments.
摘要翻译： 提供了一种用于制备聚（亚芳基硫醚）组合物的方法，其包括a）在合适的条件下使硫源，二卤化芳族化合物和任选的其它卤代芳族化合物，极性有机化合物，碱和碱金属羧酸盐接触 以形成包含聚（亚芳基硫醚）聚合物，极性有机化合物和水的基本上液体的混合物; b）缓慢冷却以形成包含固体聚（亚芳基硫醚）颗粒和包含极性有机化合物和水的液体并加入有效量的至少一种提取剂的浆料; c）使聚（亚芳基硫醚）颗粒与含有钙离子的水溶液接触; 和d）回收聚（亚芳基硫醚）组合物。 根据本发明方法制备的聚（亚芳基硫醚）组合物特别可用于制备纤维和单丝。
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2.发明授权
公开(公告)号：US5264176A
公开(公告)日：1993-11-23
申请号：US800905
申请日：1991-11-26
CPC分类号： C08G75/0254 , C08G75/024 , C08G75/0281
摘要： An aromatic sulfide/ketone polymer is prepared from a dihaloaromatic ketone, alkali metal sulfide, water and a polar organic compound. The polymerization reaction mixture is subjected to a heat soak at an elevated temperature, then a separation agent is added under controlled conditions and the mixture is subsequently cooled to provide a mixture comprising particulate aromatic sulfide/ketone polymer. Biaxially-oriented film is made from the recovered particles of aromatic sulfide/ketone polymer by (1) washing the polymer particles with an aqueous calcium salt, (2) heating the washed particles to remove water, (3) molding the heated particles to form a sheet of polymer, (4) biaxially stretching the sheet above the glass transition temperature of the polymer to form a film, and (5) heat-setting the biaxially-oriented film under stretching tension for a time and at a temperature to increase strength properties and density.
摘要翻译： 由二卤代芳族酮，碱金属硫化物，水和极性有机化合物制备芳族硫化物/酮聚合物。 将聚合反应混合物在升高的温度下进行热浸，然后在受控条件下加入分离剂，随后将混合物冷却以提供包含颗粒状芳族硫化物/酮聚合物的混合物。 通过（1）用钙盐水洗涤聚合物颗粒，（2）加热洗涤的颗粒以除去水，（3）将加热的颗粒成型形成，由回收的芳族硫化物/酮聚合物颗粒制成双轴取向膜 （4）将聚合物的玻璃化转变温度以上的双轴拉伸形成薄膜，（5）将拉伸张力下的双轴拉伸薄膜热固化一段时间，并使温度升高， 性质和密度。
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公开(公告)号：US4478969A
公开(公告)日：1984-10-23
申请号：US506949
申请日：1983-06-22
申请人： Jerry O. Reed , Ronald D. Mathis
发明人： Jerry O. Reed , Ronald D. Mathis
IPC分类号： C08K5/3472 , C08K5/34 , C08G75/14
CPC分类号： C08K5/3472
摘要： The heat stability of arylene sulfide resins, such as poly(p-phenylene sulfide) resin, is improved by the addition of cure retarders comprising an aminotriazole. The resin compositions of the invention are particularly applicable for reducing gel formation during melt extrusion.
摘要翻译： 通过加入包含氨基三唑的固化缓凝剂，改善了亚芳基硫醚树脂如聚对苯硫醚树脂的热稳定性。 本发明的树脂组合物特别适用于在熔融挤出过程中降低凝胶形成。
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公开(公告)号：US4445941A
公开(公告)日：1984-05-01
申请号：US401033
申请日：1982-07-22
申请人： Ronald D. Mathis , Jerry O. Reed
发明人： Ronald D. Mathis , Jerry O. Reed
CPC分类号： B29C47/0877 , C08G85/008 , C09D9/00 , C11D7/5022 , D01D4/04 , B29C47/0009 , B29C47/0014
摘要： A process for the removal of poly(arylene sulfide) deposits on metal surfaces is provided by contacting the deposit with at least one diaryl ether under temperature conditions and for a time sufficient to remove said poly(arylene sulfide) deposits. A process for the cleansing of metal parts having poly(arylene sulfide) deposits is also provided which comprises treatment with a diaryl ether, and thereafter contacting the ether treated part with an alcohol, washing the part with water, drying the part, and thereafter contacting the dried part with concentrated HNO.sub.3 followed by water washing and drying.
摘要翻译： 通过使沉积物与至少一种二芳基醚在温度条件下接触并足以除去所述聚（亚芳基硫化物）沉积物的时间来提供在金属表面上去除聚（亚芳基硫醚）沉积物的方法。 还提供了具有聚（亚芳基硫醚）沉积物的金属部件的清洁方法，其包括用二芳基醚处理，然后使乙醚处理的部分与醇接触，用水洗涤该部分，干燥该部件，然后接触 将干燥的部分用浓HNO 3洗涤，然后水洗和干燥。
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5.发明授权
公开(公告)号：US4435222A
公开(公告)日：1984-03-06
申请号：US403435
申请日：1982-07-30
申请人： Jerry O. Reed , Timothy W. Johnson
发明人： Jerry O. Reed , Timothy W. Johnson
CPC分类号： B29C47/0877 , C08G85/008 , C09D9/00 , D01D4/04 , B29C47/0009 , B29C47/0014
摘要： A process for removing poly(arylene sulfide) deposits from metal surfaces is provided which comprises contacting said deposits with a halogenated cleaning agent followed by contacting the remaining deposits with a solution of a aluminum halide in an aromatic hydrocarbon. In addition, a process for the cleansing of metal parts having poly(arylene sulfide) deposits is provided which comprises contacting the parts in a manner as described immediately above, and thereafter contacting the metal parts with a lower alkyl alcohol, washing the metal part with H.sub.2 O, drying the metal part, followed by treatment of the dried part with concentrated HNO.sub.3.
摘要翻译： 提供了从金属表面除去聚（亚芳基硫醚）沉积物的方法，其包括使所述沉积物与卤化清洁剂接触，然后将剩余的沉积物与卤化铝在芳族烃中的溶液接触。 另外，提供了一种用于清洁具有聚（亚芳基硫醚）沉积物的金属部件的方法，其包括以上述方式使部件接触，然后使金属部件与低级烷基醇接触，将金属部件与 H 2 O，干燥金属部分，然后用浓HNO 3处理干燥部分。
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6.发明授权
公开(公告)号：US4435221A
公开(公告)日：1984-03-06
申请号：US403434
申请日：1982-07-30
申请人： Ronald D. Mathis , Jerry O. Reed
发明人： Ronald D. Mathis , Jerry O. Reed
CPC分类号： B29C47/0877 , C08G85/008 , C09D9/00 , D01D4/04 , B29C47/0009 , B29C47/0014
摘要： A process for the removal of poly(arylene sulfide) deposits is provided which comprises contacting said deposits with a solution comprising an alkali metal hydrosulfide in a lactam. In addition, a process for the cleaning of metal parts having poly(arylene sulfide) deposits is provided by contacting the metal parts in the manner as described immediately above, contacting the metal part with a lower alkyl alcohol, washing said metal part with water, drying said metal part, contacting the dried part with concentrated HNO.sub.3 followed by water washing and drying.
摘要翻译： 提供了一种去除聚（亚芳基硫醚）沉积物的方法，其包括使所述沉积物与内酰胺中含有碱金属氢硫化物的溶液接触。 另外，通过使金属部件以上述方式接触金属部件与低级烷基醇接触来清洗具有聚（亚芳基硫醚）沉积物的金属部件的方法，用水洗涤所述金属部件， 干燥所述金属部分，使干燥部分与浓缩的HNO 3接触，然后水洗和干燥。
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公开(公告)号：US4418029A
公开(公告)日：1983-11-29
申请号：US376991
申请日：1982-05-11
申请人： Jerry O. Reed , Ronald D. Mathis
发明人： Jerry O. Reed , Ronald D. Mathis
摘要： The heat stability of arylene sulfide resins, such as poly(p-phenylene sulfide) resin, is improved by the addition of cure retarders comprising Group IIA or Group IIB metal salts of fatty acids. The resin compositions of the invention are particularly applicable for reducing gel formation during melt extrusion.
摘要翻译： 通过加入包含IIA族或IIB族IIB族脂肪酸金属盐的固化缓凝剂，可改进亚芳基硫醚树脂如聚对苯硫醚树脂的热稳定性。 本发明的树脂组合物特别适用于在熔融挤出过程中降低凝胶形成。
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公开(公告)号：US4405745A
公开(公告)日：1983-09-20
申请号：US422786
申请日：1982-09-24
申请人： Ronald D. Mathis , Jerry O. Reed
发明人： Ronald D. Mathis , Jerry O. Reed
CPC分类号： C08K3/28
摘要： The heat stability of arylene sulfide polymers, such as poly(p-phenylene sulfide), is improved by the addition of cure retarders comprising alkaline earth metal nitrites.
摘要翻译： 通过加入包含碱土金属亚硝酸盐的固化缓凝剂，改善了亚芳基硫醚聚合物如聚（对苯硫醚）的热稳定性。
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公开(公告)号：US4898904A
公开(公告)日：1990-02-06
申请号：US177255
申请日：1988-04-04
申请人： Michael C. Yu , Lacey E. Scoggins , Jerry O. Reed
发明人： Michael C. Yu , Lacey E. Scoggins , Jerry O. Reed
摘要： Poly(arylene sulfide) resins are modified by melt mixing a resin with a basic additive to form a resin product composition. The basic additive is selected from the group consisting of inorganic hydroxides, inorganic oxides and organic metal salts wherein the metals are from Group IA, IIA, or IIB and the salts are of carboxylic acids and phenols. The product compositions are suitable for injection molding, film forming and fiber spinning processes.
摘要翻译： 聚（亚芳基硫醚）树脂通过将树脂与碱性添加剂熔融混合而形成树脂产品组合物而进行改性。 碱性添加剂选自无机氢氧化物，无机氧化物和有机金属盐，其中金属来自IA，IIA或IIB族，其盐是羧酸和酚。 该产品组合物适用于注射成型，成膜和纤维纺丝工艺。
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公开(公告)号：US4543224A
公开(公告)日：1985-09-24
申请号：US576979
申请日：1984-02-03
申请人： Jerry O. Reed , Ronald D. Mathis
发明人： Jerry O. Reed , Ronald D. Mathis
摘要： The heat stability of arylene sulfide resins, such as poly(p-phenylene sulfide) resin, is improved by the addition of cure retarders comprising phenolic amide or ester-based antioxidants. The resin compositions of the invention are particularly applicable for reducing gel formation during melt extrusion.
摘要翻译： 通过加入包含酚酰胺或酯基抗氧化剂的固化缓凝剂，可改善亚芳基硫醚树脂（如聚对苯硫醚）树脂的热稳定性。 本发明的树脂组合物特别适用于在熔融挤出过程中降低凝胶形成。
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