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公开(公告)号：US5179193A
公开(公告)日：1993-01-12
申请号：US789554
申请日：1991-11-08
申请人： Rex L. Bobsein , Howard F. Efner
发明人： Rex L. Bobsein , Howard F. Efner
CPC分类号： C08G75/20 , C08G75/0236
摘要： Branched aromatic sulfide sulfone polymer is produced by contacting at least one dihalo aromatic sulfone, at least one polymerizable sulfur source other than lithium sulfide, at least one alkali metal carbonate, at least one organic amide, at least one alkali metal carboxylate, at least one polyhalodiarylsulfone having more than two halogen substituents and water including water of hydration under polymerization conditions for a period of time sufficient to form an aromatic sulfide sulfone polymer. The polymer exhibits higher melt and solution viscosity than obtained in the same process except without the use in the reaction mixture of polyhalodiarylsulfone having more than two halogen substituents and is useful in the production of coatings, films, molded objects, and fibers.
摘要翻译： 分支芳香硫醚砜聚合物是通过使至少一种二卤代芳族砜，至少一种不同于硫化锂的可聚合硫源，至少一种碱金属碳酸盐，至少一种有机酰胺，至少一种碱金属羧酸盐，至少一种 具有多于两个卤素取代基的多卤代二芳基砜和包含水合的水在聚合条件下持续足以形成芳族硫化物砜聚合物的时间。 聚合物显示出比在相同方法中获得的熔体和溶液粘度更高的熔融和溶液粘度，除非在具有多于两个卤素取代基的多卤二芳基砜的反应混合物中使用，并且可用于制备涂料，膜，模制物体和纤维。
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公开(公告)号：US5075420A
公开(公告)日：1991-12-24
申请号：US640092
申请日：1991-01-11
CPC分类号： C08J3/096 , C08G75/0236 , C08G75/0281 , C08G75/20 , C08J3/14 , C08J2381/00
摘要： A phenylene sulfide/sulfone polymer with relatively good melt stability and a method of producing such a polymer are provided. A previously produced phenylene sulfide/sulfone polymer is redissolved in N-methyl-2-pyrrolidone to form a solution. This solution is combined with an alcohol to precipitate highly melt stable phenylene sulfide/sulfone polymer in a particulate form. The alcohol has one to four carbon atoms, such as methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, and the like and mixtures thereof.
摘要翻译： 提供了具有较好熔融稳定性的亚苯基硫醚/砜聚合物和制备这种聚合物的方法。 将先前生产的苯硫醚/砜聚合物再溶解在N-甲基-2-吡咯烷酮中以形成溶液。 该溶液与醇结合以沉淀出高度熔融稳定的亚硫醚/砜聚合物的颗粒形式。 醇具有1-4个碳原子，例如甲醇，乙醇，1-丙醇，2-丙醇，1-丁醇，2-丁醇等及其混合物。
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3.发明授权Method for the production of light colored aromatic sulfide/sulfone polymers with 1,3-dialkyl-2-imidazolidinone diluent 失效用1,3-二烷基-2-咪唑烷酮稀释剂制备浅色芳香族硫化物/砜聚合物的方法
公开(公告)号：US5066774A
公开(公告)日：1991-11-19
申请号：US587836
申请日：1990-09-25
申请人： Jon F. Geibel , Rex L. Bobsein , Harold D. Yelton
发明人： Jon F. Geibel , Rex L. Bobsein , Harold D. Yelton
CPC分类号： C08G75/0259 , C08G75/0236 , C08G75/20
摘要： This invention provides a process to produce aromatic sulfide/sulfone polymers exhibiting high molecular weight, and having a light or "whitish" coloration. This process employs a dihaloaromatic sulfone, a sulfur-containing compound and a 1,3-dialkyl-2-imidazolidinone. These lighter colored polymers are more preferable commercially and may be useful in the production of coatings, films, molded objects, and glass or carbon fiber composites.
摘要翻译： 本发明提供一种生产表现出高分子量，具有浅或“发白”着色的芳族硫化物/砜聚合物的方法。 该方法采用二卤代芳砜，含硫化合物和1,3-二烷基-2-咪唑啉酮。 这些较浅的聚合物在商业上是更优选的，并且可用于制备涂料，膜，模塑物体以及玻璃或碳纤维复合材料。
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公开(公告)号：US5057592A
公开(公告)日：1991-10-15
申请号：US652302
申请日：1991-02-06
申请人： Rex L. Bobsein
发明人： Rex L. Bobsein
CPC分类号： C08G75/23 , C08G75/0236 , C08G75/025
摘要： A two-step process to make a poly(arylene sulfide sulfone) polymer containing ether groups having high molecular weights is described. In the first step an aromatic diphenol, a dihaloaromatic sulfone, a polar organic compound and an alkali metal base are reacted at an elevated temperature for a time period in the range of 1 minute to 2 hours. A sulfur source is then added to form a poly(arylene sulfide sulfone) polymer containing ether groups. An alkali metal carboxylate is also present in the second step. The polymers prepared by the invention method exhibit higher inherent viscosities, indicating higher molecular weight.
摘要翻译： 描述了制备含有高分子量的醚基的聚（亚芳基硫醚砜）聚合物的两步法。 在第一步中，将芳族二酚，二卤代芳香砜，极性有机化合物和碱金属碱在升高的温度下反应1分钟至2小时的时间。 然后加入硫源以形成含有醚基的聚（亚芳基硫醚砜）聚合物。 碱金属羧酸盐也存在于第二步中。 通过本发明方法制备的聚合物表现出较高的固有粘度，表明分子量较高。
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5.发明授权Reinforced plastic comprising fibrous reinforcement treated with poly(arylene sulfide sulfone) polymer containing ether groups 失效包括用含有醚基团的聚（亚芳基硫醚砜）聚合物处理的纤维增强材料的增强塑料
公开(公告)号：US5045367A
公开(公告)日：1991-09-03
申请号：US486589
申请日：1990-02-28
申请人： Rex L. Bobsein , Jon F. Geibel , Howard F. Efner , Mark L. Stone
发明人： Rex L. Bobsein , Jon F. Geibel , Howard F. Efner , Mark L. Stone
IPC分类号： C08J5/06
CPC分类号： C08J5/06 , C08J2381/00 , Y10S428/902 , Y10T428/2933 , Y10T428/2938 , Y10T428/30 , Y10T442/2402
摘要： A reinforced plastic is provided which comprises a poly(arylene sulfide sulfone) polymer matrix and fibrous reinforcement. The fibrous reinforcement is treated with a poly(arylene sulfide sulfone) polymer containing ether groups prior to forming the reinforced plastic. Such treatment improves the mechanical strength of the reinforced plastic.
摘要翻译： 提供了一种增强塑料，其包括聚（亚芳基硫醚砜）聚合物基质和纤维增强物。 在形成增强塑料之前，用含有醚基的聚（亚芳基硫醚砜）聚合物处理纤维增强物。 这种处理改善了增强塑料的机械强度。
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公开(公告)号：US4615836A
公开(公告)日：1986-10-07
申请号：US611655
申请日：1984-05-18
申请人： Rex L. Bobsein
发明人： Rex L. Bobsein
IPC分类号： C08H3/00
CPC分类号： C07C323/00
摘要： A process for preparing an alkylmercapto ester by reacting an alkyl mercaptoalkanol with an organic carboxylic acid or an organic anhydride in the presence of a titanium-containing catalyst.
摘要翻译： 一种通过烷基巯基烷醇与有机羧酸或有机酸酐在含钛催化剂存在下反应来制备烷基巯基酯的方法。
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7.发明授权
公开(公告)号：US5264176A
公开(公告)日：1993-11-23
申请号：US800905
申请日：1991-11-26
CPC分类号： C08G75/0254 , C08G75/024 , C08G75/0281
摘要： An aromatic sulfide/ketone polymer is prepared from a dihaloaromatic ketone, alkali metal sulfide, water and a polar organic compound. The polymerization reaction mixture is subjected to a heat soak at an elevated temperature, then a separation agent is added under controlled conditions and the mixture is subsequently cooled to provide a mixture comprising particulate aromatic sulfide/ketone polymer. Biaxially-oriented film is made from the recovered particles of aromatic sulfide/ketone polymer by (1) washing the polymer particles with an aqueous calcium salt, (2) heating the washed particles to remove water, (3) molding the heated particles to form a sheet of polymer, (4) biaxially stretching the sheet above the glass transition temperature of the polymer to form a film, and (5) heat-setting the biaxially-oriented film under stretching tension for a time and at a temperature to increase strength properties and density.
摘要翻译： 由二卤代芳族酮，碱金属硫化物，水和极性有机化合物制备芳族硫化物/酮聚合物。 将聚合反应混合物在升高的温度下进行热浸，然后在受控条件下加入分离剂，随后将混合物冷却以提供包含颗粒状芳族硫化物/酮聚合物的混合物。 通过（1）用钙盐水洗涤聚合物颗粒，（2）加热洗涤的颗粒以除去水，（3）将加热的颗粒成型形成，由回收的芳族硫化物/酮聚合物颗粒制成双轴取向膜 （4）将聚合物的玻璃化转变温度以上的双轴拉伸形成薄膜，（5）将拉伸张力下的双轴拉伸薄膜热固化一段时间，并使温度升高， 性质和密度。
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8.发明授权
公开(公告)号：US5245000A
公开(公告)日：1993-09-14
申请号：US724270
申请日：1991-07-01
申请人： Rex L. Bobsein , Jon F. Geibel , Howard F. Efner
发明人： Rex L. Bobsein , Jon F. Geibel , Howard F. Efner
CPC分类号： C08G75/23 , C08G75/0204 , C08G75/0259
摘要： Poly(arylene sulfide) polymers containing sulfone, ether and biphenyl groups are prepared by a two step process. In the first step, a diphenol is reacted with either a dihaloaromatic sulfone monomer or a bis(haloarylsulfonyl) biphenyl monomer, or both, in the presence of an alkali metal base and a polar organic compound. In the second step, the reaction mixture above is reacted with a sulfur source, and any monomer which was not employed in the first step, if any. The polymers prepared according to the invention process exhibit increased glass transition temperatures over those of known poly(arylene sulfide) polymers. The structure of repeating units of the polymer can be controlled by varying the sequence of addition of the monomers.
摘要翻译： 含有砜，醚和联苯基的聚（亚芳基硫醚）聚合物通过两步法制备。 在第一步中，在碱金属碱和极性有机化合物的存在下，二酚与二卤代芳族砜单体或双（卤代芳基磺酰基）联苯单体或两者反应。 在第二步中，将上述反应混合物与硫源反应，以及在第一步中未使用的任何单体（如果有的话）。 根据本发明方法制备的聚合物的玻璃化转变温度高于已知的聚（亚芳基硫醚）聚合物的玻璃化转变温度。 可以通过改变单体加成顺序来控制聚合物的重复单元的结构。
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公开(公告)号：US5177174A
公开(公告)日：1993-01-05
申请号：US810605
申请日：1991-12-19
申请人： Jon F. Geibel , Rex L. Bobsein
发明人： Jon F. Geibel , Rex L. Bobsein
CPC分类号： C08G75/20 , C08G75/0236
摘要： A first reaction mixture of at least one dihalo aromatic sulfone, at least one polyhydroxy aromatic compound, at least one organic amide and at least one alkali metal carbonate is contacted under polymerization conditions including a period of time at a temperature sufficient to form a reaction product, with the resulting product mixture being contacted with at least one polymerizable sulfur source, at least one organic amide, at least one alkali metal carboxylate, and water under polymerization conditions including a period of time at a temperature sufficient to form a branched aromatic sulfide sulfone polymer. The resulting polymers are useful in the production of coatings, films, molded objects, and fibers.
摘要翻译： 至少一种二卤芳族砜，至少一种多羟基芳族化合物，至少一种有机酰胺和至少一种碱金属碳酸盐的第一反应混合物在包括一段时间的聚合条件下接触，该温度足以形成反应产物 ，使得到的产物混合物在聚合条件下与至少一种可聚合硫源，至少一种有机酰胺，至少一种碱金属羧酸盐和水接触，所述聚合条件包括在足以形成支化芳族硫醚砜的温度下的一段时间 聚合物。 得到的聚合物可用于制备涂料，薄膜，模塑物体和纤维。
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10.发明授权
公开(公告)号：US5079079A
公开(公告)日：1992-01-07
申请号：US585844
申请日：1990-09-20
申请人： Mark L. Stone , Rex L. Bobsein , Howard F. Efner
发明人： Mark L. Stone , Rex L. Bobsein , Howard F. Efner
CPC分类号： C08J5/04 , C08J2381/00 , Y10S428/902 , Y10T428/24995 , Y10T428/30 , Y10T442/2549
摘要： A reinforced plastic which comprises a continuous long fiber reinforcing material in an arylene sulfide sulfone copolymer matrix consisting essentially of two structurally different arylene sulfide sulfone units within the polymer backbone.
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