公开(公告)号：US6159433A

公开(公告)日：2000-12-12

申请号：US184079

申请日：1998-11-02

Applicant: Jean-Alain Chodorge ,  Dominique Commereuc ,  Jean Cosyns ,  Didier Duee ,  Bernard Torck

Inventor： Jean-Alain Chodorge ,  Dominique Commereuc ,  Jean Cosyns ,  Didier Duee ,  Bernard Torck

IPC: C07C11/06 ,  C07C41/06 ,  C10G45/32 ,  C10G69/02 ,  B01J8/04

CPC classification number: C07C11/06 ,  C07C41/06 ,  C10G45/32 ,  C10G69/02 ,  B01J2219/00006

Abstract: The present invention concerns a plant for the conversion of an olefinic C.sub.4 or C.sub.5 cut to an alkyl-tertiobutylether or alkyl-tertioamylether and to propylene, by metathesis. The plant comprises four successive stages: (1) selective hydrogenation of the diolefins with simultaneous isomerisation of the alpha olefins to internal olefins; (2) etherification of the isoolefins; (3) elimination of oxygen-containing impurities; (4) metathesis of internal olefins with ethylene. Application to C.sub.4 and C.sub.5 steam cracking units.

Abstract translation: 本发明涉及一种通过复分解将烯烃C4或C5馏分转化为烷基 - 叔丁基醚或烷基 - 叔戊基醚并转化为丙烯的设备。 该设备包括四个连续的阶段：（1）二烯烃的选择性氢化，同时将α-烯烃异构化成内烯烃; （2）异烯烃的醚化; （3）消除含氧杂质; （4）内烯烃与乙烯的复分解。 应用于C4和C5蒸汽裂解装置。

公开(公告)号：US6137023A

公开(公告)日：2000-10-24

申请号：US996148

申请日：1997-12-22

Applicant: Michel Dorbon ,  Jean-Alain Chodorge ,  Jean Cosyns ,  Jean-Charles Viltard ,  Blaise Didillon

Inventor： Michel Dorbon ,  Jean-Alain Chodorge ,  Jean Cosyns ,  Jean-Charles Viltard ,  Blaise Didillon

IPC: B01J27/045 ,  C07B61/00 ,  C07C5/27 ,  C07C7/04 ,  C07C7/148 ,  C07C11/09 ,  C07C5/23 ,  B01D3/34 ,  C07C5/22

CPC classification number: C07C11/09 ,  C07C5/2791 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/755 ,  Y02P20/127 ,  Y10S203/06

Abstract: The invention relates to a process for producing high purity isobutene from a hydrocarbon cut essentially comprising olefinic hydrocarbons containing 4 carbon atoms per molecule including isobutene, also butene-1 and butene-2 compounds in a ratio which substantially corresponds to the thermodynamic equilibrium. The process comprises passing the cut into a distillation zone (3) associated with a hydroisomerisation reaction zone, the bottom product of the distillation zone comprising butene-2 compounds being passed into a skeletal isomerisation zone (2) where the linear butenes are at least partially isomerised to isobutene, at least part of the principal effluent from the skeletal isomerisation zone being recycled upstream of the reactive distillation zone (3).

Abstract translation: 本发明涉及从基本上包含每分子含有4个碳原子的烯烃的烃馏分生产高纯度异丁烯的方法，包括异丁烯，以及基本上对应于热力学平衡的比例的丁烯-1和丁烯-2化合物。 该方法包括将切片通入与加氢异构化反应区相关联的蒸馏区（3），蒸馏区的底部产物包含丁烯-2化合物进入骨架异构化区（2），其中线性丁烯至少部分 异构化为异丁烯，来自骨架异构化区的主要流出物的至少一部分在反应蒸馏区（3）的上游循环。

公开(公告)号：US06878837B2

公开(公告)日：2005-04-12

申请号：US10411384

申请日：2003-04-11

Applicant: Laurent Bournay ,  Gerard Hillion ,  Pierre Boucot ,  Jean-Alain Chodorge ,  Charles Bronner ,  Alain Forestiere

Inventor： Laurent Bournay ,  Gerard Hillion ,  Pierre Boucot ,  Jean-Alain Chodorge ,  Charles Bronner ,  Alain Forestiere

IPC: C07C67/03 ,  C07C51/00

CPC classification number: C11C3/003 ,  C07C67/03 ,  C07C69/24 ,  C07C69/52

Abstract: Alkyl esters of fatty acids, and high purity glycerin, are produced using a process comprising a set of transesterification reactions between a vegetable or animal oil and an aliphatic monoalcohol employing a heterogeneous catalyst, for example based on zinc aluminate, the water content in the reaction medium being controlled to a value that is below a given limiting value.

Abstract translation: 脂肪酸和高纯度甘油的烷基酯是使用包含一系列植物油或动物油与脂肪族一元醇之间的酯交换反应的方法制备的，该方法使用非均相催化剂，例如以铝酸铝为基准，反应中的水含量 介质被控制到低于给定极限值的值。

公开(公告)号：US6075173A

公开(公告)日：2000-06-13

申请号：US958909

申请日：1997-10-28

Applicant: Jean Alain Chodorge ,  Dominique Commereuc ,  Jean Cosyns

Inventor： Jean Alain Chodorge ,  Dominique Commereuc ,  Jean Cosyns

IPC: C07C5/25 ,  C07C6/04 ,  C07C11/06 ,  C07C11/09 ,  C07C1/00 ,  C07C5/03 ,  C07C6/00 ,  C10B57/02

CPC classification number: C07C11/09 ,  C07C11/06 ,  C07C5/2556 ,  C07C6/04 ,  C07C2521/04 ,  C07C2523/20 ,  C07C2523/36 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/755 ,  Y02P20/52

Abstract: The present invention concerns a process for the production of isobutene and propylene by metathesis of an olefinic C.sub.4 cut. The process comprises three successive steps: 1) selective hydrogenation of butadiene with isomerisation of butene-1 to butene-2; 2) separation by distillation to produce isobutene overhead, leaving a butene-2 bottom cut; 3) metathesis of the butene-2 cut with ethylene. The advantage of this process is that polymerisation quality propylene can be produced very selectively, in contrast to other processes such as dehydrogenation of propane or other cracking processes.

Abstract translation: 本发明涉及通过烯烃C4馏分的复分解来生产异丁烯和丙烯的方法。 该方法包括三个连续步骤：1）丁烯与丁烯-1异构化到丁烯-2的选择性氢化; 2）通过蒸馏分离以产生异丁烷塔顶馏出物，留下丁烯-2底切; 3）用乙烯进行丁烯-2切割的复分解。 该方法的优点是与其它方法如丙烷脱氢或其它裂解方法相反，可以非常有选择地生产聚合质量的丙烯。

公开(公告)号：US5898091A

公开(公告)日：1999-04-27

申请号：US644195

申请日：1996-05-10

Applicant: Jean-Alain Chodorge ,  Dominique Commereuc ,  Jean Cosyns ,  Didier Duee ,  Bernard Torck

Inventor： Jean-Alain Chodorge ,  Dominique Commereuc ,  Jean Cosyns ,  Didier Duee ,  Bernard Torck

IPC: C07C5/22 ,  C07B61/00 ,  C07C6/00 ,  C07C6/04 ,  C07C7/163 ,  C07C11/06 ,  C07C41/06 ,  C07C43/04 ,  C10G45/32 ,  C10G69/02

CPC classification number: C10G69/02 ,  C07C11/06 ,  C07C41/06 ,  C07C6/04 ,  C07C7/163 ,  C10G45/32 ,  B01J2219/00006 ,  C07C2521/04 ,  C07C2523/42

Abstract: For the conversion of an olefinic C.sub.4 or C.sub.5 cut to an alkyl-tertiobutylether or alkyl-tertioamylether and to propylene, by metathesis, the process comprises four successive steps: (1) selective hydrogenation of the diolefins with simultaneous isomerisation of the alpha olefins to internal olefins; (2) etherification of the isoolefins; (3) elimination of oxygen-containing impurities; (4) metathesis of internal olefins with ethylene. The process has application, e.g., to C.sub.4 and C.sub.5 steam cracking cuts.

Abstract translation: 为了通过复分解将烯烃C4或C5馏分转化为烷基 - 叔丁基醚或烷基 - 三甲基甲酰胺和丙烯，该方法包括四个连续步骤：（1）二烯烃的选择性氢化，同时将α-烯烃异构化成内部 烯烃; （2）异烯烃的醚化; （3）消除含氧杂质; （4）内烯烃与乙烯的复分解。 该方法具有例如C4和C5蒸汽裂解切割的应用。

公开(公告)号：US07868216B2

公开(公告)日：2011-01-11

申请号：US11315096

申请日：2005-12-23

Applicant: Jean-Alain Chodorge ,  Christian Dupraz

Inventor： Jean-Alain Chodorge ,  Christian Dupraz

IPC: C07C6/02 ,  C07C5/25 ,  C07C2/06

CPC classification number: C07C11/06

Abstract: A process for producing high purity propylene comprises: a step for dimerizing ethylene to 1-butene; a step for hydroisomerizing 1-butene to 2-butenes; and a step for metathesis of 2-butenes by ethylene. Advantageously, the ethylene used to produce the 1-butene and ethylene for metathesis derive from a steam cracking unit. To increase propylene production, the process can use a steam cracking or FCC C4cut as an additional butene source.

Abstract translation: 一种生产高纯度丙烯的方法包括：将乙烯二聚至1-丁烯的步骤; 将1-丁烯加氢异构化成2-丁烯的步骤; 以及乙烯复配2-丁烯的步骤。 有利地，用于制备用于复分解的1-丁烯和乙烯的乙烯来自蒸汽裂解装置。 为了增加丙烯生产，该方法可以使用蒸汽裂化或FCC C4cut作为附加的丁烯源。

公开(公告)号：US06358482B1

公开(公告)日：2002-03-19

申请号：US09520241

申请日：2000-03-07

Applicant: Jean Alain Chodorge ,  Dominique Commereuc ,  Jean Cosyns

Inventor： Jean Alain Chodorge ,  Dominique Commereuc ,  Jean Cosyns

IPC: B01J802

CPC classification number: C07C11/09 ,  C07C5/2556 ,  C07C6/04 ,  C07C11/06 ,  C07C2521/04 ,  C07C2523/20 ,  C07C2523/36 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/755 ,  Y02P20/52 ,  C07C11/08

Abstract: A facility for converting an olefinic C4 cut to isobutene and propylene comprising, in succession: 1) a zone 1 for selective hydrogenation of olefins in the olefinic C4 cut with simultaneous isomerisation of butene-1 to butene-2, said zone comprising at least one device for introducing the olefinic C4 cut to be converted, at least one device for removing an effluent, and at least one device for introducing hydrogen, said zone also comprising at least one catalyst bed; 2) a separation zone, comprising at least one device for introducing the effluent from zone 1 directly connected to said at least one device for removing an effluent, at least one device for removing a first fraction comprising isobutene and butene-1, and at least one device for removing a second fraction comprising butene-2 and n-butane, wherein the second fraction comprises at most 1% by weight of isobutene and at most 1% by weight of butene-1; 3) a metathesis zone for metathesis of butene-2 with ethylene to produce propylene, wherein the metathesis zone comprises at least one device for introducing butene-2 from the second fraction of the separation zone, at least one device for introducing ethylene, and at least one device for removing propylene, and at least one catalyst comprising at least one rhenium oxide deposited on a support.

Abstract translation: 将烯烃C4馏分转化为异丁烯和丙烯的设备包括：1）用于烯烃C4馏分中的烯烃的选择性氢化的区1，其中丁烯-1同时异构化为丁烯-2，所述区包括至少一个 用于引入要转化的烯烃C4馏分的装置，用于除去流出物的至少一个装置和至少一个用于引入氢气的装置，所述区域还包括至少一个催化剂床; 2）分离区，包括至少一个装置 用于将来自直接连接到所述至少一个装置的区域1的流出物引入以除去流出物，用于除去包含异丁烯和丁烯-1的第一馏分的至少一个装置和用于除去包含丁烯-2的第二馏分的至少一个装置 和正丁烷，其中第二部分包含至多1重量％的异丁烯和至多1重量％的丁烯-1; 3）用于将乙烯复分解为乙烯以产生丙烯的复分解区 其中所述复分解区包含用于从所述分离区的第二级分引入丁烯-2的至少一种装置，用于引入乙烯的至少一种装置和用于除去丙烯的至少一种装置，以及至少包含至少一种催化剂 沉积在载体上的一种氧化铼氧化物。

公开(公告)号：US5853551A

公开(公告)日：1998-12-29

申请号：US720384

申请日：1996-07-23

Applicant: Pierre Boucot ,  Jean-Alain Chodorge ,  Alain Forestiere ,  Yves Glaize ,  Fran.cedilla.ois Hughes

Inventor： Pierre Boucot ,  Jean-Alain Chodorge ,  Alain Forestiere ,  Yves Glaize ,  Fran.cedilla.ois Hughes

IPC: C07C7/05 ,  B01D3/34 ,  B01D3/14

CPC classification number: C07C7/05

Abstract: The invention concerns a process for the separation of a mixture comprising ethylene, 1-butene, alpha-olefins containing at least 6 carbon atoms per molecule and possibly heavier hydrocarbon products, the ethylene content of the mixture being in the range 30% to 70% by weight, in which separation is effected in a distillation zone to obtain an overhead fraction comprising the major portion of the ethylene present in the mixture and between 0% and 100% by weight of the 1-butene present in the mixture, the process being characterized in that the zone is also supplied with supplemental 1-butene in an amount in the range 1 to 40 times the quantity (by weight) of 1-butene present in the mixture. In a preferred implementation of the process of the invention, the mixture originates form a homogenous liquid phase ethylene oligomerisation zone.

Abstract translation: 本发明涉及一种分离包含乙烯，1-丁烯，每分子含有至少6个碳原子的α-烯烃和可能较重烃产物的混合物的混合物的方法，该混合物的乙烯含量在30％至70％的范围内， ，其中在蒸馏区中进行分离以获得包含混合物中存在的乙烯的主要部分和0重量％至100重量％的混合物中存在的1-丁烯的塔顶馏分，该方法为 其特征在于，该区域还提供了在混合物中存在的1-丁烯的量（重量）的1至40倍的量的补充的1-丁烯。 在本发明方法的优选实施方案中，混合物起始形成均相液相乙烯齐聚区。

公开(公告)号：US20060161033A1

公开(公告)日：2006-07-20

申请号：US11315096

申请日：2005-12-23

Applicant: Jean-Alain Chodorge ,  Christian Dupraz

Inventor： Jean-Alain Chodorge ,  Christian Dupraz

IPC: C07C4/00

CPC classification number: C07C11/06

Abstract: A process for producing high purity propylene comprises: a step for dimerizing ethylene to 1-butene; a step for hydroisomerizing 1-butene to 2-butenes; and a step for metathesis of 2-butenes by ethylene. Advantageously, the ethylene used to produce the 1-butene and ethylene for metathesis derive from a steam cracking unit. To increase propylene production, the process can use a steam cracking or FCC C4 cut as an additional butene source.

Abstract translation: 一种生产高纯度丙烯的方法包括：将乙烯二聚至1-丁烯的步骤; 将1-丁烯加氢异构化成2-丁烯的步骤; 以及乙烯复配2-丁烯的步骤。 有利地，用于制备用于复分解的1-丁烯和乙烯的乙烯来自蒸汽裂解装置。 为了增加丙烯生产，该方法可以使用蒸汽裂化或FCC C4馏分作为附加的丁烯源。

公开(公告)号：US06207115B1

公开(公告)日：2001-03-27

申请号：US09201087

申请日：1998-11-30

Applicant: Jean-Alain Chodorge ,  Dominique Commereuc ,  Jean Cosyns ,  Didier Duee ,  Bernard Torck

Inventor： Jean-Alain Chodorge ,  Dominique Commereuc ,  Jean Cosyns ,  Didier Duee ,  Bernard Torck

IPC: B01J804

CPC classification number: C08F110/10 ,  B01J8/08 ,  C07C6/04 ,  C07C7/163 ,  C07C11/06 ,  C07C2521/04 ,  C07C2523/20 ,  C07C2523/36 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/755 ,  C08F2/00 ,  C08F4/12

Abstract: The present invention concerns a process for the conversion of an olefinic C4 cut to polyisobutene and to propylene by metathesis. The process comprises three successive steps: (1) selective hydrogenation of diolefins with simultaneous isomerisation of 1-butene to 2-butenes, (2) polymerisation of the isobutene, including optional prior extraction of the isobutene, (3) metathesis of 2-butene with ethylene. Part or all of the C4 cut may originate from the metathesis of an olefinic C5 cut with ethylene after hydroisomerisation of the C5 cut. Application to C4 and C5 steam cracking cuts.

Abstract translation: 本发明涉及通过复分解将烯烃C4馏分转化为聚异丁烯和丙烯的方法。 该方法包括三个连续步骤：（1）将1-丁烯同时异构化为2-丁烯的二烯烃的选择性氢化，（2）异丁烯的聚合，包括任选先前提取的异丁烯，（3）2-丁烯的复分解 与乙烯。 C4馏分的部分或全部可以源自C5馏分加氢异构化后的烯烃C5馏分的复分解。 应用于C4和C5蒸汽裂解切割。