Methods of producing epoxides from alkenes using a two-component catalyst system
    2.
    发明授权
    Methods of producing epoxides from alkenes using a two-component catalyst system 有权
    使用双组分催化剂体系从烯烃生产环氧化物的方法

    公开(公告)号:US08481766B2

    公开(公告)日:2013-07-09

    申请号:US12943138

    申请日:2010-11-10

    IPC分类号: C07D301/06

    CPC分类号: C07D301/06

    摘要: Methods for the epoxidation of alkenes are provided. The methods include the steps of exposing the alkene to a two-component catalyst system in an aqueous solution in the presence of carbon monoxide and molecular oxygen under conditions in which the alkene is epoxidized. The two-component catalyst system comprises a first catalyst that generates peroxides or peroxy intermediates during oxidation of CO with molecular oxygen and a second catalyst that catalyzes the epoxidation of the alkene using the peroxides or peroxy intermediates. A catalyst system composed of particles of suspended gold and titanium silicalite is one example of a suitable two-component catalyst system.

    摘要翻译: 提供烯烃环氧化方法。 所述方法包括在烯烃被环氧化的条件下,在一氧化碳和分子氧的存在下,在水溶液中将烯烃暴露于双组分催化剂体系的步骤。 双组分催化剂体系包括在分子氧氧化CO期间产生过氧化物或过氧化物中间体的第一催化剂和使用过氧化物或过氧化物中间体催化烯烃的环氧化的第二催化剂。 由悬浮金和钛硅沸石的颗粒组成的催化剂体系是合适的双组分催化剂体系的一个实例。

    METHODS OF PRODUCING EPOXIDES FROM ALKENES USING A TWO-COMPONENT CATALYST SYSTEM
    6.
    发明申请
    METHODS OF PRODUCING EPOXIDES FROM ALKENES USING A TWO-COMPONENT CATALYST SYSTEM 有权
    使用双组分催化剂体系从碱性生产环氧化物的方法

    公开(公告)号:US20110112315A1

    公开(公告)日:2011-05-12

    申请号:US12943138

    申请日:2010-11-10

    IPC分类号: C07D301/06

    CPC分类号: C07D301/06

    摘要: Methods for the epoxidation of alkenes are provided. The methods include the steps of exposing the alkene to a two-component catalyst system in an aqueous solution in the presence of carbon monoxide and molecular oxygen under conditions in which the alkene is epoxidized. The two-component catalyst system comprises a first catalyst that generates peroxides or peroxy intermediates during oxidation of CO with molecular oxygen and a second catalyst that catalyzes the epoxidation of the alkene using the peroxides or peroxy intermediates. A catalyst system composed of particles of suspended gold and titanium silicalite is one example of a suitable two-component catalyst system.

    摘要翻译: 提供烯烃环氧化方法。 所述方法包括在烯烃被环氧化的条件下,在一氧化碳和分子氧的存在下,在水溶液中将烯烃暴露于双组分催化剂体系的步骤。 双组分催化剂体系包括在分子氧氧化CO期间产生过氧化物或过氧化物中间体的第一催化剂和使用过氧化物或过氧化物中间体催化烯烃的环氧化的第二催化剂。 由悬浮金和钛硅沸石的颗粒组成的催化剂体系是合适的双组分催化剂体系的一个实例。

    Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons
    8.
    发明授权
    Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons 失效
    烷烃氧化脱氢为不饱和烃

    公开(公告)号:US4777319A

    公开(公告)日:1988-10-11

    申请号:US69284

    申请日:1987-07-01

    IPC分类号: C07C5/48 C07C5/09 C07C5/327

    CPC分类号: C07C5/48

    摘要: Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons is carried out over metal vanadate catalysts under oxidizing conditions. The vanadate catalysts are represented by the formulas M.sub.3 (VO.sub.4).sub.2 and MV.sub.2 O.sub.6, M representing Mg, Zn, Ca, Pb, or Cd. The reaction is carried out in the presence of oxygen, but the formation of oxygenate by-products is suppressed.

    摘要翻译: 在氧化条件下,在金属钒酸盐催化剂上进行烷烃到不饱和烃的氧化脱氢。 钒酸盐催化剂由式M3(VO4)2和MV2O6表示,M表示Mg,Zn,Ca,Pb或Cd。 反应在氧的存在下进行,但是含氧化合物副产物的形成被抑制。