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公开(公告)号：US08957273B2
公开(公告)日：2015-02-17
申请号：US13000387
申请日：2009-06-24
IPC分类号： C07C1/20 , C07C1/24 , C07C1/26 , B01J21/08 , B01J21/16 , B01J27/14 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/90 , B01J38/12 , C07C1/32
CPC分类号： C07C1/20 , B01J21/08 , B01J21/16 , B01J27/14 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/90 , B01J38/12 , B01J2229/16 , B01J2229/18 , B01J2229/36 , B01J2229/37 , C07C1/26 , C07C1/322 , C07C4/06 , C07C2529/40 , Y02P20/584 , Y02P30/42 , C07C11/02
摘要： The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising: a0) providing a first portion and a second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, a) providing a catalyst comprising zeolitic molecular sieves containing at least 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, optionally at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting the first portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; d) separating said light olefins from said heavy hydrocarbon fraction; e) contacting said heavy hydrocarbon fraction and the second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the OC reactor with the catalyst at conditions effective to convert at least a portion of said heavy hydrocarbon fraction and oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to light olefins.
摘要翻译： 本发明涉及一种在组合的XTO-OC方法中由含氧，含卤素或含硫有机原料制备轻质烯烃的方法，包括：a）提供所述氧气的第一部分和第二部分 a）提供包含在其微孔结构中含有至少10元环孔或更大孔沸石分子筛的催化剂，b）提供XTO反应区，OC反应区和 催化剂再生区，所述催化剂在三个区域中循环，使得至少一部分再生催化剂通入OC反应区，任选地将OC反应区中的至少一部分催化剂通入XTO反应 区域，并且XTO反应区中的至少一部分催化剂被传送到再生区; c）在有效地转化至少一部分原料以形成包含轻质烯烃的XTO反应器流出物的条件下，将XTO反应器中的含氧卤化物或含硫有机原料的第一部分与催化剂接触， 重质烃馏分; d）从所述重质烃馏分中分离出所述轻质烯烃; e）在OC反应器中将所述重质烃部分和第二部分所述含氧卤化物或含硫有机原料与所述催化剂接触，所述条件有效地将至少一部分所述重质烃部分和氧 - 含卤素或含硫有机原料转化成轻质烯烃。
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公开(公告)号：US08957272B2
公开(公告)日：2015-02-17
申请号：US13000368
申请日：2009-06-24
IPC分类号： C07C1/20 , C07C1/24 , B01J21/08 , B01J21/16 , B01J27/14 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/90 , B01J38/02 , B01J38/12 , C07C1/26 , C07C1/32
CPC分类号： C07C1/20 , B01J21/08 , B01J21/16 , B01J27/14 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/90 , B01J38/02 , B01J38/12 , B01J2229/16 , B01J2229/18 , B01J2229/36 , B01J2229/37 , C07C1/26 , C07C1/322 , C07C4/06 , C07C2529/40 , Y02P20/584 , Y02P30/42 , C07C11/02
摘要： The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising: a0) providing a first portion and a second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, a) providing a catalyst comprising zeolitic molecular sieves containing at least 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting the first portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; d) separating said light olefins from said heavy hydrocarbon fraction; e) contacting said heavy hydrocarbon fraction and the second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the OC reactor with the catalyst at conditions effective to convert at least a portion of said heavy hydrocarbon fraction and oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to light olefins.
摘要翻译： 本发明涉及一种在组合的XTO-OC方法中由含氧，含卤素或含硫有机原料制备轻质烯烃的方法，包括：a）提供所述氧气的第一部分和第二部分 a）提供包含在其微孔结构中含有至少10元环孔或更大孔沸石分子筛的催化剂，b）提供XTO反应区，OC反应区和 催化剂再生区，所述催化剂在三个区域中循环，使得至少一部分再生催化剂通过OC反应区，OC反应区中的至少一部分催化剂通入XTO反应区 并且将XTO反应区中的至少一部分催化剂送入再生区; c）在有效地转化至少一部分原料以形成包含轻质烯烃的XTO反应器流出物的条件下，将XTO反应器中的含氧卤化物或含硫有机原料的第一部分与催化剂接触， 重质烃馏分; d）从所述重质烃馏分中分离出所述轻质烯烃; e）在OC反应器中将所述重质烃部分和第二部分所述含氧卤化物或含硫有机原料与所述催化剂接触，所述条件有效地将至少一部分所述重质烃部分和氧 - 含卤素或含硫有机原料转化成轻质烯烃。
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公开(公告)号：US20110152479A1
公开(公告)日：2011-06-23
申请号：US13000368
申请日：2009-06-24
CPC分类号： C07C1/20 , B01J21/08 , B01J21/16 , B01J27/14 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/90 , B01J38/02 , B01J38/12 , B01J2229/16 , B01J2229/18 , B01J2229/36 , B01J2229/37 , C07C1/26 , C07C1/322 , C07C4/06 , C07C2529/40 , Y02P20/584 , Y02P30/42 , C07C11/02
摘要： The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising : a0) providing a first portion and a second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, a) providing a catalyst comprising zeolitic molecular sieves containing at feast 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting the first portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; d) separating said light olefins from said heavy hydrocarbon fraction; e) contacting said heavy hydrocarbon fraction and the second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the OC reactor with the catalyst at conditions effective to convert at least a portion of said heavy hydrocarbon fraction and oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to light olefins.
摘要翻译： 本发明涉及一种在组合的XTO-OC方法中由含氧，含卤素或含硫有机原料制备轻质烯烃的方法，包括：a）提供所述氧气的第一部分和第二部分 含有卤化物或含硫有机原料，a）提供包含沸石分子筛的催化剂，所述沸石分子筛在其微孔结构中含有10元环孔或更大孔，b）提供XTO反应区，OC反应区和 催化剂再生区，所述催化剂在三个区域中循环，使得至少一部分再生催化剂通过OC反应区，OC反应区中的至少一部分催化剂通入XTO反应区 并且将XTO反应区中的至少一部分催化剂送入再生区; c）在有效地转化至少一部分原料以形成包含轻质烯烃的XTO反应器流出物的条件下，将XTO反应器中的含氧卤化物或含硫有机原料的第一部分与催化剂接触， 重质烃馏分; d）从所述重质烃馏分中分离出所述轻质烯烃; e）在OC反应器中将所述重质烃部分和第二部分所述含氧卤化物或含硫有机原料与所述催化剂接触，所述条件有效地将至少一部分所述重质烃部分和氧 - 含卤素或含硫有机原料转化成轻质烯烃。
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公开(公告)号：US4206875A
公开(公告)日：1980-06-10
申请号：US940236
申请日：1978-09-07
申请人： Giacomo Grasso
发明人： Giacomo Grasso
CPC分类号： F28D21/0008 , F28D7/12 , Y10S122/01 , Y10S165/901
摘要： A recuperator for recovering heat from hot exhaust gases flowing through a flue comprises inner and outer cylindrical walls coaxially surrounding a portion of the flue to which a plurality of fins are fixed, the fins extending longitudinally of the flue and being grouped such that fins spaced circumferentially around one section of the flue are angularly staggered with respect to fins spaced circumferentially around an adjacent section of the flue, the recuperator being arranged such that cold gas can be passed into, and is preheated as it flows along, an outer annular space between the said walls, the gas passing into an inner annular space containing the fins which cause turbulence and increase the heat-transfer by convection and radiation to the gas, and the heated gas being emitted through an outlet.
摘要翻译： 用于从流过烟道的热废气回收热量的换热器包括同轴地围绕多个翅片固定到烟道的一部分的内圆柱体和外圆柱形壁，翅片沿着烟道纵向延伸并且被分组成使得沿圆周方向间隔开的翅片 烟道的大约一个部分相对于沿着烟道的相邻部分周向间隔开的翅片成角度地交错，所述换热器被布置成使得冷气体可以被传入，并且在其沿着外部环形空间流动之间被预热 所述壁，气体进入包含翅片的内部环形空间，所述内部环形空间引起湍流，并且通过对流和辐射增加对气体的热传递，并且加热的气体通过出口排出。
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公开(公告)号：US09162937B2
公开(公告)日：2015-10-20
申请号：US13055019
申请日：2009-07-03
IPC分类号： C07C1/20
摘要： The present invention is a process for making an olefin product from an oxygen-containing organic feedstock comprising: providing a mixture of said oxygen-containing feedstock, an hydrocarbon and optionally an inert diluent, contacting said mixture in a reaction zone having an inner surface (the MTO reactor) with a zeolitic catalyst at conditions effective to convert at least a part of the oxygen-containing organic feedstock to olefin products (the MTO reactor effluent), recovering a reactor effluent comprising light olefins, a heavy hydrocarbon fraction and undesired by-products, wherein: at least a part of the inner surface is passivated such that the undesired by-products are reduced by comparison with a non passivated inner surface and/or one or more sulphur compound is co-injected with the said oxygen-containing feedstock and the hydrocarbon and said sulphur compound is capable to reduce the undesired by-products by comparison with a non injection of sulphur compound. The present invention is of high interest for the catalyst of the ZSM type such as ZSM-5 optionally containing phosphorus and regenerated in the MTO reactor.
摘要翻译： 本发明是从含氧有机原料制备烯烃产物的方法，包括：提供所述含氧原料，烃和任选的惰性稀释剂的混合物，使所述混合物在具有内表面的反应区 MTO反应器），在有效地将至少一部分含氧有机原料转化为烯烃产物（MTO反应器流出物）的条件下使用沸石催化剂，回收包含轻质烯烃，重质烃馏分和不希望的副产物的反应器流出物， 产品，其中：所述内表面的至少一部分被钝化，使得通过与非钝化内表面相比减少不需要的副产物和/或一种或多种硫化合物与所述含氧原料共注入 并且烃和所述硫化合物能够通过与非注射硫化合物相比而减少不期望的副产物。 本发明对ZSM型催化剂如ZSM-5任选含磷并在MTO反应器中再生而感兴趣。
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公开(公告)号：US08957274B2
公开(公告)日：2015-02-17
申请号：US13000401
申请日：2009-06-24
IPC分类号： C07C1/20 , C07C1/24 , C07C1/26 , B01J21/08 , B01J21/16 , B01J27/14 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/90 , B01J38/12 , C07C1/32
CPC分类号： C07C1/20 , B01J21/08 , B01J21/16 , B01J27/14 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/90 , B01J38/12 , B01J2229/16 , B01J2229/18 , B01J2229/36 , B01J2229/37 , C07C1/26 , C07C1/322 , C07C2/864 , C07C4/06 , C07C2529/40 , Y02P20/584 , Y02P30/42 , C07C15/02 , C07C11/02
摘要： The present invention relates to a process to make light olefins and aromatics, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising: a0) providing a first portion and a second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, a) providing a catalyst comprising zeolitic molecular sieves containing at least 10 membered ring pore openings or larger in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting the first portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; d) separating said light olefins from said heavy hydrocarbon fraction; e) contacting said heavy hydrocarbon fraction and the second portion of said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the OC reactor with the catalyst at conditions effective to convert at least a portion of said heavy hydrocarbon fraction and oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to light olefins and aromatics.
摘要翻译： 本发明涉及一种在组合的XTO-OC方法中由含氧，含卤素或含硫有机原料制备轻质烯烃和芳族化合物的方法，包括：a0）提供第一部分和第二部分 所述含氧，含卤素或含硫有机原料，a）提供包含在其微孔结构中含有至少10元环孔孔或更大的沸石分子筛的催化剂，b）提供XTO反应区，OC反应 区域和催化剂再生区，所述催化剂在三个区域中循环，使得至少一部分再生催化剂通过OC反应区，OC反应区中的至少一部分催化剂通过XTO 反应区和XTO反应区中的至少一部分催化剂通入再生区; c）在有效地转化至少一部分原料以形成包含轻质烯烃的XTO反应器流出物的条件下，将XTO反应器中的含氧卤化物或含硫有机原料的第一部分与催化剂接触， 重质烃馏分; d）从所述重质烃馏分中分离出所述轻质烯烃; e）在OC反应器中将所述重质烃部分和第二部分所述含氧卤化物或含硫有机原料与所述催化剂接触，所述条件有效地将至少一部分所述重质烃部分和氧 - 含有卤化物或含硫有机原料至轻质烯烃和芳族化合物。
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7.发明申请PROCESS FOR AROMATIC HYDROGENATION AND CETANE VALUE INCREASE OF MIDDLE-DISTILLATE FEEDSTOCKS 审中-公开芳烃加氢方法和中等离子交换剂的增值价格公开(公告)号：US20110303585A1
公开(公告)日：2011-12-15
申请号：US13139451
申请日：2009-12-11
CPC分类号： C10G45/52 , B01J23/44 , B01J23/63 , B01J23/652 , B01J23/89 , B01J35/0066 , B01J35/1019 , B01J35/1042 , C10G45/04 , C10G45/08 , C10G65/08
摘要： The instant invention pertains to a process for treating a feed, for example a Light Cycle Oil (LCO), having a high content of S and/or N impurities and/or a high content of aromatics, comprising the following steps, in particular in such an order a step of desulphurisation (HDS) and denitrification (HDN) of a feed, in particular LCO, is passed in presence of hydrogen over a catalyst, containing metals of the group VI B and VIII, leading to an effluent, optionally a step of stripping of the effluent, at least a subsequent step for dearomatization (HDA) in which at least a portion of the effluent, optionally stripped, is passed in presence of hydrogen over a catalyst comprising a combination of platinum and palladium supported on a carrier comprising silica-alumina dispersed in an alumina binder wherein the amount of alumina binder is 5-50 wt. % based on the total weight of the silica-alumina and alumina binder present in the carrier and wherein the silica-alumina comprises 5-50 wt. % of alumina based on the weight of the silica-alumina, and recovering the final load obtained, the use of a specific catalyst and a process for preparing diesel comprising the step of mixing the final effluent obtained by a process of the invention.
摘要翻译： 本发明涉及用于处理具有高含量的S和/或N杂质和/或高含量芳族化合物的进料例如轻循环油（LCO）的方法，其包括以下步骤，特别是在 进料的脱硫（HDS）和脱氮（HDN），特别是LCO的步骤在氢气存在下通过含有VIB和VIII族的金属的催化剂，导致流出物，任选地 至少后续的脱气步骤（HDA），其中至少一部分流出物（任选地被汽提）在氢气存在下通过催化剂，所述催化剂包含负载在载体上的铂和钯的组合 包括分散在氧化铝粘合剂中的二氧化硅 - 氧化铝，其中氧化铝粘合剂的量为5-50wt。 基于存在于载体中的二氧化硅 - 氧化铝和氧化铝粘合剂的总重量，其中二氧化硅 - 氧化铝包含5-50wt。 基于二氧化硅 - 氧化铝的重量的氧化铝的百分比，并且回收所获得的最终载荷，使用特定催化剂和制备柴油的方法，包括混合通过本发明的方法获得的最终流出物的步骤。
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公开(公告)号：US20110166303A1
公开(公告)日：2011-07-07
申请号：US13000364
申请日：2009-06-24
CPC分类号： C07C1/22 , B01J21/08 , B01J21/16 , B01J27/14 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/90 , B01J37/10 , B01J38/12 , B01J2229/16 , B01J2229/186 , B01J2229/36 , C07C1/20 , C07C1/26 , C07C1/322 , C07C4/06 , C07C2529/40 , C10G3/44 , C10G3/49 , C10G3/62 , C10G9/00 , C10G55/04 , C10G2400/20 , Y02P20/584 , Y02P30/20 , Y02P30/42 , C07C11/02
摘要： The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising:a) providing a catalyst comprising zeolitic molecular sieves containing 10 member and larger channels in their microporous structure, b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; d) separating said light olefins from said heavy hydrocarbon fraction; e) contacting said heavy hydrocarbon fraction in the OC reactor with the catalyst at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins.
摘要翻译： 本发明涉及一种在组合的XTO-OC方法中由含氧的含卤化物或含硫有机原料制备轻质烯烃的方法，包括：a）提供包含含10个成员的沸石分子筛和 在其微孔结构中较大的通道，b）提供XTO反应区，OC反应区和催化剂再生区，所述催化剂在三个区中循环，使得至少一部分再生催化剂通过OC反应区 ，将OC反应区中的至少一部分催化剂通入XTO反应区，并将XTO反应区中的至少一部分催化剂通入再生区; c）在有效地转化至少一部分原料以形成包含轻质烯烃和重质烃部分的XTO反应器流出物的条件下，将XTO反应器中的含氧卤化物或含硫有机原料与催化剂接触 ; d）从所述重质烃馏分中分离出所述轻质烯烃; e）使OC反应器中的所述重质烃馏分与催化剂在有效将至少一部分所述重质烃馏分转化为轻质烯烃的条件下接触。
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公开(公告)号：US4368777A
公开(公告)日：1983-01-18
申请号：US233258
申请日：1981-02-10
申请人： Giacomo Grasso
发明人： Giacomo Grasso
CPC分类号： F28D21/0007 , F28D7/106 , F28F1/42 , F28F1/422
摘要： The characteristics of a gas-liquid heat exchanger are described, for particular use in the production of hot or superheated water by means of the exhaust gases emitted through the chimneys of a thermal treatment furnace, comprising an internal tubular element, for the passage of the gases, surrounded by an external tubular element which defines an annular chamber through which a liquid flows in counter-current to the flow of the gases in the internal tubular element. The latter is provided on its external surface and on its internal surface with radial fins, angularly equidistant from each other, extending axially for a substantial portion of the length of the internal tubular element. The height of each radial fin decreases linearly, both on the side exposed to the gas, and on the side exposed to the liquid, in the opposite direction to that of the flow of the fluid intended to come into contact with the fin, so as to enhance the heat exchange, while the same time avoiding damage through overheating of the said fin and of the wall of the internal tubular element.
摘要翻译： 描述了气液热交换器的特征，特别用于通过热处理炉的烟囱排出的废气生产热过热水或过热水，其包括内部管状元件，用于通过 气体被外部管状元件包围，外部管状元件限定了环形室，液体通过该环形室与内部管状元件中的气体流逆流。 后者在其外表面上及其内表面上设置有径向翼片，其彼此成角度地等距，在内部管状元件的长度的大部分上轴向延伸。 每个径向翅片的高度在暴露于气体的一侧和在暴露于液体的一侧上沿着与用于与翅片接触的流体的流动的方向相反的方向线性地减小，以便 以增强热交换，同时通过所述翅片和内部管状元件的壁的过热避免损坏。
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公开(公告)号：US08957271B2
公开(公告)日：2015-02-17
申请号：US13000364
申请日：2009-06-24
IPC分类号： C07C1/20 , C07C1/24 , B01J38/12 , B01J21/08 , B01J21/16 , B01J27/14 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/90 , B01J37/10 , C07C1/26 , C07C1/32 , C10G3/00 , C10G9/00 , C10G55/04
CPC分类号： C07C1/22 , B01J21/08 , B01J21/16 , B01J27/14 , B01J29/18 , B01J29/40 , B01J29/65 , B01J29/90 , B01J37/10 , B01J38/12 , B01J2229/16 , B01J2229/186 , B01J2229/36 , C07C1/20 , C07C1/26 , C07C1/322 , C07C4/06 , C07C2529/40 , C10G3/44 , C10G3/49 , C10G3/62 , C10G9/00 , C10G55/04 , C10G2400/20 , Y02P20/584 , Y02P30/20 , Y02P30/42 , C07C11/02
摘要： The present invention relates to a process to make light olefins, in a combined XTO-OC process, from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising:a) providing a catalyst comprising zeolitic molecular sieves containing 10 member and larger channels in their microporous structure,b) providing an XTO reaction zone, an OC reaction zone and a catalyst regeneration zone, said catalyst circulating in the three zones, such that at least a portion of the regenerated catalyst is passed to the OC reaction zone, at least a portion of the catalyst in the OC reaction zone is passed to the XTO reaction zone and at least a portion of the catalyst in the XTO reaction zone is passed to the regeneration zone; c) contacting said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with the catalyst at conditions effective to convert at least a portion of the feedstock to form a XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; d) separating said light olefins from said heavy hydrocarbon fraction; e) contacting said heavy hydrocarbon fraction in the OC reactor with the catalyst at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins.
摘要翻译： 本发明涉及一种在组合的XTO-OC方法中由含氧的含卤素或含硫有机原料制备轻质烯烃的方法，包括：a）提供包含含有10个成员的沸石分子筛和 在其微孔结构中较大的通道，b）提供XTO反应区，OC反应区和催化剂再生区，所述催化剂在三个区中循环，使得至少一部分再生催化剂通过OC反应区 ，将OC反应区中的至少一部分催化剂通入XTO反应区，并将XTO反应区中的至少一部分催化剂通入再生区; c）在有效地转化至少一部分原料以形成包含轻质烯烃和重质烃部分的XTO反应器流出物的条件下，将XTO反应器中的含氧卤化物或含硫有机原料与催化剂接触 ; d）从所述重质烃馏分中分离出所述轻质烯烃; e）使OC反应器中的所述重质烃馏分与催化剂在有效将至少一部分所述重质烃馏分转化为轻质烯烃的条件下接触。
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