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公开(公告)号：US5077430A
公开(公告)日：1991-12-31
申请号：US684751
申请日：1991-04-15
IPC分类号： C07F9/38
CPC分类号： C07F9/3813
摘要： A process is provided for producing N-phosphonomethylglycine by the oxidation of N-phosphonomethyliminodiacetic acid with a peroxide to form an intermediate N-phosphonomethyliminodiacetic acid-N-oxide. Thereafter, the N-phosphonomethyliminodiacetic acid-N-oxide is converted to N-phosphonomethylglycine by adding a catalytic amount of a metal selected from the group consisting of iron, zinc, aluminum, vanadium and copper, or a compound selected from the group consisting of water-soluble vanadium compounds, ferrous salts and cuprous salts.
摘要翻译： 提供了通过用过氧化物氧化N-膦酰基甲基亚氨基二乙酸以形成中间体N-膦酰甲基亚氨基二乙酸-N-氧化物来生产N-膦酰基甲基甘氨酸的方法。 此后，通过添加催化量的选自铁，锌，铝，钒和铜的金属或选自下组的化合物，将N-膦酰基甲基亚氨基二乙酸-N-氧化物转化成N-膦酰基甲基甘氨酸： 水溶性钒化合物，亚铁盐和亚铜盐。
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公开(公告)号：US5047579A
公开(公告)日：1991-09-10
申请号：US543002
申请日：1990-06-25
IPC分类号： C07F9/38
CPC分类号： C07F9/3813
摘要： An improved process is disclosed for the preparation of N-phosphonomethylglycine by the oxidation of N-phosphonomethyliminodiacetic acid. In the process N-phosphonomethyliminodiacetic acid is oxidized with a peroxide to form an intermediate, N-phosphonomethyliminodiacetic acid-N-oxide, and thereafter, adding a metabisulfite compound in the presence of a molybdenum compound to convert the intermediate to N-phosphonomethylglycine.
摘要翻译： 公开了通过N-膦酰甲基亚氨基二乙酸的氧化制备N-膦酰基甲基甘氨酸的改进方法。 在该方法中，N-膦酰甲基亚氨基二乙酸用过氧化物氧化形成中间体N-膦酰甲基亚氨基二乙酸-N-氧化物，然后在钼化合物的存在下加入偏亚硫酸氢盐化合物，将中间体转化为N-膦酰基甲基甘氨酸。
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公开(公告)号：US4937376A
公开(公告)日：1990-06-26
申请号：US356484
申请日：1989-05-25
IPC分类号： B01J27/053 , B01J27/08 , B01J27/128 , B01J27/24 , B01J27/25 , B01J31/02 , B01J31/04 , B01J31/22 , B01J31/26 , C07B61/00 , C07F9/38 , C07F9/40
CPC分类号： C07F9/3813
摘要： A process for the production of N-phosphonomethylglycine comprising contacting N-phosphonomethyliminoacetic acid with a molecular oxygen-containing gas in the presence of a catalyst selected from the group consisting of the salts and salt complexes of manganese, cobalt, iron, nickel, chromium, ruthenium, aluminum, molybdenum, vanadium and cerium, and an effective amount of a quinone or hydroquinone.
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4.发明授权Amine salts of 1,4,2-oxazaphospholidine-4-acetic acid, 2-alkoxy-2-oxides 失效1,4-二氧杂磷杂环丁烷-4-乙酸，2-烷氧基-2-氧化物的胺盐
公开(公告)号：US4889906A
公开(公告)日：1989-12-26
申请号：US276009
申请日：1988-11-25
IPC分类号： A01N57/36 , C07F9/6584
CPC分类号： A01N57/36 , C07F9/6584
摘要： The compounds 1,4,2-oxazaphospholidine-4-acetic acid, 2-alkoxy-2-oxides and their trialkylamine salts represented by the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are individually selected from the group consisting of alkyl having from one to about four carbon atoms are useful as post emergent, selective herbicides and plant growth regulators.
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公开(公告)号：US06184385B2
公开(公告)日：2001-02-06
申请号：US09292682
申请日：1999-04-16
IPC分类号： C07D41712
CPC分类号： C07D277/80
摘要： A process for the manufacture of a sulfenimide by reacting sulfenamide in slurry with a water immiscible organic solvent with an acid to yield a solvent slurry comprising sulfenimide product. The product is recovered from the solvent slurry by a method comprising the addition of water to the solvent slurry and the isolating of the product by a single filtration step. While water is added to the solvent slurry an azeotrope of solvent and water may be distilled under vacuum until substantially all solvent is separated from product and product becomes part of an aqueous slurry. Alternatively, water may be added to the solvent slurry while the resulting mixture is being agitated, followed by filtering the mixture in the single filtration step for recovery of product from the mixture.
摘要翻译： 通过使浆料中的次磺酰胺与与水不混溶的有机溶剂与酸反应制备亚磺酰亚胺的方法，以产生包含亚硫酰亚胺产物的溶剂浆料。 通过包括向溶剂浆料中加入水并通过单一过滤步骤分离产物的方法从溶剂浆料中回收产物。 当将水加入到溶剂浆料中时，溶剂和水的共沸物可以在真空下蒸馏，直到基本上所有溶剂与产物分离，并且产物成为含水浆料的一部分。 或者，可以在搅拌所得混合物的同时将水加入到溶剂淤浆中，然后在单过滤步骤中过滤混合物以从混合物中回收产物。
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公开(公告)号：US5023369A
公开(公告)日：1991-06-11
申请号：US543016
申请日：1990-06-25
CPC分类号： C07F9/3813
摘要： A process is provided to produce N-phosphonomethylglycine by the oxidation of N-phosphonomethyliminodiacetic acid to form an intermediate N-phosphonomethyliminodiacetic acid-N-oxide with a peroxide in the presence of an effective amount of a catalyst selected from the group consisting of water-soluble tungsten compounds and a mixture of water-soluble tungsten compounds and a water-soluble molybdenum compound to form the intermediate, and thereafter converting the intermediate N-phosphonomethyliminodiacetic acid-N-oxide to N-phosphonomethylglycine.
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公开(公告)号：US4965403A
公开(公告)日：1990-10-23
申请号：US267870
申请日：1988-11-07
IPC分类号： C07F20060101 , C07F9/38
CPC分类号： C07F9/3813
摘要： There is disclosed a process for producing the alkali metal salts of N-phosphonomethylglycine which comprises heating to an elevated temperature a di-alkali metal salt of N-alkyl-N-(2-hydroxyethyl)aminomethylphosphonic acid.
摘要翻译： 公开了N-膦酰基甲基甘氨酸的碱金属盐的制造方法，其包括将N-烷基-N-（2-羟乙基）氨基甲基膦酸的二碱金属盐升温至高温。
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公开(公告)号：US4952723A
公开(公告)日：1990-08-28
申请号：US386738
申请日：1989-07-31
IPC分类号： B01J27/053 , B01J27/08 , B01J27/128 , B01J27/24 , B01J27/25 , B01J31/02 , B01J31/04 , B01J31/22 , B01J31/26 , C07B61/00 , C07F9/38 , C07F9/40
CPC分类号： C07F9/3813
摘要： A process for the production of N-phosphonomethylglycine comprising contacting N-phosphonomethyliminodiacetic acid with a molecular oxygen-containing gas in the presence of a catalyst selected from the group consisting of the salts and salt complexes of manganese, cobalt, iron, nickel, chromium, ruthenium, aluminum, moleybdenum, vanadium and cerium, and an effective amount of a dipyridyl compound.
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公开(公告)号：US06187937B1
公开(公告)日：2001-02-13
申请号：US09264989
申请日：1998-12-23
IPC分类号： C07C5004
CPC分类号： C07C249/02 , C07C251/22
摘要： A hydroxydiphenylamine compound can be converted to an N-phenylquinoneimine by reacting the hydroxydiphenylamine with oxygen or an oxygen containing gas in the presence of a modified activated carbon catalyst, the catalyst having had surface oxides removed therefrom.
摘要翻译： 在改性的活性炭催化剂存在下，羟基二苯胺与氧或含氧气体反应，可以将羟基二苯胺化合物转化成N-苯基醌亚胺。
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10.发明授权Preparation of quinoneimines from hydroxyphenylamines using a hypochlorite as an oxidation agent 失效使用次氯酸盐作为氧化剂由羟基苯胺制备醌亚胺
公开(公告)号：US6072061A
公开(公告)日：2000-06-06
申请号：US272346
申请日：1999-03-19
IPC分类号： C07B61/00 , C07C249/02 , C07C251/22 , C07C50/04
CPC分类号： C07C249/02
摘要： A hydroxyphenylamine compound can be converted, with high yield and high selectivity, into its corresponding quinoneimine by reacting the hydroxyphenylamine with a hypochlorite oxidation reactant.
摘要翻译： 羟基苯胺化合物可通过羟基苯胺与次氯酸盐氧化反应物反应，以高产率和高选择性转化成相应的醌亚胺。
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