公开(公告)号：US09012084B2

公开(公告)日：2015-04-21

申请号：US13990200

申请日：2011-12-16

Applicant: Chihiro Yada ,  Kazuto Ide

Inventor： Chihiro Yada ,  Kazuto Ide

IPC: H01G11/50 ,  H01M4/485 ,  H01M4/131 ,  H01M4/62 ,  H01M10/052 ,  H01M4/04 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0562

CPC classification number: H01M4/485 ,  H01G11/50 ,  H01M4/0471 ,  H01M4/131 ,  H01M4/505 ,  H01M4/525 ,  H01M4/62 ,  H01M10/052 ,  H01M10/0562 ,  H01M2300/0071 ,  Y02E60/122 ,  Y02E60/13

Abstract: A secondary battery is provided with a positive electrode active material layer a containing a positive electrode active material, a negative electrode active material layer containing a negative electrode active material, an electrolyte layer formed between the positive electrode active material layer and the negative electrode active material layer, and a modification material disposed at an interface between an electrolyte material and at least one electrode active material among the positive electrode active material and the negative electrode active material, and having a higher relative permittivity than the relative permittivity of the electrolyte material.

Abstract translation: 二次电池设置有含有正极活性物质的正极活性物质层a，含有负极活性物质的负极活性物质层，在正极活性物质层和负极活性物质之间形成的电解质层 以及设置在所述正极活性物质和所述负极活性物质中的所述电解质材料与所述至少一种电极活性物质之间的界面处的相对介电常数高于所述电解质材料的相对介电常数的相对介电常数的改性材料。

公开(公告)号：US20140287160A1

公开(公告)日：2014-09-25

申请号：US14117823

申请日：2012-07-20

Applicant: Brian Elliott Hayden ,  Christopher Edward Lee ,  Duncan Clifford Alan Smith ,  Mark Stephen Beal ,  Xiaojuan Lu ,  Chihiro Yada

Inventor： Brian Elliott Hayden ,  Christopher Edward Lee ,  Duncan Clifford Alan Smith ,  Mark Stephen Beal ,  Xiaojuan Lu ,  Chihiro Yada

IPC: C01B25/30 ,  C01B21/20 ,  C01B25/45

CPC classification number: C01B25/30 ,  C01B21/20 ,  C01B25/45 ,  C23C14/06 ,  C23C14/24 ,  C30B23/066 ,  C30B23/08 ,  H01M4/5825 ,  H01M10/052

Abstract: The present invention provides a vapour deposition process for the preparation of a phosphate compound, wherein the process comprises providing each component element of the phosphate compound as a vapour, and co-depositing the component element vapours on a common substrate, wherein the component elements react on the substrate to form the phosphate compound.

Abstract translation: 本发明提供了一种用于制备磷酸盐化合物的气相沉积方法，其中该方法包括提供磷酸盐化合物的每个组分元素作为蒸气，并将组分元素蒸气共沉积在共同的基底上，其中组分元素反应 在底物上形成磷酸盐化合物。

公开(公告)号：US20130071757A1

公开(公告)日：2013-03-21

申请号：US13640413

申请日：2010-04-13

Applicant: Chihiro Yada ,  Hiroshi Suyama ,  Shoji Yokoishi ,  Brian Elliott Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

Inventor： Chihiro Yada ,  Hiroshi Suyama ,  Shoji Yokoishi ,  Brian Elliott Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

IPC: H01M10/0562

CPC classification number: H01M10/0562 ,  H01B1/06 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0561 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011

Abstract: A main object of the present invention is to provide a solid electrolyte material having excellent Li ion conductivity. To attain the object, the present invention provides a solid electrolyte material represented by a general formula: Lix(La1-aM1a)y(Ti1-bM2b)zOδ, characterized in that “x”, “y”, and “z” satisfy relations of x+y+z=1, 0.652≦x/(x+y+z)≦0.753, and 0.167≦y/(y+z)≦0.232; “a” is 0≦a≦1; “b” is 0≦b≦1; “δ” is 0.8≦δ≦1.2; “M1” is at least one selected from the group consisting of Sr, Na, Nd, Pr, Sm, Gd, Dy, Y, Eu, Tb, and Ba; and “M2” is at least one selected from the group consisting of Mg, W, Mn, Al, Ge, Ru, Nb, Ta, Co, Zr, Hf, Fe, Cr, and Ga.

Abstract translation: 本发明的主要目的是提供具有优异的Li离子传导性的固体电解质材料。 为了达到上述目的，本发明提供一种由通式Lix（La1-aM1a）y（Ti1-bM2b）zOδ表示的固体电解质材料，其特征在于x，y和z满足x + y + z = 1，0.652＆nlE; x /（x + y + z）＆nlE; 0.753和0.167＆nlE; y /（y + z）＆nlE; 0.232; a是0＆nlE; a＆nlE; 1; b为0＆nlE; b＆nlE; 1; δ为0.8＆nlE;δ＆nlE; 1.2; M1是选自Sr，Na，Nd，Pr，Sm，Gd，Dy，Y，Eu，Tb和Ba中的至少一种; M2是选自Mg，W，Mn，Al，Ge，Ru，Nb，Ta，Co，Zr，Hf，Fe，Cr和Ga中的至少一种。

公开(公告)号：US20130022878A1

公开(公告)日：2013-01-24

申请号：US13386167

申请日：2010-04-13

Applicant: Chihiro Yada ,  Hiroshi Suyama ,  Shoji Yokoishi ,  Brian Elliot Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

Inventor： Chihiro Yada ,  Hiroshi Suyama ,  Shoji Yokoishi ,  Brian Elliot Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

IPC: H01M10/0562

CPC classification number: H01M10/052 ,  H01B1/06 ,  H01M10/0562 ,  H01M2300/0071 ,  Y02T10/7011

Abstract: A main object of the present invention is to provide a solid electrolyte material having excellent Li ion conductivity. To attain the object, the present invention provides a solid electrolyte material represented by a general formula: Lix(La1-aM1a)y(Ti1-bM2b)zOδ, wherein “x”, “y”, and “z” satisfy relations of x+y+z=1, 0.850≦x/(x+y+z)≦0.930, and 0.087≦y/(y+z)≦0.115; “a” is 0≦a≦1; “b” is 0≦b≦1; “67 ” is 0.8≦δ≦1.2; “M1” is at least one selected from the group consisting of Sr, Na, Nd, Pr, Sm, Gd, Dy, Y, Eu, Tb, and Ba; and “M2” is at least one selected from the group consisting of Mg, W, Mn, Al, Ge, Ru, Nb, Ta, Co, Zr, Hf, Fe, Cr, and Ga.

Abstract translation: 本发明的主要目的是提供具有优异的Li离子传导性的固体电解质材料。 为了达到上述目的，本发明提供一种由通式Lix（La1-aM1a）y（Ti1-bM2b）zOδ表示的固体电解质材料，其中x，y和z满足x + y + z = 1的关系 ，0.850＆nlE; x /（x + y + z）＆nlE; 0.930和0.087＆nlE; y /（y + z）＆nlE; 0.115; a是0＆nlE; a＆nlE; 1; b为0＆nlE; b＆nlE; 1; 67为0.8＆nlE;δ＆nlE; 1.2; M1是选自Sr，Na，Nd，Pr，Sm，Gd，Dy，Y，Eu，Tb和Ba中的至少一种; M2是选自Mg，W，Mn，Al，Ge，Ru，Nb，Ta，Co，Zr，Hf，Fe，Cr和Ga中的至少一种。

公开(公告)号：US09300008B2

公开(公告)日：2016-03-29

申请号：US13512649

申请日：2010-04-13

Applicant: Chihiro Yada ,  Shoji Yokoishi ,  Brian Elliott Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

Inventor： Chihiro Yada ,  Shoji Yokoishi ,  Brian Elliott Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

IPC: H01M10/0562 ,  H01M10/052 ,  H01B1/12 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525

CPC classification number: H01M10/052 ,  H01B1/122 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0562 ,  H01M2300/0068 ,  H01M2300/0071 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011

Abstract: A main object of the present invention is to provide a Li—La—Ti—O based solid electrolyte material having high Li ion conductivity in the crystal grain boundary. The present invention attains the object by providing solid electrolyte material represented by a general formula: Li3x(La(2/3−x)−aM1a) (Ti1−bM2b)O3, wherein “x” is 0

Abstract translation: 本发明的主要目的在于提供在晶界上具有高Li离子传导性的Li-La-Ti-O基固体电解质材料。 本发明的目的是提供由通式Li 3 x（La（2/3-x）-aMa）（Ti1-bM2b）O3表示的固体电解质材料，其中“x”为0

公开(公告)号：US08795902B2

公开(公告)日：2014-08-05

申请号：US13386167

申请日：2010-04-13

Applicant: Chihiro Yada ,  Hiroshi Suyama ,  Shoji Yokoishi ,  Brian Elliot Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

Inventor： Chihiro Yada ,  Hiroshi Suyama ,  Shoji Yokoishi ,  Brian Elliot Hayden ,  Thierry Le Gall ,  Duncan Clifford Alan Smith ,  Christopher Edward Lee

IPC: H01M10/0562

CPC classification number: H01M10/052 ,  H01B1/06 ,  H01M10/0562 ,  H01M2300/0071 ,  Y02T10/7011

Abstract: A main object of the present invention is to provide a solid electrolyte material having excellent Li ion conductivity. To attain the object, the present invention provides a solid electrolyte material represented by a general formula: Lix(La1-aM1a)y(Ti1-bM2b)zOδ, wherein “x”, “y”, and “z” satisfy relations of x+y+z=1, 0.850≦x/(x+y+z)≦0.930, and 0.087≦y/(y+z)≦0.115; “a” is 0≦a≦1; “b” is 0≦b≦1; “δ” is 0.8≦δ≦1.2; “M1” is at least one selected from the group consisting of Sr, Na, Nd, Pr, Sm, Gd, Dy, Y, Eu, Tb, and Ba; and “M2” is at least one selected from the group consisting of Mg, W, Mn, Al, Ge, Ru, Nb, Ta, Co, Zr, Hf, Fe, Cr, and Ga.

Abstract translation: 本发明的主要目的是提供具有优异的Li离子传导性的固体电解质材料。 为了达到上述目的，本发明提供一种由以下通式表示的固体电解质材料：Lix（La1-aM1a）y（Ti1-bM2b）zOδ，其中“x”，“y”和“z”满足关系x + y + z = 1，0.850＆nlE; x /（x + y + z）＆nlE; 0.930和0.087＆nlE; y /（y + z）＆nlE; “a”为0＆nlE; a＆nlE; 1; “b”为0＆nlE; b＆nlE; 1; “δ”为0.8＆nlE;δ＆nlE; 1.2; “M1”是选自Sr，Na，Nd，Pr，Sm，Gd，Dy，Y，Eu，Tb和Ba中的至少一种; “M2”为选自Mg，W，Mn，Al，Ge，Ru，Nb，Ta，Co，Zr，Hf，Fe，Cr和Ga中的至少一种。

公开(公告)号：US08586139B2

公开(公告)日：2013-11-19

申请号：US13306434

申请日：2011-11-29

Applicant: Chihiro Yada ,  Brian E. Hayden ,  Duncan C. A. Smith ,  Christopher E. Lee

Inventor： Chihiro Yada ,  Brian E. Hayden ,  Duncan C. A. Smith ,  Christopher E. Lee

IPC: C23C16/00 ,  B05D3/06 ,  H01B1/00

CPC classification number: H01B1/08 ,  C04B35/462 ,  C04B2235/3203 ,  C04B2235/3227 ,  C23C14/08 ,  H01M4/0423 ,  H01M4/1391 ,  H01M4/483 ,  H01M10/052 ,  H01M10/0562 ,  Y02T10/7011

Abstract: An object of the present invention is to simplify the process of producing an electrode composite material. Disclosed is a method for producing an electrode composite material, comprising the steps of: preparing a material comprising Li, La, Ti and O and heating the material, wherein the composition ratio between Li, La and Ti of the material is in the range of a triangle having three vertices at LiO0.5:LaO1.5:TiO2=23:24:53, LiO0.5:LaO1.5:TiO2=5:36:59 and LiO0.5:LaO1.5:TiO2=8:28:64 in the LiO0.5—LaO1.5—TiO2 triangular diagram.

Abstract translation: 本发明的目的在于简化电极复合材料的制造工序。 公开了一种电极复合材料的制造方法，包括以下步骤：制备包含Li，La，Ti和O的材料并加热材料，其中材料的Li，La和Ti的组成比在 在LiO0.5：LaO1.5:TiO2 = 23:24:53，Li0.5:LaO1.5:TiO2 = 5:36:59和Li0.5：LaO1.5:TiO2 = 8的三角形： 在LiO0.5-LaO1.5-TiO2三角图中为28:64。

公开(公告)号：US20130260250A1

公开(公告)日：2013-10-03

申请号：US13990200

申请日：2011-12-16

Applicant: Chihiro Yada ,  Kazuto Ide

Inventor： Chihiro Yada ,  Kazuto Ide

IPC: H01M4/485

CPC classification number: H01M4/485 ,  H01G11/50 ,  H01M4/0471 ,  H01M4/131 ,  H01M4/505 ,  H01M4/525 ,  H01M4/62 ,  H01M10/052 ,  H01M10/0562 ,  H01M2300/0071 ,  Y02E60/122 ,  Y02E60/13

Abstract: A secondary battery is provided with a positive electrode active material layer a containing a positive electrode active material, a negative electrode active material layer containing a negative electrode active material, an electrolyte layer formed between the positive electrode active material layer and the negative electrode active material layer, and a modification material disposed at an interface between an electrolyte material and at least one electrode active material among the positive electrode active material and the negative electrode active material, and having a higher relative permittivity than the relative permittivity of the electrolyte material.

Abstract translation: 二次电池设置有含有正极活性物质的正极活性物质层a，含有负极活性物质的负极活性物质层，在正极活性物质层和负极活性物质之间形成的电解质层 以及设置在所述正极活性物质和所述负极活性物质中的所述电解质材料与所述至少一种电极活性物质之间的界面处的相对介电常数高于所述电解质材料的相对介电常数的相对介电常数的改性材料。

公开(公告)号：US20130183589A1

公开(公告)日：2013-07-18

申请号：US13820777

申请日：2011-09-27

Applicant: Yoshitaka Minamida ,  Chihiro Yada ,  Keiichi Kohama

Inventor： Yoshitaka Minamida ,  Chihiro Yada ,  Keiichi Kohama

IPC: H01M10/0562 ,  H01M10/052

CPC classification number: H01M10/0562 ,  C04B35/447 ,  C04B35/62685 ,  C04B2235/3203 ,  C04B2235/3217 ,  C04B2235/3251 ,  C04B2235/3256 ,  C04B2235/3258 ,  C04B2235/3268 ,  C04B2235/3279 ,  C04B2235/3287 ,  C04B2235/447 ,  C04B2235/5436 ,  C04B2235/763 ,  C04B2235/80 ,  H01M4/505 ,  H01M4/525 ,  H01M10/052 ,  H01M10/0585 ,  H01M2300/002 ,  Y02T10/7011

Abstract: A battery sintered body, in which charge-discharge properties are restrained from deteriorating in accordance with sintering, and a producing method thereof. A battery sintered body includes: a phosphate compound of a nasicon type as a solid electrolyte material; and any one of an oxide of a spinel type containing at least one of Ni and Mn, LiCoO2 and a transition metal oxide as an active material, wherein a component except a component of the above-mentioned solid electrolyte material and a component of the above-mentioned active material is not detected on an interface between the above-mentioned solid electrolyte material and the above-mentioned active material in analyzing by an X-ray diffraction method.

Abstract translation: 根据烧结抑制充放电特性的电池烧结体及其制造方法。 电池烧结体包括：作为固体电解质材料的鼻型的磷酸盐化合物; 和包含Ni和Mn中的至少一种的尖晶石型氧化物，作为活性物质的LiCoO 2和过渡金属氧化物中的任一种，其中除上述固体电解质材料的成分以外的成分和上述成分 在通过X射线衍射法进行分析时，在上述固体电解质材料和上述活性物质的界面上未检测到上述活性物质。

公开(公告)号：US20130093130A1

公开(公告)日：2013-04-18

申请号：US13703485

申请日：2010-07-01

Applicant: Chihiro Yada ,  Yoshitaka Minamida ,  Keiichi Kohama

Inventor： Chihiro Yada ,  Yoshitaka Minamida ,  Keiichi Kohama

IPC: H01M4/04

CPC classification number: H01M4/0471 ,  B28B1/16 ,  B32B18/00 ,  B82Y30/00 ,  C01B25/45 ,  C04B35/01 ,  C04B35/447 ,  C04B35/62805 ,  C04B35/62892 ,  C04B35/62897 ,  C04B2235/3203 ,  C04B2235/3217 ,  C04B2235/3275 ,  C04B2235/3287 ,  C04B2235/447 ,  C04B2235/5436 ,  C04B2235/5454 ,  C04B2235/76 ,  C04B2235/80 ,  C04B2237/34 ,  C04B2237/66 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/0585 ,  Y02E60/122 ,  Y02P70/54

Abstract: The present invention provides a method for producing a ceramic laminate capable of preventing coming-off of materials and warpage of the ceramic laminate by a heat treatment at a relatively-low temperature, and a ceramic laminate produced by the production method. Disclosed is a method for producing a ceramic laminate having a layer structure in which two or more layers are laminated, including: a step of producing a laminate including a first layer and a second layer, the first layer containing a solid electrolyte and the second layer containing at least composite particles obtained by covering an electrode active material with the solid electrolyte; and a step of performing a heat treatment on the laminate including the first and second layers at a temperature of 500° C. or more and less than 700° C.

Abstract translation: 本发明提供一种能够通过在较低温度下的热处理来防止材料脱落和陶瓷层叠体翘曲的陶瓷层叠体的制造方法以及通过该制造方法制造的陶瓷层叠体。 公开了一种具有层叠有两层以上层的层结构体的陶瓷层叠体的制造方法，包括：制造包含第一层和第二层的层叠体的工序，含有固体电解质的第一层和第二层 至少含有通过用固体电解质覆盖电极活性材料获得的复合颗粒; 以及在500℃以上且小于700℃的温度下对包含第一层和第二层的层压体进行热处理的步骤。