摘要:
The present invention provides a sequential and efficient method of assembling a battery with a desired number of layers while reliably separating positive and negative electrode sides from each other with one or more separator structures. According to the invention, the method of assembling a battery includes stacking one or multiple combinations each comprising a frame and a positive electrode plate to be disposed in a region defined by the frame and one or multiple combinations each comprising a frame and a negative electrode plate to be disposed in a region defined by the frame, once or alternately, such that the positive and adjacent negative electrode plates are separated from each other by a separator structure and the periphery of the separator structure is held between the adjacent frames. The separator structure includes a separator exhibiting hydroxide ion conductivity and water impermeability.
摘要:
Disclosed herein are garnet material compositions, e.g., lithium-stuffed garnets and lithium-stuffed garnets doped with alumina, which are suitable for use as electrolytes and catholytes in solid state battery applications. Also disclosed herein are lithium-stuffed garnet thin films having fine grains therein. Also disclosed herein are methods of making and using lithium-stuffed garnets as catholytes, electrolytes and/or anolytes for all solid state lithium rechargeable batteries. Also disclosed herein are electrochemical devices which incorporate these garnet catholytes, electrolytes and/or anolytes. Also disclosed herein are methods for preparing dense thin (
摘要:
Provided is a nonaqueous electrolyte secondary battery including a porous film containing polyolefin as a main component, the nonaqueous electrolyte secondary battery separator having a parameter X of not more than 20, the parameter X being calculated based on the following equation: X=100×|MD tan δ−TD tan δ|/{(MD tan δ+TD tan δ)/2}, where MD tan δ is tan δ in a machine direction of the porous film and TD tan δ is tan δ in a transverse direction of the porous film, MD tan δ and TD tan δ each being obtained by viscoelasticity measurement carried out with respect to the porous film at a frequency of 10 Hz and a temperature of 90° C., the nonaqueous electrolyte secondary battery separator making it possible to reduce an increase in internal resistance which increase is caused by repeated charge and discharge.
摘要:
To provide an ultrahigh molecular weight polyethylene stretched microporous film having high strength and heat resistance.An ultrahigh molecular weight polyethylene stretched microporous film, which comprises at least an ultrahigh molecular weight polyethylene having an intrinsic viscosity ([η]) of at least 7 dl/g and at most 60 dl/g, and which has a porosity of at least 10% and at most 70% and a breaking stress of at least 1 MPa when melt-stretched at 150° C., which uses, as the ultrahigh molecular weight polyethylene, preferably ultrahigh molecular weight polyethylene particles which satisfy (1) an intrinsic viscosity ([η]) of at least 7 dl/g and at most 60 dl/g, (2) a bulk density of at least 130 kg/m3 and at most 700 kg/m3, and (3) ΔTm (ΔTm=Tm1−Tm2) of at least 9° C. and at most 30° C., which is a difference between the melting point (Tm1) at the 1st scanning and the melting point (Tm2) at the 2nd scanning measured by DSC.
摘要:
One object is to provide a power storage device including an electrolyte using a room-temperature ionic liquid which includes a univalent anion and a cyclic quaternary ammonium cation having excellent reduction resistance. Another object is to provide a high-performance power storage device. A room-temperature ionic liquid which includes a cyclic quaternary ammonium cation represented by a general formula (G1) below is used for an electrolyte of a power storage device. In the general formula (G1), one or two of R1 to R5 are any of an alkyl group having 1 to 20 carbon atoms, a methoxy group, a methoxymethyl group, and a methoxyethyl group. The other three or four of R1 to R5 are hydrogen atoms. A− is a univalent imide anion, a univalent methide anion, a perfluoroalkyl sulfonic acid anion, tetrafluoroborate (BF4−), or hexafluorophosphate (PF6−).
摘要:
LiPO2F2, an electrolyte salt additive for batteries, is manufactured by the reaction of POF3, PF5 or mixtures thereof, with Li3PO4 forming a reaction mixture comprising LiPO2F2. When POF3 is applied, the reaction mixture which contains essentially only LiPO2F2 is preferably extracted from the reaction mixture with a solvent which also is applicable as solvent for lithium ion batteries. If PF5 is applied, then, depending on the molar ratio of PF5 and Li3PO4, the reaction mixture also contains LiF and/or LiPF6. To isolate pure LiPO2F2 from LiF, the reaction mixture containing essentially only LiPO2F2 and LiF may for example, be extracted with dimethoxyethane, acetone, dimethyl carbonate or propylene carbonate. To isolate pure LiPO2F2 from LiPF6, the reaction mixture containing essentially only these constituents is preferably extracted with a solvent which also is applicable as solvent for the LiPF6 in lithium ion batteries to dissolve and remove LiPF6.
摘要:
One object is to provide a power storage device including an electrolyte using a room-temperature ionic liquid which includes a univalent anion and a cyclic quaternary ammonium cation having excellent reduction resistance. Another object is to provide a high-performance power storage device. A room-temperature ionic liquid which includes a cyclic quaternary ammonium cation represented by a general formula (G1) below is used for an electrolyte of a power storage device. In the general formula (G1), one or two of R1 to R5 are any of an alkyl group having 1 to 20 carbon atoms, a methoxy group, a methoxymethyl group, and a methoxyethyl group. The other three or four of R1 to R5 are hydrogen atoms. A− is a univalent imide anion, a univalent methide anion, a perfluoroalkyl sulfonic acid anion, tetrafluoroborate (BF4−), or hexafluorophosphate (PF6−).
摘要:
A glass ceramic is provided that has at least one crystal phase that conducts lithium ions and a total content of Ta2O5 of at least 0.5 wt. %. The glass ceramic finds utility as a component selected from the group consisting of a lithium ion battery, an electrolyte in a lithium ion battery, an electrode component in a lithium ion battery, an additive to a liquid electrolyte in a lithium ion battery, a coating on an electrode in a lithium ion battery, and combinations thereof.
摘要翻译:提供玻璃陶瓷,其具有至少一个导电锂离子的结晶相,并且Ta 2 O 5的总含量为至少0.5重量%。 %。 玻璃陶瓷作为选自锂离子电池,锂离子电池中的电解质,锂离子电池中的电极成分,锂离子电池中的液体电解质的添加剂,涂层 在锂离子电池中的电极上,以及它们的组合。
摘要:
To provide a non-aqueous electrolyte secondary battery having high capacity and superior safety and cycle characteristics.The present invention is a non-aqueous electrolyte secondary battery including an electrode assembly and a non-aqueous electrolyte, the electrode assembly having a positive electrode, a negative electrode and a separator separating the positive electrode and the negative electrode, the non-aqueous electrolyte secondary battery characterized in that the separator has a three-layer laminated structure, the melting point of the middle layer being lower than either of the two outer layers, and the non-aqueous electrolyte including lithium bis(oxalato)borate.
摘要:
It is difficult to display the polarity of terminal electrodes of lithium ion batteries. With conventional lithium ion secondary batteries, since different materials are employed for the active substances that make up a positive electrode and a negative electrode, problems arise if the polarities of the electrodes are mistaken when the battery is installed. A battery has been developed using an active substance material functioning as a secondary battery even when the same material is used for the active substances that make up the positive electrode and the negative electrode, and a non-polar secondary battery has been produced. With no distinction between the terminal electrodes, attention does not need to be paid to the direction of installation, thereby simplifying the installation step. Furthermore, since there is no need to manufacture a positive electrode layer and a negative electrode layer separately, the step for manufacturing the battery is also simplified.