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公开(公告)号：US4406867A
公开(公告)日：1983-09-27
申请号：US339166
申请日：1982-01-13
CPC分类号： B01D53/1493 , B01D53/1425 , B01D53/1475 , C01B13/0285 , C01B21/0411 , C01B21/0488 , C01B23/00 , C01B3/52 , C07C7/11 , C01B2203/0415 , C01B2203/0465 , C01B2203/0475 , C01B2203/0485 , C01B2203/0495 , C01B2210/0051 , C01B2210/0056 , C01B2210/0057 , C01B2210/0062 , C01B2210/0064 , C01B2210/0067 , C01B2210/0068 , C01B2210/0071 , Y02C10/06 , Y02P20/152
摘要： Regenerative process for the purification of a non-reacting industrial gas stream by removal of trace amounts of carbon dioxide therefrom, comprising contacting said gas stream with non-aqueous liquid solution of at least one member selected from the group consisting of: (a) hydroxides and weak acid salts of sodium, potassium, and lithium and (b) specific liquid aliphatic polyhydric alcohol; separating the purified industrial gas from the reaction products of said contacting step including said solution; increasing said reaction products stream to an elevated temperature up to 200.degree. C.; reducing the partial pressure of carbon dioxide in the vapor phase above said reaction product stream; separating carbon dioxide from said reaction product stream; and recycling the treated reaction product stream to said liquid body of said solution for contacting a further quantity of said industrial gas stream.
摘要翻译： 通过从其中除去痕量的二氧化碳来净化非反应性工业气体流的再生方法，包括使所述气流与选自以下的至少一种的非水液体溶液接触：（a）氢氧化物 和钠，钾和锂的弱酸盐和（b）特定的液体脂族多元醇; 将纯化的工业气体与包括所述溶液的所述接触步骤的反应产物分离; 将所述反应产物流增加至高达200℃的升高温度; 降低在所述反应产物流之上的气相中二氧化碳的分压; 从所述反应产物流中分离二氧化碳; 并将经处理的反应产物流再循环到所述溶液的液体中，以接触另外数量的所述工业气流。
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2.发明授权Catalyst for regulating the molecular weight distribution of ethylene polymers 失效用于调节乙烯聚合物分子量分布的催化剂
公开(公告)号：US4923938A
公开(公告)日：1990-05-08
申请号：US339590
申请日：1989-04-14
申请人： Sun-Chueh Kao , Kevin J. Cann , Frederick J. Karol , Arthur E. Marcinkowsky , Mark G. Goode , Eugene H. Theobald
发明人： Sun-Chueh Kao , Kevin J. Cann , Frederick J. Karol , Arthur E. Marcinkowsky , Mark G. Goode , Eugene H. Theobald
IPC分类号： C08F10/00
CPC分类号： C08F10/00
摘要： A vanadium-based catalyst is treated with certain oxygen-containing compounds as a means of narrowing and effectively regulating the molecular weight distribution of the polymers produced with the catalyst.
摘要翻译： 用某些含氧化合物处理钒基催化剂作为缩小并有效调节用催化剂生产的聚合物的分子量分布的手段。
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公开(公告)号：US4772736A
公开(公告)日：1988-09-20
申请号：US124084
申请日：1987-11-23
摘要： A process for the preparation of aluminoxanes comprising introducing, under reaction conditions, at least one stream of water beneath the surface of an agitated solution of a hydrocarbyl aluminum compound in such a manner that the stream of water is essentially immediately dispersed on contact with the solution.
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公开(公告)号：US4313916A
公开(公告)日：1982-02-02
申请号：US141141
申请日：1980-04-17
CPC分类号： C07C7/11 , B01D53/1425 , B01D53/1475 , B01D53/1493 , C01B13/0285 , C01B21/0411 , C01B21/0488 , C01B23/00 , C01B3/52 , C01B2203/0415 , C01B2203/0465 , C01B2203/0475 , C01B2203/0485 , C01B2203/0495 , C01B2210/0051 , C01B2210/0056 , C01B2210/0057 , C01B2210/0062 , C01B2210/0064 , C01B2210/0067 , C01B2210/0068 , C01B2210/0071 , Y02C10/06 , Y02P20/152
摘要： A process is disclosed for the purification of an inert or non-reacting gas such as lower mono-olefins by the removal of trace amounts of reacting impurities such as carbon dioxide therefrom, comprising passing said gas through an essentially non-aqueous liquid solution of alkali or alkaline earth metal hydroxides and/or weak acid salts and certain selected liquid polyhydric alcohols.
摘要翻译： 公开了通过从其中除去痕量的反应杂质如二氧化碳来纯化惰性或非反应性气体如低级单烯烃的方法，包括使所述气体通过基本上非水性的碱性液体溶液 或碱土金属氢氧化物和/或弱酸盐和某些选定的液体多元醇。
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5.发明授权
公开(公告)号：US4220803A
公开(公告)日：1980-09-02
申请号：US919481
申请日：1978-06-27
CPC分类号： C07C45/38 , C07C51/235
摘要： A process for producing acetic acid and acetaldehyde from ethanol which comprises contacting a mixture of ethanol and oxygen with a supported copper oxide catalyst essentially free of barium, the mole ratio of oxygen to ethanol being from about 0.1 to about 0.5.
摘要翻译： 一种从乙醇生产乙酸和乙醛的方法，包括使乙醇和氧气的混合物与基本上不含钡的负载氧化铜催化剂接触，氧气与乙醇的摩尔比为约0.1至约0.5。
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6.发明授权Ethylene polymerization using a titanium and vanadium catalyst system in staged reactors 失效在分段反应器中使用钛和钒催化剂体系的乙烯聚合
公开(公告)号：US5442018A
公开(公告)日：1995-08-15
申请号：US221845
申请日：1994-04-01
申请人： Kevin J. Cann , James W. Nicoletti , Frederick J. Karol , Arthur E. Marcinkowsky , Thomas E. Spriggs , Mark C. Hwu
发明人： Kevin J. Cann , James W. Nicoletti , Frederick J. Karol , Arthur E. Marcinkowsky , Thomas E. Spriggs , Mark C. Hwu
IPC分类号： C08F2/34 , C08F10/02 , C08F210/16 , C08L23/04
CPC分类号： C08F10/02 , C08L23/04 , C08F210/16 , C08F2410/05
摘要： A process for producing polyethylene having a broad molecular weight distribution is provided, in which ethylene and optionally a comonomer are contacted in two reactors connected in series, one reactor containing a titanium-based catalyst and the other reactor containing a vanadium-based catalyst and a halohydrocarbon promoter, or alternatively, both reactors containing a mixed metal catalyst comprising both titanium and vanadium. In the latter case, the halohydrocarbon promoter is present in only one of the reactors to activate the vanadium sites of the catalyst and deactivate the titanium sites of the catalyst simultaneously.
摘要翻译： 提供了一种制备具有宽分子量分布的聚乙烯的方法，其中乙烯和任选的共聚单体在串联连接的两个反应器中接触，一个包含钛基催化剂的反应器和另一个含有钒基催化剂的反应器和 或者可选地，两个反应器都含有包含钛和钒的混合金属催化剂。 在后一种情况下，卤代烃促进剂仅存在于一个反应器中以活化催化剂的钒位点并同时使催化剂的钛位点失活。
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公开(公告)号：US5070057A
公开(公告)日：1991-12-03
申请号：US502678
申请日：1990-04-02
CPC分类号： C08F10/00
摘要： An improved support vanadium catalyst, especially an improved Beran et al. catalyst system and ethylene polymerization process in which the improvement derives from fixing the promoter to a component of the catalyst composition such that it is a molecularly structural component of the catalyst and thus is not separately fed to the polymerization reaction, but instead is part of the catalyst composition fed to the reaction.
摘要翻译： 改进的载体钒催化剂，特别是改进的Beran等 催化剂体系和乙烯聚合方法，其中改进来自于将催化剂固定到催化剂组合物的组分，使得其是催化剂的分子结构组分，因此不分别进料到聚合反应中，而是部分 催化剂组合物进料到反应中。
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公开(公告)号：US4892853A
公开(公告)日：1990-01-09
申请号：US251360
申请日：1988-09-30
CPC分类号： C08F10/02
摘要： A vanadium catalyst composition comprising:(i) the reaction product of a vanadium compound and an electron donor, which is a liquid, organic Lewis base in which the vanadium compound is soluble;(ii) a hydrocarbyl aluminum cocatalyst; and(iii) a promoter having the following formula:C.sub.3 (X).sub.a (F).sub.b (H).sub.cwherein X is chlorine, bromine, or iodine, and each X can be alike or differenta=an integer from 6 to 8b=an integer from 0 to 2c=an integer from 0 to 2a+b+c=8
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公开(公告)号：US4845067A
公开(公告)日：1989-07-04
申请号：US214587
申请日：1988-07-01
申请人： Sun-Chueh Kao , Kevin J. Cann , Frederick J. Karol , Arthur E. Marcinkowsky , Mark G. Goode , Eugene H. Theobald
发明人： Sun-Chueh Kao , Kevin J. Cann , Frederick J. Karol , Arthur E. Marcinkowsky , Mark G. Goode , Eugene H. Theobald
CPC分类号： C08F10/00 , Y10S526/901
摘要： A vanadium-based catalyst is treated with certain oxygen-containing compounds as a means of narrowing and effectively regulating the molecular weight distribution of the polymers produced with the catalyst.
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公开(公告)号：US4174353A
公开(公告)日：1979-11-13
申请号：US919420
申请日：1978-06-27
CPC分类号： C07C7/11 , C07C7/152 , Y02P30/464
摘要： There is disclosed a process for the separation of ethylene or propylene from a purified, multi-component gas stream produced from the thermal cracking of hydrocarbons and containing ethylene or propylene and other low molecular weight components comprising the steps of: introducing said multi-component gas stream into an aqueous silver salt solution stream to effect the absorption and/or complexing of said contained ethylene or propylene and reaction of trace acetylenes with the silver metal ions of such solution; venting of the silver salt solution stream at reduced pressure to remove the dissolved other low molecular weight components; treating the resulting silver salt solution stream to separate the absorbed and/or complexed ethylene or propylene from the silver salt stream; further treating the resultant silver salt solution stream to release the contained trace acetylenes therefrom and provide an aqueous silver salt stream; and recycling said aqueous silver salt stream to said introducing step.
摘要翻译： 公开了一种用于从烃的热裂解产生并含有乙烯或丙烯和其它低分子量组分的纯化多组分气流分离乙烯或丙烯的方法，包括以下步骤：引入所述多组分气体 流入银盐水溶液流中以实现所述含有乙烯或丙烯的吸收和/或络合以及痕量乙炔与该溶液的银金属离子的反应; 在减压下排出银盐溶液流以除去溶解的其它低分子量组分; 处理所得的银盐溶液流以从银盐流中分离吸收的和/或络合的乙烯或丙烯; 进一步处理所得的银盐溶液流以从其中释放所含的痕量乙炔，并提供银盐水流; 并将所述含水银盐流再循环到所述引入步骤。
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