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公开(公告)号：US08062746B2
公开(公告)日：2011-11-22
申请号：US10383523
申请日：2003-03-10
申请人： Ernest L. Lawton , Robert Rau
发明人： Ernest L. Lawton , Robert Rau
CPC分类号： H05K1/0366 , C03C25/26 , C03C25/47 , H05K2201/0212 , H05K2201/0239 , H05K2201/029 , H05K2203/127 , Y10T428/2927 , Y10T428/2933 , Y10T428/2938 , Y10T428/2962 , Y10T428/2964
摘要： A fiber strand comprising at least one fiber at least partially coated with a composition formed from at least one rosin, at least one cationic lubricant, at least one film forming material, at least one organosilane coupling agent, and at least one dispersion of polymeric particles. A fiber strand comprising at least one fiber at least partially coated with a composition formed from components comprising at least one rosin, at least one polymeric lubricant, at least one film forming material, at least one organosilane coupling agent, and at least one dispersion of polymeric particles. A fiber strand comprising at least one fiber at least partially coated with a starch-free composition comprising at least one rosin, at least one cationic lubricant, at least one film forming material, and at least one organosilane coupling agent. A fiber strand comprising at least one fiber at least partially coated with a starch-free composition comprising at least one rosin, at least one polymeric lubricant, at least one film forming material, and at least one organosilane coupling agent. A fiber strand comprising at least one fiber at least partially coated with a composition comprising at least one rosin, at least one silyated polyamine, at least one film forming material, and at least one organosilane coupling agent. Also provided are fabrics and composite materials comprising at least one of these fiber strands.
摘要翻译： 一种纤维束，其包含至少部分涂覆有由至少一种松香，至少一种阳离子润滑剂，至少一种成膜材料，至少一种有机硅烷偶联剂和至少一种聚合物颗粒分散体形成的组合物的纤维 。 一种纤维束，其包含至少部分涂覆有组合物的纤维，所述组合物由包含至少一种松香，至少一种聚合物润滑剂，至少一种成膜材料，至少一种有机硅烷偶联剂和至少一种有机硅烷偶联剂的组分形成， 聚合物颗粒。 一种纤维束，其包含至少部分地涂覆有无淀粉组合物的至少一种纤维，所述组合物包含至少一种松香，至少一种阳离子润滑剂，至少一种成膜材料和至少一种有机硅烷偶联剂。 一种纤维束，其包含至少部分地涂覆有无淀粉组合物的至少一种纤维，所述组合物包含至少一种松香，至少一种聚合物润滑剂，至少一种成膜材料和至少一种有机硅烷偶联剂。 一种纤维束，其包含至少部分地涂覆有包含至少一种松香，至少一种巯基多胺，至少一种成膜材料和至少一种有机硅烷偶联剂的组合物的纤维。 还提供了包含这些纤维束中的至少一种的织物和复合材料。
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2.发明授权Waterborn film-forming compositions containing alternating copolymers of isobutylene type monomers 失效含有异丁烯型单体的交替共聚物的含水成膜组合物公开(公告)号：US07101930B2
公开(公告)日：2006-09-05
申请号：US10887626
申请日：2004-07-09
IPC分类号： C08J3/00
CPC分类号： C09D201/02 , C08F8/00 , Y10T428/31504 , Y10T428/31855 , C08F10/00 , C08F20/00
摘要： A curable, aqueous film-forming composition is provided that includes a polymeric binder comprising reactive functional groups, a crosslinking agent having at least two functional groups that are reactive with the functional groups of the polymeric binder, and a copolymer flow control agent comprising at least 30 mol % of residues containing alternating residues from a donor monomer and from an acceptor monomer. The copolymer contains at least 15 mol % of an isobutylene type donor monomer. Components (a) and (b) are substantially hydrophobic and are prepared as an aqueous dispersion comprising polymeric microparticles, prepared by mixing components (a) and (b) together under high shear conditions.A multi-component composite coating composition is also provided, comprising a base coat deposited from a pigmented film-forming composition and a transparent topcoat applied over the base coat. The topcoat is deposited from the film-forming composition described above.
摘要翻译： 提供了一种可固化的水性成膜组合物，其包括含有反应性官能团的聚合物粘合剂，具有至少两个与聚合物粘合剂的官能团反应的官能团的交联剂，以及至少包含共聚物流动控制剂 30mol％的残余物含有来自供体单体和受体单体的交替残基。 共聚物含有至少15摩尔％的异丁烯型供体单体。 组分（a）和（b）基本上是疏水性的，并且被制备成包含通过在高剪切条件下将组分（a）和（b）混合在一起而制备的聚合物微粒的水分散体。 还提供了一种多组分复合涂料组合物，其包含由着色成膜组合物沉积的底涂层和涂覆在底涂层上的透明面漆。 面漆从上述成膜组合物沉积。
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公开(公告)号：US6004676A
公开(公告)日：1999-12-21
申请号：US522782
申请日：1995-09-01
申请人： Mikhail M. Girgis
发明人： Mikhail M. Girgis
CPC分类号： C03C25/28 , C03C25/1065 , C03C25/285 , C03C25/30 , C03C25/50 , G02B6/443 , Y10T428/1369 , Y10T428/2933 , Y10T428/2936 , Y10T428/2938 , Y10T428/2942 , Y10T428/2956 , Y10T428/2962 , Y10T428/2964
摘要： The present invention provides an optical fiber cable assembly including an optical fiber and a reinforcement strand including a plurality of sized glass fibers positioned about the optical fiber, the strand having thereon a dried residue of a secondary aqueous coating composition which is essentially free of a urethane-containing material and includes a first polymer prepared by vinyl addition polymerization of a first monomer component including a first vinyl aromatic monomer and an acrylic monomer and a second polymer different from the first polymer, the second polymer being prepared by vinyl addition polymerization of a second monomer component including a curable polymer of a second vinyl aromatic monomer, wherein the surface of the strand wicks water at a rate of less than about 25.4 millimeters (one inch) in about six hours at a temperature of about 25.degree. C. A method of reducing the wicking of water along the surface of a glass fiber strand is also provided.
摘要翻译： 本发明提供了一种光纤电缆组件，其包括光纤和加强线，所述加强线包括围绕光纤定位的多个尺寸的玻璃纤维，所述绞线上具有基本上不含氨基甲酸酯的第二水性涂料组合物的干燥残余物 含有第一聚合物，该第一聚合物是通过包含第一乙烯基芳族单体和丙烯酸单体的第一单体组分和不同于第一聚合物的第二聚合物的乙烯基加成聚合制备的，第二聚合物是通过第二聚合物 包括第二乙烯基芳族单体的可固化聚合物的单体组分，其中所述链的表面在约25℃的温度下在约6小时内以小于约25.4毫米（1英寸）的速率吸水。 还提供了沿着玻璃纤维束的表面减少水的芯吸。
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4.发明授权Glass fiber mats, thermosetting composites reinforced with the same and methods for making the same 失效玻璃纤维毡，热固性复合材料与其相同的加固方法和制造方法
公开(公告)号：US5910458A
公开(公告)日：1999-06-08
申请号：US866775
申请日：1997-05-30
IPC分类号： B29C70/08 , B29C70/16 , B29C70/24 , B29C70/50 , B32B5/26 , C03C25/26 , D04H13/00 , D04H1/74 , B32B5/06
CPC分类号： B32B5/26 , B29C70/083 , B29C70/16 , B29C70/24 , B29C70/50 , B29C70/502 , C03C25/26 , D04H3/004 , D04H3/105 , D04H3/12 , Y10T442/116 , Y10T442/2311 , Y10T442/2402 , Y10T442/2943 , Y10T442/2951 , Y10T442/604 , Y10T442/644 , Y10T442/667 , Y10T442/67 , Y10T442/682
摘要： The present invention provides a needled mat adapted to reinforce a thermosetting matrix material to form a composite, composites formed therefrom, and methods related thereto. The needled mat includes a primary layer of a plurality of unidirectional continuous glass fiber strands coated with a composition which is compatible with the thermosetting matrix material and a secondary layer positioned thereon of a plurality of randomly oriented, generally continuous and/or chopped glass fiber strands coated with a composition which is compatible with the thermosetting matrix material. The mat has a total surface weight ranging from about 1300 to about 11,500 grams per square meter.
摘要翻译： 本发明提供了一种针刺垫，其适于加强热固性基质材料以形成复合材料，由此形成的复合材料及其相关方法。 针刺垫包括涂覆有与热固性基质材料相容的组合物的多个单向连续玻璃纤维线的主层和位于其上的多个随机取向的，大致连续的和/或切割的玻璃纤维束的第二层 涂覆有与热固性基质材料相容的组合物。 垫的总表面重量为约1300至约11,500克/平方米。
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公开(公告)号：US5900133A
公开(公告)日：1999-05-04
申请号：US914600
申请日：1997-08-18
摘要： Describes a method of electrochemically converting amine hydrohalide, e.g., ethyleneamine hydrochloride, into free amine, e.g., free ethyleneamine. A three compartment electrolytic cell is provided having (1) a catholyte compartment containing a cathode assembly comprising a cathode and anion exchange membrane, (2) an anolyte compartment containing an anode assembly comprising an anode and a cation exchange membrane, and (3) an intermediate compartment separated from the catholyte and anolyte compartments by the anion and cation exchange membranes respectively. An aqueous solution of amine hydrohalide is charged to the catholyte compartment, while hydrogen halide solutions are charged to the intermediate and anolyte compartments. Direct current is passed through the electrolytic cell and an aqueous solution comprising free amine is removed from the catholyte compartment.
摘要翻译： 描述了将胺氢卤化物（例如乙烯胺盐酸盐）电化学转化成游离胺，例如游离亚乙基胺的方法。 提供一种三室电解池，其具有（1）阴极电解室，其包含阴极组件和阴离子交换膜;（2）阳极室，其包含阳极和阳离子交换膜;以及（3） 中间室分别通过阴离子和阳离子交换膜与阴极电解液和阳极电解质隔室分离。 将胺氢卤化物的水溶液加入到阴极电解液室中，同时将卤化氢溶液装入中间体和阳极电解液室。 直流电流通过电解槽，并从阴极电解液隔室除去包含游离胺的水溶液。
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6.发明授权Coating compositions with citric acid containing polymers for enhanced adhesion to substrates 失效含有柠檬酸的聚合物的涂料组合物，用于增强与基材的粘合性
公开(公告)号：US5891960A
公开(公告)日：1999-04-06
申请号：US928533
申请日：1997-09-12
IPC分类号： C08F8/14 , C08G59/42 , C09D133/06 , C09D163/00 , C08F8/30 , C09D133/14
CPC分类号： C09D163/00 , C08F8/14 , C08G59/4207 , C09D133/062
摘要： Coating compositions comprised of a film forming polymer which is the reaction product of (a) a compound containing pendant and/or terminal hydroxyl or epoxy functional groups and (b) citric acid or citric acid anhydride. The coating compositions have enhanced adhesion to galvanized and galvanealed steel substrates without the use of a chrome containing wash primer.
摘要翻译： 包含成膜聚合物的涂料组合物是（a）含有侧基和/或末端羟基或环氧官能团的化合物和（b）柠檬酸或柠檬酸酐的反应产物。 涂料组合物在不使用含铬洗涤底漆的情况下具有增强的对镀锌和镀锌钢基材的粘合性。
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公开(公告)号：US5880196A
公开(公告)日：1999-03-09
申请号：US874898
申请日：1997-06-13
CPC分类号： B41M5/52 , B41M5/506 , B41M5/5218 , B41M5/5236 , B41M5/5245 , B41M5/5254
摘要： A printing medium comprising a substrate having at least one surface and a coating on the surface wherein the coating comprises: (a) binder comprising: (1) organic polymer which is substantially free of onium groups, and (2) onium addition polymer consisting essentially of onium-containing mer units derived from addition monomer and onium-free mer units derived from addition monomer of which from 20 to 100 percent by weight is hydrophobic addition monomer, wherein the binder constitutes from 20 to 90 percent by weight of the coating; and (b) finely divided substantially water-insoluble pseudoboehmite particles which have a maximum dimension of less than 500 nanometers, are distributed throughout the binder, and constitute from 10 to 80 percent by weight of the coating.
摘要翻译： 一种印刷介质，包括具有至少一个表面和表面上的涂层的基材，其中所述涂层包含：（a）粘合剂，其包含：（1）基本上不含鎓基的有机聚合物，和（2）基本上由 的衍生自加成单体的含鎓mer单元和衍生自其加入单体的无鎓单体单元为20〜100重量％的疏水性加成单体，其中粘合剂占涂料重量的20〜90重量％ 和（b）具有最大尺寸小于500纳米的基本上非水不溶性假勃姆石颗粒分布在整个粘合剂中，并且构成涂层的10至80重量％。
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公开(公告)号：US5869658A
公开(公告)日：1999-02-09
申请号：US990890
申请日：1997-12-15
申请人： Jibing Lin , Barry Van Gemert
发明人： Jibing Lin , Barry Van Gemert
IPC分类号： A61K33/18 , A61K38/44 , C07C43/23 , C07D311/94 , G02B5/23 , C07D311/78 , C07D405/02 , C07D413/02
CPC分类号： G02B5/23 , A61K33/18 , C07C43/23 , C07D311/94 , Y10T428/31551 , Y10T428/31565 , Y10T428/31601 , Y10T428/31721
摘要： Described are novel photochromic indeno-fused naphthopyran compounds having certain substituents at the 2-position of the pyran ring and an alkoxy group at the number 6 carbon atom. Certain other substituents may also optionally be present at the number 5, 7, 8, 9, 10, 11, 12 or 13 carbon atoms of the compounds. These compounds may be represented by the following graphic formula: ##STR1## Also described are certain novel indeno-fused naphthols which are used to make the novel naphthopyran compounds. Further described are polymeric organic host materials that contain or that are coated with the novel naphthopyran compounds, or combinations thereof with complementary photochromic compounds, e.g., certain other naphthopyrans, benzopyrans, and spiro(indoline)type compounds.
摘要翻译： 描述了在吡喃环的2位具有一定取代基和6个碳原子上的烷氧基的新型光致变色茚并稠合萘并吡喃化合物。 某些其它取代基也可以任选地存在于化合物的5,7,8,9,10,11,12或13个碳原子上。 这些化合物可以由以下图解表示：
I还描述了用于制备新型萘并吡喃化合物的某些新型茚并稠合萘酚。 进一步描述的是含有新的萘并吡喃化合物或与其互补的光致变色化合物例如某些其它萘并吡喃，苯并吡喃和螺（二氢吲哚）型化合物的组合的聚合有机基质材料。 -
公开(公告)号：US5855695A
公开(公告)日：1999-01-05
申请号：US786561
申请日：1997-01-21
CPC分类号： C23C22/83
摘要： The composition of a non-chrome post-rinse composition for treating phosphated metal substrates is disclosed. The composition comprises the reaction product of an epoxy-functional material containing at least two epoxy groups; and an alkanolamine, or a mixture of alkanolamines. The composition further comprises a group IV-B metal ion, or a mixture of group IV-B metal ions. Also provided is a non-chrome post-rinse concentrate; a process for treating a phosphated metal substrate comprising contacting said phosphated metal substrate with the non-chrome post-rinse composition described above; and the coated article prepared by this process.
摘要翻译： 公开了用于处理磷化金属基材的非铬漂洗组合物的组成。 该组合物包含含有至少两个环氧基团的环氧官能材料的反应产物; 和烷醇胺，或链烷醇胺的混合物。 组合物还包含IV-B族金属离子或IV-B族金属离子的混合物。 还提供了非铬后冲洗浓缩物; 一种处理磷酸化金属基材的方法，包括使所述磷酸化金属基材与上述非铬漂洗组合物接触; 和通过该方法制备的涂层制品。
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公开(公告)号：US5820987A
公开(公告)日：1998-10-13
申请号：US700977
申请日：1996-08-21
IPC分类号： C08G18/58 , C08G18/64 , C09D5/44 , C09D163/00 , C09D175/04 , C09D179/02 , B32B27/38 , C08K3/20
CPC分类号： C08G18/643 , C09D5/4434 , Y10T428/31511 , Y10T428/31551
摘要： An electrodepositable composition that has: (A) an active hydrogen-containing cationic resin, electrodepositable on a cathode, having: (1) a polyepoxide; (2) an oxygen-substituted diamine compound having the following formula: ##STR1## where n is an integer from 2 to 4; and where R.sup.1 or R.sup.2 are the same or different and either one or both contain at least one oxygen and are alkyl, cycloalkyl, substituted alkyl, or substituted cycloalkyl having from 1 to 6 carbon atoms, or R.sup.1 and R.sup.2 are alkanol groups having from 2 to 6 carbon atoms, or R.sup.1, R.sup.2, and the N atom form a cyclic group which is substituted or unsubstituted such as morpholine and 1-(3-aminopropyl) imidazole; and (B) at least partially blocked isocyanate or polyisocyanate curing agent. The diamine compound of Formula I can be used alone or in conjunction with one or more secondary amines, nonhydroxy group containing amines and/or amines with ring structures. Optionally, the polyepoxide can be chain extended with active hydrogen-containing compounds other than polyoxyalkylene polyamines. Also provided is a method of producing an active hydrogen-containing cationic resin composition, electrodepositable on a cathode, comprised of (a) mixing together in a suitable reaction vessel a polyepoxide, or the precursors of the polyepoxide, a polycarboxylic acid, a blocked isocyanate curing agent; (b) adding to the mixture of (a) a base catalyst and the diamine compound of Formula I; (c) polymerizing the mixture of (b) to form a resinous composition; and (d) neutralizing the resinous composition of (c) by adding the resinous composition to a dilute mixture of acid and water to form an aqueous dispersed electrodepositable cationic resin composition.
摘要翻译： 一种电沉积组合物，其具有：（A）可阴离子电解的活性含氢阳离子树脂，其具有：（1）聚环氧化物; （2）具有下式的氧取代二胺化合物：其中n是2至4的整数; 并且其中R 1或R 2相同或不同，并且一个或两者含有至少一个氧，并且是具有1至6个碳原子的烷基，环烷基，取代的烷基或取代的环烷基，或者R 1和R 2是具有2个 至6个碳原子，或R 1，R 2和N原子形成取代或未取代的环状基团，例如吗啉和1-（3-氨基丙基）咪唑; 和（B）至少部分封端的异氰酸酯或多异氰酸酯固化剂。 式I的二胺化合物可以单独使用或与一种或多种仲胺，含羟基的胺和/或具有环结构的胺结合使用。 任选地，聚环氧化物可以用除聚氧化烯多胺以外的活性含氢化合物链延伸。 还提供了一种生产可阴离子电沉积的含活性氢的阳离子树脂组合物的方法，其包括（a）在合适的反应容器中在聚环氧化物或聚环氧化物的前体，多元羧酸，封端异氰酸酯 固化剂; （b）向（a）碱催化剂和式I的二胺化合物的混合物中加入; （c）使（b）的混合物聚合以形成树脂组合物; 和（d）通过将树脂组合物加入酸和水的稀混合物中和（c）的树脂组合物，形成水分散的可电沉积阳离子树脂组合物。
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