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    Bicyclo tertiary hydroxyl carboxaldehyde
    72.
    发明授权
    Bicyclo tertiary hydroxyl carboxaldehyde 失效
    双环叔羟基甲醛

    公开(公告)号：US4554384A

    公开(公告)日：1985-11-19

    申请号：US656661

    申请日：1984-10-01

    申请人： Futoshi Fujioka ,  Richard M. Boden ,  William L. Schreiber

    发明人： Futoshi Fujioka ,  Richard M. Boden ,  William L. Schreiber

    IPC分类号： C07C45/49 ,  C07C47/27 ,  C07C47/36 ,  C11B9/00 ,  C07C47/347

    CPC分类号： C11B9/0061 ,  C07C45/49 ,  C07C47/27 ,  C07C47/36

    摘要： Described are tertiary hydroxyl carboxaldehydes defined according to the generic structure: ##STR1## represent covalent carbon-carbon bonds when m does not=0; and wherein the lines ##STR2## do not represent any bonds when m=0; wherein R represents hydrogen or methyl; wherein p and q each represents 0 or 1 with the proviso that p=1 when q=0 and p=0 when q=1; wherein X and Z each represent one or more carbon atoms required to complete a bicyclo ring with the lines ##STR3## representing carbon-carbon bonds; wherein X and Z complete a phenyl moiety when the line ##STR4## represents no bond; wherein X and Z complete a cycloalkyl ring moiety with the lines ##STR5## represent carbon-carbon bonds and with the line ##STR6## representing no bond; and wherein when m is 0, X represents an alkylene moiety, processes for preparing same by means of reacting carbon monoxide and hydrogen with an unsaturated tertiary alcohol defined according to the structure: ##STR7## by means of an oxo reaction, and uses thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles (e.g., cosmetic powders, perfumed polymers, solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, hair preparations, face creams, and the like).

    摘要翻译： 描述的是根据通用结构定义的叔羟基醛：其中当m不为0时，线和 - - - - 和/或+ + + + +代表共价碳 - 碳键; 并且当m = 0时，线+ + + + +和 - - - - - 不表示任何键; 其中R表示氢或甲基; 其中p和q各自表示0或1，条件是当q = 0时p = 1，q = 1时p = 0; 其中X和Z各自表示一个或多个用代表碳 - 碳键的+ + + + +和 - 当线 - - - - 表示无键时，X和Z完全为苯基部分; 其中X和Z与所述线完成环烷基环部分，并且+ + + + +代表碳 - 碳键，并且具有不代表键的线 - - - - - 。 并且其中当m为0时，X表示亚烷基部分，通过使一氧化碳和氢与根据以下结构定义的不饱和叔醇反应制备其方法：通过氧代反应，其用途在 增加或增强香水组合物，古龙水和香水制品（例如，化妆品粉末，加香聚合物，固体或液体阴离子，阳离子，非离子或两性离子洗涤剂，织物柔软剂组合物，织物柔软剂制品，头发制剂，面霜和 喜欢）。

    Mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives
    73.
    发明授权
    Mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives 失效

    公开(公告)号：US4448984A

    公开(公告)日：1984-05-15

    申请号：US458890

    申请日：1983-01-18

    申请人： Mark A. Sprecker ,  Marie R. Hanna ,  Richard J. Tokarzewski ,  Robert P. Belko ,  Hugh Watkins ,  Manfred H. Vock

    发明人： Mark A. Sprecker ,  Marie R. Hanna ,  Richard J. Tokarzewski ,  Robert P. Belko ,  Hugh Watkins ,  Manfred H. Vock

    IPC分类号： A24B15/34 ,  C07C47/347 ,  C07C47/445 ,  C07C43/162 ,  C07C35/28 ,  C07C67/035 ,  C07C67/04

    CPC分类号： A24B15/345 ,  C07C47/347 ,  C07C47/445

    摘要： Described are mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives having the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond; wherein R.sub.1, R.sub.1 ', R.sub.1 ", R.sub.1 '", R.sub.1 "", R.sub.3, R.sub.5, R.sub.5 ', R.sub.5 ", R.sub.5 '", R.sub.5 "" and R.sub.6 represent hydrogen or methyl with the provisos:(i) at least four of R.sub.1, R.sub.1 ', R.sub.1 ", R.sub.1 '" and R.sub.1 "" are hydrogen; and (ii) at least four of R.sub.5, R.sub.5 ', R.sub.5 ", R.sub.5 '" and R.sub.5 "" represent hydrogen;and wherein Z represents one of the moieties:(i) carboxaldehyde having the structure: ##STR2## (ii) alkylene dioxy or dialkoxy methyl having the structure: ##STR3## (iii) hydroxy methyl having the structure: ##STR4## (iv) acetoxymethyl having the structure: ##STR5## and wherein R.sub.7 and R.sub.8 taken separately represent C.sub.1 -C.sub.4 lower alkyl or R.sub.7 and R.sub.8 taken together represent C.sub.2 -C.sub.4 alkylene; wherein the line represented by:[++++] is either (i) a carbon-carbon single bond when R.sub.7 and R.sub.8 taken together are C.sub.2 -C.sub.4 alkylene or (ii) no bond at all when R.sub.7 and R.sub.8 taken separately represent C.sub.1 -C.sub.4 lower alkyl. Also described are processes for preparing such mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives, and processes for using the above defined mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives for their organoleptic properties and compositions containing said mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives including perfumes, perfumed articles (such as solid or liquid anionic, cationic, nonionic or zwitterionic detergents, perfumed polymers, fabric softeners and cosmetic powders), foodstuffs, chewing gums, toothpastes, medicinal products, chewing tobaccos, smoking tobaccos and smoking tobacco articles.

    5,6-Methano-5,6-dihydroretinoids
    74.
    发明授权
    5,6-Methano-5,6-dihydroretinoids 失效
    5,6-甲基-5,6-二氢赖氨酸

    公开(公告)号：US4439614A

    公开(公告)日：1984-03-27

    申请号：US421065

    申请日：1982-09-22

    申请人： Marcia I. Dawson ,  Rebecca Chan ,  Peter D. Hobbs

    发明人： Marcia I. Dawson ,  Rebecca Chan ,  Peter D. Hobbs

    IPC分类号： C07C45/29 ,  C07C47/347 ,  C07C69/767 ,  C07C69/76 ,  C07C69/74

    CPC分类号： C07C47/347 ,  C07C45/292 ,  C07C45/298

    摘要： 5,6-Methano-5,6-dihydroretinoids such as ethyl (E)-5,6-methano-5,6-dihydroretinoate and (E)-1-(4-carbethoxyphenyl)-2-methyl-4-(2,2,6-trimethylbicyclo[4.1.0]hept-1-yl)-1,3-butadiene are disclosed. These componds are useful as chemopreventive agents for inhibiting tumor promotion in epithelial cells and for treating nonmalignant skin disorders.

    摘要翻译： （E）-5,6-亚甲基-5,6-二氢视黄酸乙酯和（E）-1-（4-甲氧基苯基）-2-甲基-4-（2 ，2,6-三甲基双环[4.1.0]庚-1-基）-1,3-丁二烯。 这些化合物可用作用于抑制上皮细胞中的肿瘤促进和用于治疗非恶性皮肤病的化学预防剂。

    Use in modifying smoking tobacco aroma and flavor or mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives
    76.
    发明授权
    Use in modifying smoking tobacco aroma and flavor or mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives 失效
    用于改变吸烟烟草香气和风味或单氧甲基取代的多羟基甲基萘衍生物

    公开(公告)号：US4391284A

    公开(公告)日：1983-07-05

    申请号：US354387

    申请日：1982-03-02

    申请人： Mark A. Sprecker ,  Marie R. Hanna ,  Richard J. Tokarzewski ,  Robert P. Belko ,  Hugh Watkins ,  Manfred H. Vock

    发明人： Mark A. Sprecker ,  Marie R. Hanna ,  Richard J. Tokarzewski ,  Robert P. Belko ,  Hugh Watkins ,  Manfred H. Vock

    IPC分类号： A24B15/34 ,  C07C47/347 ,  C07C47/445 ,  A24B3/12 ,  A24B15/30

    CPC分类号： A24B15/345 ,  C07C47/347 ,  C07C47/445

    摘要： Described is the use in modifying, augmenting or enhancing the aroma or taste of smoking tobacco products of mono-oxomethyl substituted polyhydrodimethanonaphthalene derivatives having the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond; wherein R.sub.1, R.sub.1 ', R.sub.1 ", R.sub.1 '", R.sub.1 "", R.sub.3, R.sub.5, R.sub.5 ', R.sub.5 ", R.sub.5 '", R.sub.5 "" and R.sub.6 represent hydrogen or methyl with the provisos:(i) at least four of R.sub.1, R.sub.1 ', R.sub.1 ", R.sub.1 '" and R.sub.1 "" are hydrogen; and (ii) at least four of R.sub.5, R.sub.5 ', R.sub.5 ", R.sub.5 '" and R.sub.5 "" represent hydrogen;and wherein Z represents one of the moieties:(i) carboxaldehyde having the structure: ##STR2## (ii) alkylene dioxy or dialkoxy methyl having the structure: ##STR3## (iii) hydroxy methyl having the structure: ##STR4## (iv) acetoxymethyl having the structure: ##STR5## and wherein R.sub.7 and R.sub.8 taken separately represent C.sub.1 -C.sub.4 lower alkyl or R.sub.7 and R.sub.8 taken together represent C.sub.2 -C.sub.4 alkylene; wherein the line represented by:[++++]is either (i) a carbon-carbon single bond when R.sub.7 and R.sub.8 taken together are C.sub.2 -C.sub.4 alkylene or (ii) no bond at all when R.sub.7 and R.sub.8 taken separately represent C.sub.1 -C.sub.4 lower alkyl.

    摘要翻译： 描述了用于改变，增强或增强具有以下通用结构的单氧代甲基取代的多羟基甲基萘衍生物的烟草产品的香气或味道：其中虚线表示碳 - 碳单键或碳 - 碳双 键; 其中R1，R1'，R1“，R1”，R1“，R3，R5，R5'，R5”，R5“，R5”和R6表示氢或甲基， 条件：（i）R1，R1'，R1“，R1”和R1“”中的至少四个为氢; 和（ii）R5，R5'，R5“，R5”和R5“中的至少四个表示氢; （ⅰ）具有以下结构的甲醛：（ⅱ）具有以下结构的亚烷基二氧基或二烷氧基甲基：（ⅲ）具有以下结构的羟基甲基：（ⅳ） 具有以下结构的乙酰氧基甲基：其中R7和R8分别代表C1-C4低级烷基或R7和R8一起代表C2-C4亚烷基; 其中由以下各项表示的线：[++++]是（i）当R 7和R 8一起为C 2 -C 4亚烷基时的碳 - 碳单键或（ii）当R7和R8分别表示C1 -C4低级烷基。

    Carboamidoalkyl norbornanes, organoleptic uses thereof and process for preparing same
    78.
    发明授权
    Carboamidoalkyl norbornanes, organoleptic uses thereof and process for preparing same 失效
    碳酰胺基烷基降冰片烷，感官用途及其制备方法

    公开(公告)号：US4324912A

    公开(公告)日：1982-04-13

    申请号：US206632

    申请日：1980-11-13

    申请人： Philip T. Klemarczyk ,  Frederick L. Schmitt ,  Edward J. Granda ,  Domenick Luccarelli, Jr.

    发明人： Philip T. Klemarczyk ,  Frederick L. Schmitt ,  Edward J. Granda ,  Domenick Luccarelli, Jr.

    IPC分类号： A24B15/34 ,  C07C45/62 ,  C07C45/69 ,  C07C47/347 ,  C07C47/445 ,  C07C61/13 ,  C11B9/00 ,  C11D3/50 ,  C07C103/19

    CPC分类号： C11D3/50 ,  A24B15/345 ,  C07C45/62 ,  C07C45/69 ,  C07C47/347 ,  C07C47/445 ,  C07C61/13 ,  C11B9/0046

    摘要： Described are compounds having the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond and wherein R.sub.2 is methyl or hydrogen; R.sub.6 is methyl or hydrogen; R.sub.1, R.sub.3 or R.sub.7 represent methyl or hydrogen, with the proviso that one of R.sub.1, R.sub.3 and R.sub.7 represents methyl and the other two of R.sub.1, R.sub.3 and R.sub.7 represent hydrogen; wherein R.sub.4 and R.sub.5 are the same or different and each represents hydrogen or C.sub.1 -C.sub.3 lower alkyl. In addition, organoleptic uses of such compounds are disclosed for augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, toothpastes, medicinal products, chewing tobaccos, smoking tobaccos, smoking tobacco articles, perfumes, perfumed articles (such as liquid or solid anionic, cationic, nonionic or zwitterionic detergents, fabric softeners, dryer-added fabric softener articles, fabric brighteners and other perfumed articles and colognes). Also disclosed is a process for preparing such compounds according to the reaction scheme: ##STR2## wherein R" represents C.sub.1 -C.sub.3 alkyl; m+n=3 with the further proviso that m is 1 or 2 and n is 1 or 2; and wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 are as defined above.

    摘要翻译： 描述了具有通用结构的化合物：其中虚线表示碳 - 碳单键或碳 - 碳双键，其中R2是甲基或氢; R6是甲基或氢; R 1，R 3或R 7表示甲基或氢，条件是R 1，R 3和R 7中的一个表示甲基，R 1，R 3和R 7中的另外两个表示氢; 其中R 4和R 5相同或不同，各自表示氢或C 1 -C 3低级烷基。 此外，公开了这种化合物的感官用途，用于增强或增强消费材料的香味或味道，包括食品，口香糖，牙膏，药用产品，咀嚼烟草，烟草烟草，烟草制品，香水，香水制品（如液体 或固体阴离子，阳离子，非离子或两性离子洗涤剂，织物柔软剂，干燥剂添加的织物柔软剂制品，织物增白剂和其它香料制品和古龙水）。 还公开了根据反应方案制备这些化合物的方法：其中R“表示C 1 -C 3烷基; m + n = 3，进一步的条件是m为1或2，n为1或2; 并且其中R 1，R 2，R 3，R 4，R 5，R 6和R 7如上所定义。

    Polycyclic polyamines
    79.
    发明授权
    Polycyclic polyamines 失效
    多环多胺

    公开(公告)号：US4229376A

    公开(公告)日：1980-10-21

    申请号：US74368

    申请日：1979-09-10

    申请人： Edgar R. Rogier

    发明人： Edgar R. Rogier

    IPC分类号： C08K5/00 ,  C07C45/50 ,  C07C47/347 ,  C07C67/00 ,  C07C209/00 ,  C07C211/19 ,  C08G59/00 ,  C08G59/50 ,  C08K5/17 ,  C07C87/40

    CPC分类号： C08G59/5026 ,  C07C211/19 ,  C07C45/50 ,  C07C47/347 ,  C07C2103/68 ,  C07C2103/91

    摘要： Disclosed herein are tricyclic and pentacyclic polyamines having a secondary or tertiary amine group on an amine functional substituent and at least one primary amine group on each of two amine functional substituents in the molecule. These compounds function excellently as non-visably carbonating epoxy curing agents and in addition unlike most other amines exhibit a mild amine odor.

    摘要翻译： 本文公开了在胺官能取代基上具有仲胺或叔胺基团的三环和五环多胺，以及分子中两个胺官能取代基中的每一个上的至少一个伯胺基团。 这些化合物作为不可见的碳酸化环氧固化剂具有优异的功能，此外与大多数其他胺不同，其表现出温和的胺气味。