EXTRUSION GRANULATED UREA-FORMALDEHYDE-BASED MULTI-NUTRIENT SLOW/CONTROLLED RELEASE FERTILIZER AND PREPARATION METHOD THEREOF

    公开(公告)号:US20190218152A1

    公开(公告)日:2019-07-18

    申请号:US16180889

    申请日:2018-11-05

    Abstract: The invention relates to the field of slow/controlled release fertilizer, in particular to a urea-formaldehyde-based multi-nutrient slow/controlled release fertilizer and a preparation method thereof. The urea-formaldehyde-based multi-nutrient slow/controlled release fertilizer comprises ammonium polyphosphate, inorganic silica gel and urea-formaldehyde, wherein the phosphorus-oxygen double bond of ammonium polyphosphate can at least form hydrogen bond linkage with a urea-formaldehyde molecule chain, the hydroxyl group of the inorganic silica gel can at least form hydrogen bond linkage with the urea-formaldehyde molecular chain, and ammonium polyphosphate, inorganic silica gel and urea-formaldehyde together form a hydrogen bond associated polymer network structure. The invention can prepare a urea-formaldehyde-based multi-nutrient slow/controlled release fertilizer comprising a strong hydrogen bond network structure by using a conventional aqueous solution polymerization in combination with a normal temperature extrusion granulation process, avoiding the coating process in the latter stage of the preparation of a coated fertilizer, achieving a simple and effective preparation process, and saving a lot of manpower and material resources. The urea-formaldehyde-based multi-nutrient slow/controlled release fertilizer provided by the invention can stably and continuously release nitrogen nutrient throughout the release period, thereby making up for the shortcoming of excessively long nutrient release period of the existing urea-formaldehyde fertilizers.

    Wet milled organic fertilizer and feed product

    公开(公告)号:US10266456B2

    公开(公告)日:2019-04-23

    申请号:US14990727

    申请日:2016-01-07

    Inventor: Larry V. Connell

    Abstract: A compatible combination of micron size carbon based particles along with beneficial microbial species and conventional plant nutrients into a plant or an animal food. This balanced product is a combination of nutrients and microbes, and can be applied as a suspension in water or as a slow release granule. This combination of organic plant food and fertilizer can also be applied as a foliar, as a seed coating, and as an all-in-one granule combination of nutrients and biological agents, to facilitate mineralization, nutrient availability and provide energy to the soil and plants, with a total conversion of a storable processed biomass into a precisely known quality and quantity of usable fertilizer ‘tea’ solution, with no biomass waste, odors, or crop application timing problems. The process of formulating the combination product reduces green house gas emissions by limiting mineralization and composting.

    C FERTILIZER AND FEED PRODUCT
    75.
    发明申请

    公开(公告)号:US20170197889A1

    公开(公告)日:2017-07-13

    申请号:US14990727

    申请日:2016-01-07

    Inventor: Larry V. Connell

    CPC classification number: C05B17/00 C05B19/00 C05F11/08 C05G3/0094

    Abstract: A compatible combination of micron size carbon based particles along with beneficial microbial species and conventional plant nutrients into a plant or an animal food. This balanced product is a combination of nutrients and microbes, and can be applied as a suspension in water or as a slow release granule. This combination of organic plant food and fertilizer can also be applied as a foliar, as a seed coating, and as an all-in-one granule combination of nutrients and biological agents, to facilitate mineralization, nutrient availability and provide energy to the soil and plants, with a total conversion of a storable processed biomass into a precisely known quality and quantity of usable fertilizer ‘tea’ solution, with no biomass waste, odors, or crop application timing problems. The process of formulating the combination product reduces green house gas emissions by limiting mineralization and composting

    PROCESS FOR PREPARING A FERTILISER
    76.
    发明申请
    PROCESS FOR PREPARING A FERTILISER 审中-公开
    制备肥料的方法

    公开(公告)号:US20160368830A1

    公开(公告)日:2016-12-22

    申请号:US14901748

    申请日:2014-07-02

    Abstract: A process for preparing a micronutrient-enriched phosphate-based fertiliser is disclosed. An aqueous fertiliser mixture comprising phosphoric acid and/or phosphate rock is prepared and optionally granulated in granulator unit. The pH of the fertiliser mixture is measured and controlled such that the pH is maintained within a predefined range.

    Abstract translation: 公开了一种制备富含微量营养素的磷酸盐肥料的方法。 制备包含磷酸和/或磷酸盐岩的含水肥料混合物,并任选在造粒机中造粒。 测量和控制肥料混合物的pH使得pH保持在预定范围内。

    Composition for enhancing the production of crystal agglomerates from a precipitation liquor
    77.
    发明授权
    Composition for enhancing the production of crystal agglomerates from a precipitation liquor 有权
    用于从沉淀液中增强结晶聚集体的生成的组合物

    公开(公告)号:US08784509B2

    公开(公告)日:2014-07-22

    申请号:US13645577

    申请日:2012-10-05

    Applicant: Nalco Company

    CPC classification number: C01F7/145 B01D9/005 C01F7/08

    Abstract: The present invention relates to compositions and methods to increase the output of a high quality product from the precipitation liquor crystallization process exemplified through the aluminum hydroxide recovery processes such as the Bayer process. The invention is a method of increasing the size of precipitates from a liquor. The invention in one embodiment relates to the use of a crystal growth modifier compositions added to the precipitation process to increase the particle size distribution of the precipitated alumina trihydrate.

    Abstract translation: 本发明涉及通过氢氧化铝回收方法例如拜耳方法例举的沉淀液结晶方法来提高高质量产品的产量的组合物和方法。 本发明是一种从酒中提高沉淀物的尺寸的方法。 在一个实施方案中的本发明涉及添加到沉淀方法中的晶体生长改性剂组合物用于增加沉淀的三水合氧化铝的粒度分布的用途。

    Method for detecting clogging and granulation method

    公开(公告)号:US5964901A

    公开(公告)日:1999-10-12

    申请号:US981401

    申请日:1997-12-16

    Abstract: There is disclosed a method for detecting clogging of air feed pipes, comprising air feed pipes (15), each having an outlet (13) for jetting air into a granulation section (1), and jetting nozzles (13), each situated at the center of the air outlet of a said air feed pipe for jetting a liquid of a molten raw material (e.g. molten urea), wherein, in jetting the liquid of the molten raw material from the jetting nozzles into the granulation section to carry out granulation,(a) an orifice section (14) is provided at a lower part of each of the air feed pipes (15), a section for taking up orifice rear pressure (16) is provided in each air feed pipe and is located downstream of the orifice section, and a section for taking up orifice forward pressure (17) is provided upstream of the orifice section, and(b) the pressure difference between the orifice forward pressure and the orifice rear pressure is measured, to detect clogging of the air feed pipes based on an abnormality in the pressure difference regarding the air feed pipes. There is also disclosed a granulation method, comprising monitoring the pressure difference by the above method, stopping the feed of a liquid of a molten raw material to the air feed pipe whose pressure difference is abnormal, and compensating the amount corresponding to the stoppage with the remaining function. The detection method is a method capable of detecting accurately a malfunction related to jetting of air in the granulation of urea or the like. Further, the granulation method is a granulation method wherein, accurately, in response to the occurrence of a malfunction related to the jetting of air, the feed of a raw material liquid to the malfunctioned section is stopped, and the raw material liquid to be fed to the jet nozzles having other normal air outlets is suitably increased, thereby allowing continuous operation, with the productivity before the occurrence of the malfunction kept.

    Granulated fertilizer and slurry process therefor
    79.
    发明授权
    Granulated fertilizer and slurry process therefor 失效
    颗粒肥料和浆料加工

    公开(公告)号:US4528021A

    公开(公告)日:1985-07-09

    申请号:US561763

    申请日:1983-12-15

    Inventor: John L. Medbery

    CPC classification number: C05B19/00

    Abstract: A continuous process for the production of a granulated fertilizer wherein comminuted phosphate rock, phosphoric acid and water are introduced into a pre-reactor where they are heated. The mixture is continuously withdrawn and transferred to a digester where heating is continued resulting in formation of a slurry. The slurry is continuously withdrawn and is split into two streams, one of which is recycled to either the pre-reactor or to the digester while the other stream is delivered to a granulator where it is mixed with other fertilizer ingredients and dried to form the granulated fertilizer.

    Abstract translation: 用于生产颗粒肥料的连续方法,其中粉碎的磷酸盐岩,磷酸和水被引入预热器中,在那里它们被加热。 将混合物连续取出并转移到蒸煮器,在该蒸煮器继续加热导致浆料的形成。 浆料被连续取出并分成两股,其中一个被再循环到预反应器或蒸煮器中,而另一个流被输送到造粒机,在其中与其他肥料成分混合并干燥形成颗粒状 肥料。

    Granulation of urea phosphate from urea and merchant-grade phosphoric
acid
    80.
    发明授权
    Granulation of urea phosphate from urea and merchant-grade phosphoric acid 失效
    从尿素和商品级磷酸制备尿素磷酸盐

    公开(公告)号:US4512793A

    公开(公告)日:1985-04-23

    申请号:US605345

    申请日:1984-04-30

    CPC classification number: C05B15/00 C05B19/00

    Abstract: A process for direct granulation of unpurified urea phosphate from urea and merchant- or filter-grade wet-process phosphoric acid to produce a product with exceptional satisfactory physical and chemical properties for direct application to the soil or for use in production of fluid fertilizers. The process involves the utilization of sweep air in both the reactor and the granulator to remove water from the heat-sensitive urea phosphate mixture to enhance the granulation characteristics of the product. Product drying with applied heat after granulation is essentially eliminated. Moisture content of the urea phosphate is reduced to an acceptable level (about 1.0 percent) in the granulator; however, the granules are somewhat sticky. It has been found, however, that the resulting urea phosphate with about 1.0 percent moisture is less sensitive to heat than high (4 to 6 percent) moisture product. Consequently, heated air (up to about 200.degree. F.) may be applied downstream from the granulator and into the dryer chiefly for control of relative humidity of ambient air introduced therein to less than 40 percent, thereby resulting in still further water removal and curing to effect a very dry and free-flowing product. This alternative is a viable expedient in geographic areas wherein the relative humidity of ambient air is normally in the range of about 50 percent and 80 percent.

    Abstract translation: 从尿素和商用或过滤级湿法磷酸直接造粒未纯化的尿素磷酸的方法,以生产具有特别令人满意的物理和化学性质的产品,用于直接施用于土壤或用于生产流体肥料。 该方法涉及在反应器和造粒机中利用吹扫空气以从热敏磷酸尿素混合物中除去水以增强产品的造粒特性。 基本上消除了造粒后用加热干燥的产品。 尿素磷酸盐的水分含量在造粒机中降低到可接受的水平(约1.0%); 然而,颗粒有些粘稠。 然而,已经发现,具有约1.0%水分的所得尿素磷酸盐比高(4至6%)的水分产物对热敏感性差。 因此,加热空气(高达约200°F)可以从造粒机的下游施加到干燥器中,主要用于控制引入其中的环境空气的相对湿度小于40%,从而进一步进行除水和固化 以实现非常干燥和自由流动的产品。 这种替代方案是在地理区域中可行的方法,其中环境空气的相对湿度通常在约50%和80%的范围内。

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