摘要:
METHOD FOR THE OXIDATIVE DEHYDROGENATION OF PARAFFINS TO PRODUCE OLEFINS BY CONTACTING THE PARAFFINS WITH MOLECULAR OXYGEN IN THE PRESENCE OF MOLTEN ALKALI METAL HYDROXIDES, ALUMINUM, AND A SOLUBLE TRANSITION METAL OXYANION INCLUDED IN THE MOLTEN ALKALI METAL HYDROXIDE.
摘要:
Catalyst for the oxidation of an Alpha , Beta -unsaturated aldehyde to an Alpha , Beta -unsaturated carboxylic acid, said catalyst comprising (A) a mixture of oxides of the elements antimony, molybdenum, vanadium and tungsten and/or compounds of said elements and oxygen, and (B) at least one oxide or oxygen containing compound of the elements lead, silver, copper, tin, titanium or bismuth, said catalyst having an atomic ratio of antimony to molybdenum to vanadium to tungsten to Group (B) elements of about 1 - 60 : 12 : 0.5 - 25 : 0.1 - 12 : 0.1 - 12. Processes for the use and preparation of the catalysts are provided.
摘要:
GRANULAR OR PELLETED CATALYSTS SUITABLE FOR USE IN THE VAPOUR PHASE OXIDATION OF ORGANIC COMPOUNDS CONTAINING ANTIMONY AND TIN AS OXIDE COMPOSITIONS WHICH HAVE BEEN PRETREATED IN POWDER FORM BY HEATING IN AN INERT ATMOSPHERE TO 200 TO 500*C. AND THEREAFTER PELLETED AND REHEATED IN MOLECULAR OXYGEN TO 550 TO 1000*C.
摘要:
AN IMPROVED CATALYST STRUCTURE FOR USE IN CATALYIC PROCESSES, CONSISTING OF A POWDERED CATALYST, CARRIER, AND METAL FIBER THOROUGHLY MIXED TO ASSURE A PERMANENT UNIFORM DISTRIBUTION OF THE METAL FIBER, THE CATALYST-METAL FIBER MIXTURE THEN PRESSED INTO ANY DESIRED SHAPE FOR ITS INTENDED USE. THE PERMANENT UNIFORM DISPERSION OF METAL FIBERS RESULTS IN A CATALYST STRUCTURE HAVING INCREASED THERMAL CONDUCTIVITY AND MORE UNIFORM POROSITY, THE IMPROVED HEAT TRANSFER CHARACTERISTICS INCREASING SELECTIVITY AND MINIMIZING TEMPERATURE GRADIENTS IN THE CATALYTIC STRUCTURE THEREBY ASSURING CONSTANT REACTOR TEMPERATURE AND IMPARTING STABILITY, IMPROVED YIELD AND TEMPERATURE CONTROL IN HIGHLY EXOTHERMIC AND ENDOTHERMIC CATALYTIC REACTIONS.
摘要:
A resid hydrocarbon is converted to lower boiling hydrocarbons and/or desulfurized by contacting, in the presence of hydrogen, said resid with a bed of catalyst particles, substantially all of said particles having a surface-to-volume ratio ranging between about 100 and about 250 l/inches, and wherein substantially all points within each of said particles are less than about 0.015 inch from the particle''s surface. When one of these particles is circumscribed by a right circular cylinder having an altitude equal to that of the particle, the particle contacts the sidewall of the cylinder at at least three elements and occupies from about 70 to about 90 percent of the cylinder''s volume. Preferred particle shapes are clover-leaf, cross, ring and C-shape.
摘要:
A process for the hydrodealkylation of alkyl-substituted aromatic hydrocarbons, including contacting the alkyl-substituted aromatic hydrocarbons with a catalyst comprising a metal of Group VIB of the Periodic System, such as chromium, molybdenum, and tungsten, and mixtures thereof, in an amount of about 5 to 15 per cent by weight of the finished catalyst, and a promoter selected from the group consisting of alkali metals, alkaline earth metals, rare earth metals, and mixtures thereof, such as potassium, rubidium, cesium, calcium, strontium, barium, cerium, thorium, etc., in an amount between about 1 to 10 percent by weight of the finished catalyst, at a temperature of about 1,050* to 1,200*F, a pressure of about 100 to 1,000 psig., a liquid hourly space velocity of about 0.1 to 5, and a hydrogento-hydrocarbon mole ratio between about 3 and 15 to 1.
摘要:
Production of catalyst tablets by admixing the catalyst particles, with or without substrate, with graphite and a polyethylene, polyproplene, polyethylene glycol and/or polypropylene glycol; and then tabletizing the mass.
摘要:
A GROUP VII-B OR VIII METAL ON CARBON CATALYST IS STABILIZED BY HEATING THE CATALYST AT A TEMPERATURE OF FROM 500 TO 1200*F. IN ANON-OXIDIZING ATMOSPHERE. THE HEAT TREATED COMPOSITION IS PROVIDED WITH STABILIZED ACTIVITY AND IMPROVED CRUSH STRENGTH IN LOWTEMPERATURE CATALYTIC REACTIONS INVOLVING THE REDUCTION OF NITRATED OR OXYGENATED HYDROCARBONS TO AMINES AND ALCOHOLS WHERE COPIOUS AMOUNTS OF BY-PRODUCT WATER IS FORMED AND IS PARTICULARLY SUITED FOR UTLIZATION AS A HYDROGENATION CATALYST SUCH AS IN THE SELECTIVE CONVERSION OF MONONITROPARAFFINS TO SECONDARY ALKYL PRIMARY AMINES.
摘要:
Porous manganese oxide pellets in which a major portion of the manganese oxides is manganous oxide and the porosity of the pellets is not less than about 45%. Preferably, substantially all the manganese oxide in the pellets is manganous oxide and the porosity is about 60 percent. The porous manganese oxide pellets are between about one-fourth inch to about five-eighths inch in diameter. The pellets are useful as sulfur acceptors whereby they can be used to reduce the sulfur content of other materials such as coke pellets, iron ore pellets and the like.