Abstract:
A novel process for preparing superconductor of bismuth-containing compound oxide such as Bi--Sr--Ca--Cu system.In the present invention, firstly an intermediate compound oxide containing metal elements of the superconductor except bismuth is prepared and then the intermediate compound oxide is contacted with bismuth oxide vapour at a temperature between 750.degree. and 950.degree. C. so that bismuth oxide is reacted with said intermediate compound oxide.
Abstract:
Method of applying in accordance with a pattern thin layers of oxidic superconductive material onto a substrate, it not being necessary to subject the superconductive material to mechanical or chemical treatments. At its surface the substrate is provided in accordance with a desired pattern with two different material compositions. The first composition is chosen such that the oxidic material applied thereon is superconductive at a desired surface temperature. The second composition is chosen such that the oxidic material applied thereon is not superconductive.
Abstract:
The invention relates to a method for producing a high temperature superconductor (HTSC) from a strip including an upper side precursor layer and which, for continuous sintering of the precursor layer within a furnace in the presence of a fed-in reaction gas, is drawn across a support. A furnace for performing the method is also described.
Abstract:
A class of superconductive materials containing copper-oxygen bonding and with mixed cation-occupancy designed with a view to size and valence consideration yield useful values of critical temperature and other properties. Uses entail all applications which involves superconducting materials such as magnets and transmission lines which require continuous superconductivity paths as well as detectors (e.g., which may rely on tunneling).
Abstract:
A method of fabricating large bulk high temperature superconducting articles which comprises the steps of selecting predetermined sizes of crystalline superconducting materials and mixing these specific sizes of particles into a homogeneous mixture which is then poured into a die. The die is placed in a press and pressurized to predetermined pressure for a predetermined time and is heat treated in the furnace at predetermined temperatures for a predetermined time. The article is left in the furnace to soak at predetermined temperatures for a predetermined period of time and is oxygenated by an oxygen source during the soaking period.
Abstract:
A method of preparing a superconducting oxide by combining the matalic elements of the oxide to form an alloy, folled by oxidation of the alloy to form the oxide. Superconducting oxide-metal composites are prepared in which a noble metal phase intimately mixed with the oxide phase results in improved mechanical properties. The superconducting oxides and oxide-metal composites are provided in a variety of useful forms.
Abstract:
A method of preparing a superconducting oxide by combining the metallic elements of the oxide to form an alloy, followed by oxidation of the alloy to form the oxide. Superconducting oxide-metal composites are prepared in which a noble metal phase intimately mixed with the oxide phase results in improved mechanical properties. The superconducting oxides and oxide-metal composites are provided in a variety of useful forms.
Abstract:
A method for improving the phase purity of a multiphase ceramic high temperature superconductor by selective microwave heating of undesired phases in a multiphase material to cause a phase transformation of the undesired phase to the desired phase. The selective microwave heating may be employed during initial firing and sintering of the ceramic superconductor compound or as a subsequent annealing step. Plane polarized microwave energy may be employed to enhance the two dimensional anisotropy of the compound by similar selective heating.
Abstract:
A process for producing an oxide superconductor, comprising putting a formed body of raw material powders for forming an oxide superconductor on silver or silver oxide within a pan which does not melt at the melting point of silver, heating the pan to a temperature higher than the melting point of silver to bring the formed body to a semi-molten state with the formed body being floated on molten silver, cooling the pan and taking the formed body out of the re-solidified silver. This process enables a large bulk material having a diameter of 10 cm or more to be produced without occurrence of cracking.
Abstract:
The present invention relates to a process for preparing an oxide superconductor having a high critical current density, a uniform structure and an excellent mechanical property and thermal stability, which comprises heating raw material powders of a REBaCuO system at 1050.degree. C. or higher, cooling the material for solidification, pulverizing and mixing the solidified material to homogeneously disperse the structure of the solidified material, molding the material, optionally mixed with silver oxide or silver, into a predetermined shape, and reheating the molding to 1050.degree. C. or higher to grow a superconducting phase.