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    Azeotrope-like compositions of tetrafluoropropene and water
    62.
    发明授权
    Azeotrope-like compositions of tetrafluoropropene and water 有权
    四氟丙烯和水的共沸组合物

    公开(公告)号：US08747691B2

    公开(公告)日：2014-06-10

    申请号：US13082980

    申请日：2011-04-08

    申请人： Ryan Hulse ,  Haluk Kopkalli ,  Hang T. Pham

    发明人： Ryan Hulse ,  Haluk Kopkalli ,  Hang T. Pham

    IPC分类号： C09K5/04 ,  C07C17/38

    CPC分类号： C07C21/18 ,  C07C17/38 ,  C07C17/383 ,  C07C17/386 ,  C07C17/389

    摘要： Provided are azeotropic and azeotrope-like compositions of trans-1,3,3,3-tetrafluoropropene (HFO-1234ze(E)) and water. Such azeotropic and azeotrope-like compositions are useful in isolating trans-1,3,3,3-tetrafluoropropene from impurities during production. Azeotropes of the instant invention are similarly useful in final compositions or for the manufacture of final compositions, such as blowing agent, propellants, refrigerants, diluents for gaseous sterilization and the like.

    摘要翻译： 提供了反式-1,3,3,3-四氟丙烯（HFO-1234ze（E））和水的共沸和类共沸组合物。 这种共沸和类共沸组合物可用于在生产过程中从杂质中分离反式-1,3,3,3-四氟丙烯。 本发明的共沸物类似地可用于最终组合物或用于制造最终组合物，例如发泡剂，推进剂，制冷剂，用于气体灭菌的稀释剂等。

    PURIFICATION METHOD OF 2,3,3,3-TETRAFLUOROPROPENE
    67.
    发明申请
    PURIFICATION METHOD OF 2,3,3,3-TETRAFLUOROPROPENE 有权
    2,3,3,3-四氯丙烯的纯化方法

    公开(公告)号：US20130105296A1

    公开(公告)日：2013-05-02

    申请号：US13808358

    申请日：2011-07-21

    申请人： Takehiro Chaki ,  Kazuhiro Takahashi

    发明人： Takehiro Chaki ,  Kazuhiro Takahashi

    IPC分类号： C07C17/386

    CPC分类号： C07C17/386 ,  C01B7/196 ,  C07C17/38 ,  C07C17/383 ,  Y02P20/582 ,  C07C21/18

    摘要： This invention provides a method for purifying HFO-1234yf by removing HF from a mixture of HFO-1234yf and HF under simple and economically advantageous conditions. According to the present invention, this is a purification method for 2,3,3,3-tetrafluoropropene, (1) the purification method comprising the step of subjecting a mixture comprising 2,3,3,3-tetrafluoropropene and hydrogen fluoride to extractive distillation in a distillation column A using an extractant, thereby obtaining a fraction I that contains 2,3,3,3-tetrafluoropropene and has a lower ratio of hydrogen fluoride to 2,3,3,3-tetrafluoropropene than that of the mixture, while obtaining a fraction II that contains hydrogen fluoride and has a lower ratio of 2,3,3,3-tetrafluoropropene to hydrogen fluoride than that of the mixture; (2) the extractant comprising at least one member selected from the group consisting of: (i) alcohols represented by ROH, wherein R is a C1-5 alkyl group, (ii) ethers represented by ROR′, wherein R and R′ are the same or different, and each is a C1-4 alkyl group, (iii) fluorinated alcohols represented by RfOH, wherein Rf is a C1-3 fluoroalkyl group, (iv) ketones represented by RCOR′, wherein R and R′ are the same or different, and each is a C1-4 alkyl group, (v) esters represented by RCOOR′, wherein R and R′ are the same or different, and each is a C1-4 alkyl group, (vi) polyols represented by R(OH)n, wherein R is a C1-4 alkyl group, and n is an integer of 2 to 3, and (vii) ethylene glycols represented by R1O(CH2CH2O)nR2, wherein R1 and R2 are the same or different, and each is hydrogen or a C1-4 alkyl group, and n is an integer of 1 to 3.

    摘要翻译： 本发明提供了一种通过在简单且经济有利的条件下从HFO-1234yf和HF的混合物中除去HF来净化HFO-1234yf的方法。 根据本发明，这是2,3,3,3-四氟丙烯的纯化方法，（1）纯化方法，其包括将包含2,3,3,3-四氟丙烯和氟化氢的混合物进行萃取 在使用萃取剂的蒸馏塔A中进行蒸馏，从而获得含有2,3,3,3-四氟丙烯的馏分I，并且氟化氢与2,3,3,3-四氟丙烯的比例低于混合物， 同时获得含有氟化氢并且比2,3混合物具有较低的2,3,3,3-四氟丙烯与氟化氢的比例II; （2）萃取剂，其包含选自以下的至少一种：（i）由ROH表示的醇，其中R为C 1-5烷基，（ii）由ROR'表示的醚，其中R和R'为 相同或不同，各自为C1-4烷基，（iii）由RfOH表示的氟化醇，其中Rf为C1-3氟代烷基，（iv）由RCOR'表示的酮，其中R和R'为 相同或不同，并且各自为C 1-4烷基，（v）由RCOOR'表示的酯，其中R和R'相同或不同，并且各自为C 1-4烷基，（vi）由 R（OH）n，其中R是C 1-4烷基，n是2至3的整数，和（vii）由R 10（CH 2 CH 2 O）n R 2表示的乙二醇，其中R 1和R 2相同或不同， 各自为氢或C 1-4烷基，n为1〜3的整数。

    Azeotrope-Like Compositions Of Tetrafluoropropene And Water
    69.
    发明申请
    Azeotrope-Like Compositions Of Tetrafluoropropene And Water 有权
    四氟丙烯和水的共沸组合物

    公开(公告)号：US20110275723A1

    公开(公告)日：2011-11-10

    申请号：US13082980

    申请日：2011-04-08

    申请人： Ryan Hulse ,  Haluk Kopkalli ,  Hang T. Pham

    发明人： Ryan Hulse ,  Haluk Kopkalli ,  Hang T. Pham

    IPC分类号： A01N25/02 ,  C07C17/38 ,  C09K3/00

    CPC分类号： C07C21/18 ,  C07C17/38 ,  C07C17/383 ,  C07C17/386 ,  C07C17/389

    摘要： Provided are azeotropic and azeotrope-like compositions of trans-1,3,3,3-tetrafluoropropene (HFO-1234ze(E)) and water. Such azeotropic and azeotrope-like compositions are useful in isolating trans-1,3,3,3-tetrafluoropropene from impurities during production. Azeotropes of the instant invention are similarly useful in final compositions or for the manufacture of final compositions, such as blowing agent, propellants, refrigerants, diluents for gaseous sterilization and the like.

    摘要翻译： 提供了反式-1,3,3,3-四氟丙烯（HFO-1234ze（E））和水的共沸和类共沸组合物。 这种共沸和类共沸组合物可用于在生产过程中从杂质中分离反式-1,3,3,3-四氟丙烯。 本发明的共沸物类似地可用于最终组合物或用于制造最终组合物，例如发泡剂，推进剂，制冷剂，用于气体灭菌的稀释剂等。

    Method of Purifying (Z)-1-Chloro-3,3,3-Trifluoropropene
    70.
    发明申请
    Method of Purifying (Z)-1-Chloro-3,3,3-Trifluoropropene 有权
    纯化（Z）-1-氯-3,3,3-三氟丙烯的方法

    公开(公告)号：US20110270001A1

    公开(公告)日：2011-11-03

    申请号：US13142531

    申请日：2010-01-25

    申请人： Akira Ishihara ,  Yasuo Hibino ,  Ryoichi Tamai

    发明人： Akira Ishihara ,  Yasuo Hibino ,  Ryoichi Tamai

    IPC分类号： C07C17/386

    CPC分类号： C07C17/386 ,  C07C21/18

    摘要： Disclosed is a method of purifying (Z)-1-chloro-3,3,3-trifluoropropene of the formula [1], comprising: distilling a mixture containing (Z)-1-chloro-3,3,3-trifluoropropene and 1-chloro-1,3,3,3-tetrafluoropropane (CF3CH2CHClF), wherein the distilling is performed by extractive distillation of the mixture in the coexistence of at least one kind of compound selected from the group consisting of halogenated hydrocarbons of the formula [2], halogenated unsaturated hydrocarbons, nitriles, ketones, carbonates, ethers, esters and alcohols as an extractant [Chem. 8] CFnCl3-nCHXCClFmH2-m  [2] where X represents a hydrogen atom (H), a fluorine atom (F) or a chlorine atom (Cl); n represents an integer of 0 to 3; and m represents an integer of 0 to 2.

    摘要翻译： 公开了一种纯化式[1]的（Z）-1-氯-3,3,3-三氟丙烯的方法，其包括：蒸馏含有（Z）-1-氯-3,3,3-三氟丙烯和 1-氯-1,3,3,3-四氟丙烷（CF 3 CH 2 CHClF），其中通过萃取蒸馏混合物进行蒸馏，所述混合物共存于至少一种选自式[ 2]，卤代不饱和烃，腈，酮，碳酸酯，醚，酯和醇作为萃取剂[Chem。 8] CF nCl 3-n CHXCClFmH 2-m [2]其中X表示氢原子（H），氟原子（F）或氯原子（Cl）; n表示0〜3的整数， m表示0〜2的整数。