Film forming method and film forming apparatus

    公开(公告)号:US11417521B2

    公开(公告)日:2022-08-16

    申请号:US17150177

    申请日:2021-01-15

    发明人: Hitoshi Kato

    摘要: A film forming method forms a silicon film on a substrate placed on a turntable which rotates and passes through first and second process regions that are mutually separated along a circumferential direction inside a vacuum chamber that is settable to a first temperature at which Si—H bond dissociation can occur. A film forming process includes forming a molecular layer of SiH3 on the substrate, by supplying a Si2H6 gas that is set to a second temperature higher than the first temperature during a time period in which the substrate passes through the first process region, and forming a molecular layer of SiCl3 on the substrate having the molecular layer of SiH3 formed thereon while causing the Si—H bond dissociation in the molecular layer of SiH3, by supplying a gas including silicon and chlorine during a time period in which the substrate passes through the second process region.

    METHOD OF MAKING COMPOSITE ARTICLES FROM SILICON CARBIDE

    公开(公告)号:US20220251702A1

    公开(公告)日:2022-08-11

    申请号:US17731458

    申请日:2022-04-28

    IPC分类号: C23C16/32 C23C16/56

    摘要: A method of forming a composite article may generally comprise forming a mixture of (i) a reactant gas stream comprising hydrogen and methyltrichlorosilane and (ii) solid silicon carbide particles; heating a carbon substrate in the reactor; heating the mixture of the reactant gas stream and solid silicon carbide particles to decompose the methyltrichlorosilane to produce silicon carbide material without causing the solid silicon carbide particles to react and injecting the heated mixture into the reactor; co-depositing the silicon carbide material and the solid silicon carbide particles onto the heated carbon substrate in the reactor to produce a CVD matrix comprising the silicon carbide material and the solid silicon carbide particles by chemical vapor deposition on the heated carbon substrate; post-treating the carbon substrate having the CVD matrix coating in a furnace; and cooling and removing the carbon substrate from the CVD matrix to form the transparent composite article.

    Coating and coated cutting tool comprising the coating

    公开(公告)号:US11371150B2

    公开(公告)日:2022-06-28

    申请号:US16734329

    申请日:2020-01-04

    申请人: Kennametal Inc.

    发明人: Zhenyu Liu

    摘要: A coating includes a layer having an alumina matrix and at least one of zirconia grains and hafnia grains in the alumina matrix. An average grain size of the at least one of the zirconia grains and hafnia grains is 100 nm or less. A coated cutting tool includes a substrate and the coating bonded to the substrate. The substrate has a rake face, a flank face, and a cutting edge formed at the intersection of the rake face and the flank face.

    Method for stabilizing chlorosilane polymer

    公开(公告)号:US11319212B2

    公开(公告)日:2022-05-03

    申请号:US16282413

    申请日:2019-02-22

    申请人: IHI Corporation

    摘要: This disclosure is to make it possible to easily stabilize a chlorosilane polymer while preventing a solid chlorosilane polymer from being generated. Disclosed is a method for stabilizing a chlorosilane polymer generated secondarily in a step of a chemical vapor deposition method using chlorosilane-based gas, the method including: a step of bringing alcohol into contact with the chlorosilane polymer, degrading the chlorosilane polymer to alkoxide, hydrogen chloride and hydrogen, and diluting the degraded alkoxide with the alcohol; and a step of performing hydrolysis for the alkoxide.