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    Ternary intercalation compound of a graphite with a metal fluoride and fluorine, a process for producing the same, and an electrically conductive material comprising the ternary intercalation compound
    51.
    发明授权
    Ternary intercalation compound of a graphite with a metal fluoride and fluorine, a process for producing the same, and an electrically conductive material comprising the ternary intercalation compound 失效
    石墨与金属氟化物和氟的三元插层化合物，其制备方法和包含三元嵌入化合物的导电材料

    公开(公告)号：US4511493A

    公开(公告)日：1985-04-16

    申请号：US530239

    申请日：1983-09-08

    申请人： Nobuatsu Watanabe ,  Tsuyoshi Nakajima ,  Masayuki Kawaguchi

    发明人： Nobuatsu Watanabe ,  Tsuyoshi Nakajima ,  Masayuki Kawaguchi

    IPC分类号： B01J27/12 ,  C01B31/00 ,  C01B31/04 ,  H01B1/04 ,  H01B1/12

    CPC分类号： H01B1/04 ,  B01J27/12 ,  C01B31/0415

    摘要： A novel ternary intercalation compound of a graphite with a metal fluoride and fluorine, which is represented by the formula C.sub.x F(MF.sub.z).sub.y wherein M is a metal is produced by reacting a graphite material with a metal fluoride in an atmosphere of fluorine gas at a temperature of 0.degree. C. to 400.degree. C. for at least a period of time to effect a weight increase in the graphite. The ternary graphite intercalation compound thus obtained has not only an excellent stability to humidity or moisture but also a high electrical conductivity. The novel ternary graphite intercalation compound according to the present invention may be practically used as a novel electrically conductive material and a catalyst of organic reactions.

    摘要翻译： 通过在氟气气氛中使石墨材料与金属氟化物反应，在其中M为金属的式CxF（MFz）y表示的具有金属氟化物和氟的石墨的新颖的三元嵌入化合物 温度为0℃至400℃，持续至少一段时间才能使石墨重量增加。 由此获得的三元石墨插入化合物不仅对湿度或湿度具有优异的稳定性，而且具有高导电性。 根据本发明的新型三元石墨插层化合物可以实际上用作新的导电材料和有机反应的催化剂。

    Fluorine-promoted sulfactive metal hydrogenation catalysts
    54.
    发明授权
    Fluorine-promoted sulfactive metal hydrogenation catalysts 失效
    氟促进磺化金属加氢催化剂

    公开(公告)号：US4220557A

    公开(公告)日：1980-09-02

    申请号：US963573

    申请日：1978-11-24

    申请人： Grant A. Mickelson

    发明人： Grant A. Mickelson

    IPC分类号： B01J23/85 ,  B01J27/12 ,  C10G45/08 ,  B01J23/28 ,  B01J23/30 ,  C10G23/02

    CPC分类号： B01J23/85 ,  B01J27/12 ,  C10G45/08

    摘要： Highly active, acidic sulfactive metal hydrogenation catalysts comprising Mo and/or W plus Ni and/or Co are prepared by methods comprising as the essential novel feature impregnating gamma alumina particles with an aqueous solution having dissolved therein one or more fluosilicates of cobalt and/or nickel, followed by drying and calcining. The resulting compositions contain uniformly distributed fluorine and SiO.sub.2 as active acidic promoters, intimately associated with the sulfactive metal components.

    摘要翻译： 包含Mo和/或W加上Ni和/或Co的高活性酸性磺化金属氢化催化剂是通过包括作为必需的新颖特征的方法制备的，所述方法包括用溶解有一种或多种钴和/或氟化硅的硅酸盐的水溶液浸渍γ氧化铝颗粒 镍，然后干燥和煅烧。 所得组合物含有均匀分布的氟和SiO 2作为活性酸性促进剂，与磺化金属组分密切相关。

    Perfluoroallyl fluorosulfate and its sultone and polymers
    55.
    发明授权
    Perfluoroallyl fluorosulfate and its sultone and polymers 失效
    全氟烯丙基氟硫酸盐及其磺内酯和聚合物

    公开(公告)号：US4206138A

    公开(公告)日：1980-06-03

    申请号：US931905

    申请日：1978-08-08

    申请人： David C. England

    发明人： David C. England

    IPC分类号： B01J27/12 ,  B01J31/02 ,  B01J31/10 ,  B01J31/14 ,  B01J39/04 ,  B01J39/20 ,  C07C305/26 ,  C07D327/02 ,  C08F14/18 ,  C07C141/02 ,  C07C141/10

    CPC分类号： C08F14/185 ,  B01J27/12 ,  B01J31/0212 ,  B01J31/10 ,  B01J39/04 ,  B01J39/20 ,  C07C305/26 ,  C07D327/02

    摘要： Hexafluoropropene is reacted with liquid sulfur trioxide in the presence of boric oxide, boron trichloride, boron trifluoride, tri(lower alkyl) borate, boron trioxychloride or boron trioxyfluoride at from 0.degree. C. to 150.degree. C. to form perfluoroallyl fluorosulfate and the sultone thereof. The perfluoroallyl fluorosulfate can be homopolymerized or copolymerized with various fluoroethylenes to form resins useful as ion exchange resins or catalysts. The fluorosulfate groups on the resins can be hydrolyzed to form carboxylic acid groups or various corresponding salts. The sultone of perfluoroallyl fluorosulfate can be rearranged to form .beta.-fluorocarbonyl-.beta.-fluorosulfonyl-trifluorethyl fluorosulfate.

    摘要翻译： 在0℃至150℃下，在氧化硼，三氯化硼，三氟化硼，三（低级烷基）硼酸盐，三氯氧化硼或三氟氧化硼的存在下，六氟丙烯与液体三氧化硫反应，形成全氟烯丙基氟硫酸盐和磺内酯 其中。 全氟烯丙基氟硫酸盐可以与各种氟乙烯均聚或共聚以形成可用作离子交换树脂或催化剂的树脂。 可以将树脂上的氟硫酸盐基团水解形成羧酸基团或各种相应的盐。 全氟烯丙基氟硫酸盐的磺内酯可重新排列形成β-氟羰基-β-氟磺酰基 - 三氟乙基氟硫酸盐。

    Catalyst pretreatment with hydrocarbon feedstock
    57.
    发明授权
    Catalyst pretreatment with hydrocarbon feedstock 失效
    用烃原料催化剂预处理

    公开(公告)号：US4058575A

    公开(公告)日：1977-11-15

    申请号：US586177

    申请日：1975-06-12

    申请人： Robert P. Cahn ,  John P. Longwell

    发明人： Robert P. Cahn ,  John P. Longwell

    IPC分类号： B01J27/12 ,  C07C5/27 ,  C07C13/00 ,  C07C3/56 ,  C07C5/28

    CPC分类号： B01J27/12 ,  C07C5/2721 ,  Y02P20/584

    摘要： Partially deactivated hydrocarbon conversion catalysts comprising (a) one or more Lewis acids of the formula MX.sub.n where M is a metal selected from Group III-A, IV-B, V or VI-B elements of the Periodic Table, X is a halogen, n is the ratio of halogen atoms to atoms of M and varies from 1-8, and (b) a strong Bronsted acid are contacted with a hydrocarbon feedstock to recover the active or potentially active catalyst species from the partially deactivated catalyst stream prior to regeneration. In addition, potential organic and inorganic catalyst poisons present in said feedstock are removed therefrom during said contacting prior to introducing said feedstock into a hydrocarbon conversion process.

    摘要翻译： 部分失活的烃转化催化剂，其包含（a）一种或多种式MXn的路易斯酸，其中M是选自元素周期表III-A，IV-B，V或VI-B族元素的金属，X是卤素， n是卤素原子与M原子的比率并且从1-8变化，和（b）强烈的布朗斯台德酸与烃原料接触以在再生之前从部分失活的催化剂物流中回收活性或潜在活性的催化剂物质 。 此外，在将所述原料引入烃转化过程之前，在所述接触期间，从所述原料中除去存在于所述原料中的潜在有机和无机催化剂毒物。

    Novel aluminum fluoride catalyst and process for hydrofluorinating acetylene using same
    60.
    发明授权
    Novel aluminum fluoride catalyst and process for hydrofluorinating acetylene using same 失效
    新型氟化铝催化剂及其使用乙炔氢化方法

    公开(公告)号：US3720722A

    公开(公告)日：1973-03-13

    申请号：US3720722D

    申请日：1971-02-18

    申请人： DAIKIN IND LTD

    发明人： WADA H ,  KAWAKAMI Y ,  KAMIHIGOSHI T

    IPC分类号： B01J27/12 ,  C07C17/08

    CPC分类号： C07C17/08 ,  B01J27/12 ,  C07C19/08 ,  C07C21/18

    摘要： Process for hydrofluorinating acetylene which comprises reacting acetylene with hydrogen fluoride in the vapor phase and in the presence of Epsilon -aluminum fluoride at a temperature from about 200*C to about 380*C to produce vinyl fluoride and 1,1difluoroethane, said Epsilon -aluminum fluoride is being prepared by evaporating an aqueous hydrofluoric acid solution of aluminum fluoride to dryness under vacuum at a temperature from 30*to 120*C optionally followed by heating the resulting product at a temperature from 120* to 500*C.

    摘要翻译： 氢化乙炔的方法，其包括在气相和氟化铝存在下，在约200℃至约380℃的温度下使乙炔与氟化氢反应，以产生氟乙烯和1,1-二氟乙烷，所述ε 通过在30〜120℃的温度下真空蒸发氟化铝的氢氟酸水溶液进行干燥，然后在120〜500℃的温度下加热得到的产物，制备了氟化铝。