Abstract:
A hollow gas transfer fibre is arranged in tows and potted into a module. The module may be used to treat wastewater by supplying hydrogen containing gas via the interior of the fibers to a biofilm present on an exterior surface of the fibers.
Abstract:
An apparatus is described for withdrawing filtered permeate from a substrate contained in a reservoir at ambient pressure. The apparatus includes a plurality of membrane assemblies. Each assembly has a plurality of hollow fiber filtering membranes, immersed in the reservoir, at least one permeating header with the membranes sealingly secured therein, and a permeate collector to collect the permeate sealingly connected to the at least one permeating header and in fluid communication with lumens of the membranes. The membranes of each assembly extend generally vertically upwards from a first header during permeation. One or more sources of suction are provided in fluid communication with the lumens of the membranes of each assembly through the permeate collectors and apply sufficient suction to withdraw permeate from the lumens of the membranes. An aeration system for discharging bubbles assists in keeping the membranes clean. In other aspects, a method of removing fouling materials from the surface of a plurality of porous membranes includes providing, from within a membrane module, gas bubbles in a uniform distribution relative to the membranes. The bubbles move past the surfaces of the membranes to dislodge fouling materials from them. The membranes are arranged in close proximity to one another and mounted to prevent excessive movement.
Abstract:
A method of cleaning ultrafiltration or microfiltration membranes reduces the rate of decline in the permeability of the membranes so that intensive recovery cleaning is required less frequently. In one aspect, cleaning events using a chemical cleaner are started before the membranes foul significantly and are repeated between 1 and 7 times per week. The product of the concentration of the chemical cleaner expressed as an equivalent concentration of NaOCl and the duration of all cleaning events is between 2,000 minutes·mg/l and 30,000 minutes·mg/l per week. When performed in situ, each cleaning event comprises (a) stopping permeation and any agitation of the membranes, (b) backwashing the membranes with a chemical cleaner in repeated pulses and (c) resuming agitation, if any, and permeation. The pulses last for between 10 seconds and 100 seconds and there is a time between pulses between 50 seconds and 6 minutes. Each cleaning event typically involves between 5 and 20 pulses. In another aspect, cleaning events using a pulsed backwash of heated water are similarly started before the membranes foul significantly and are repeated between twice a day and once every two days.
Abstract:
An aerator for immersed filtering membranes has an aerator shell with openings for discharging bubbles from its upper surface and a shape capable of temporarily containing a volume of air in fluid communication with the openings. The shell is open to tank water below it and located so that discharged bubbles will rise through an assembly of the filtering membranes. The shell may be wholly or partially made of parts of the assemblies of filtering membranes. A supply of air is provided to the air space in the aerators alternating between a high flow rate and a low flow rate in short cycles of between about 10 seconds and 100 seconds. A filtration system has an inlet for adding substrate and an outlet for retentate are located so as to create a horizontal flow of substrate through the tank. Membrane assemblies are located within the horizontal flow of substrate. Aerators as described above are provided and operated as described above.
Abstract:
An apparatus to transfer gas to or from a liquid has a flexible and oxygen permeable but liquid water impermeable membrane, a flexible and gas permeable spacer, an inlet conduit, an outlet conduit and a non-rigid restraint system. When used for treating wastewater, an aerobic biofilm is cultured adjacent the planar elements, an anoxic biofilm is cultivated adjacent the aerobic biofilm and the wastewater is maintained in an anaerobic state. A first reactor for treating wastewater has an anaerobic section, a plurality of gas transfer membrane modules, and an aerobic section. A biofilm is cultivated on the surface of the gas transfer membranes in fluid communication with the anaerobic section. Biological reduction of COD, BOD, nitrogen and phosphorous are achieved. In a second reactor, phosphorous is also removed chemically in a precipitation branch.
Abstract:
A single tank submerged membrane bioreactor for treating feed water having unacceptable levels of ammonia or total nitrogen has both a membrane scouring bubble supply and an oxygenating bubble supply. The membrane scouring bubble supply continuously provides large scouring bubbles to clean the membranes. Permeate is continuously withdrawn from the membranes at a high rate but the large scouring bubbles do not transfer sufficient oxygen to the mixed liquor to create aerobic conditions in the reactor. The oxygenating bubble supply is operated to provide small bubbles of air or oxygen that intermittently produce aerobic conditions in a significant part of the mixed liquor. Alternating aerobic and anoxic conditions occur in a significant portion of the tank suitable for nitrification and denitrification. The level of dissolved oxygen (DO) or oxygen reduction potential (ORP) in the tank is measured by sensors and determines when the oxygenating bubble supply will be turned on or off between set minimum and maximum time limits.
Abstract:
The outer surfaces of hollow fiber membranes in a skein, or a bank or cassette of stacked skeins, are kept essentially free of solids by maintaining a substantially uniform flow of a stream of coarse bubbles through each of plural orifices in an aerator disposed beneath the fibers. Aerators for skeins used in microfiltration of wastewater in a tank are periodically flushed by injecting flushing air into permeate returned to the tank over a short period. The air is injected into returning permeate for less than 1 minute, preferably less than 20 sec so as to produce discrete masses of water which are flowed laterally through the body of the aerator, cleaning its walls and maintaining the orifices essentially free from plugging.
Abstract:
A gas-scrubbed vertical cylindrical skein of "fibers" has their opposed terminal portions held in headers unconfined in a modular shell, and aerated with a cleansing gas supplied by a gas-distribution means which produces a mass of bubbles serving the function of a scrub-brush for the outer surfaces of the fibers. The skein is surprisingly effective with relatively little cleansing gas, the specific flux through the membranes reaching an essentially constant relatively high value because the vertical deployment of fibers allows bubbles to rise upwards along the outer surfaces of the fibers. The effectiveness is critically dependent upon the length of each fiber in the skein. That length is in the range from at least 0.1% more than the fixed distance between opposed faces of the skein's headers, but less than 5% greater than the fixed distance. Lack of tension allows the fibers to sway in bubbles flowing along their outer surfaces making them surprisingly resistant to being fouled by build-up of deposits of inanimate particles or microorganisms in the substrate. For use in a large reservoir, a bank of skeins is used with a gas distributor means which has fibers preferably >0.5 meter long, which together provide a surface area >10 m.sup.2. The terminal end portions of fibers in each header are kept free from fiber-to-fiber contact with a novel method of forming a header.
Abstract:
A wastewater feed containing an ultimate BOD/COD ratio >0.6 is well-suited for especially acclimated thermophilic and/or caldo-active living micro-organisms ("hot cells") which thrive in an autothermal aerobic (ATA) reaction zone having an ATA bioreactor ("ATAB") operating at substantially ambient atmospheric pressure in combination with a MF or UF membrane filtration device from which a solids-free permeate may be withdrawn. This combination, of ATAB and membrane device is a "membrane bioreactor" (ATA MBR), which operates autothermally with a feed containing biodegradable organic materials having a BOD of at least 5,000 mg/L, preferably at least 10,000 mg/L (10 g/L) with a minor portion of "municipal" wastewater or domestic sewage. Operation of the ATAB, preferably in the thermophilic range from 45.degree. C.-75.degree. C., with constant HRT from 1 to 12 days, is contingent upon maintaining a stable population of live hot cells. Such cells enhance the biokinetics of degradation and allow operation of the ATAB at higher COD loading and a lower concentration of TSS, than would be possible at a lower temperature. A surprisingly high membrane productivity allows production of much less sludge to be disposed of outside the system, than would have to be disposed of with a conventional mesophilic reactor in normal operation with a HRT of less than 24 hr. A combination of an MP MBR with an ATA MBR is highly effective when the MPB produces high BOD concentration mixed liquor for destruction by the ATAB.
Abstract:
The invention provides a new method and apparatus for measuring the concentration of ultra-violet light absorbing organic materials liquids, particularly in pure or ultra-pure water, the speed and convenience being such that it is possible to take successive readings with periods as short as ten seconds. The apparatus can be mounted directly in or as a by-pass to a process stream, giving the capability of constant monitoring with virtually instant microprocessor-controlled response to measurements outside a pre-set range. The water to be measured passes upwards in a cylindrical opaque-walled sample cell at the upper end of which is mounted an intense light source, preferably a Xenon flash tube, and at the lower end of which is mounted two transmission photodetectors, which have in front of them respective narrow-band optical transmission filters in the ultra-violet and visible regions. The light source sits on the upper end of a quartz rod which extends into the cell at or below the water inlet and is coaxial with the cell longitudinal axis, the rod serving to direct the light toward the transmission photodetectors. The output from the "visible" photodetector is used to correct the output from the "ultraviolet" photodetector for transmission losses caused by particulates, element fouling and bubbles in the stream. Two reference photodetectors employing two similar transmission filters are disposed close to the flash tube outlet window and their signals are used to correct for variation in the flash tube output.