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    Calcined UZM-22 and UZM-22HS aluminosilicate zeolites
    51.
    发明授权
    Calcined UZM-22 and UZM-22HS aluminosilicate zeolites 有权
    煅烧的UZM-22和UZM-22HS铝硅酸盐沸石

    公开(公告)号：US08349291B2

    公开(公告)日：2013-01-08

    申请号：US12821555

    申请日：2010-06-23

    申请人： Mark A. Miller ,  Jaime G. Moscoso ,  Gregory J. Lewis

    发明人： Mark A. Miller ,  Jaime G. Moscoso ,  Gregory J. Lewis

    IPC分类号： C01B39/46 ,  C01B39/48

    CPC分类号： B01J29/70 ,  C01B39/06 ,  C01B39/48 ,  C10G29/205 ,  C10G45/64 ,  C10G49/08 ,  C10G50/00

    摘要： Crystalline microporous zeolites designated calcined UZM-22 and UZM-22HS have been synthesized. The calcined UZM-22 is represented by the empirical formula: M1′mn+Al1-xExSiyOz and UZM-22HS has an empirical formula of: M1an+Al(1-x)ExSiy′Oz″ where M1 and M1′ are exchangeable cations such as lithium or strontium and E is a framework element such as gallium. Both zeolites are obtained from an as synthesized microporous crystalline composition having an empirical formula of: Mmn+RrAl1-xExSiyOz either by calcination for UZM-22 or by various treatments such as ammonium hexafluorosilicate treatment for UZM-22HS.M is an alkali, alkaline earth, or rare earth metal such as lithium and strontium, R is a singly charged organoammonium cation such as the choline cation and E is a framework element such as gallium.

    摘要翻译： 已经合成了称为煅烧UZM-22和UZM-22HS的结晶微孔沸石。 煅烧的UZM-22由经验式表示：M1'mn + Al1-xExSiyOz，UZM-22HS具有经验式：M1an + Al（1-x）ExSiy'Oz“，其中M1和M1'是可交换阳离子 作为锂或锶，E是诸如镓的骨架元素。 两种沸石均由具有经验式：Mmn + RrAl1-xExSiyOz的合成微孔结晶组合物获得，其通过煅烧UZM-22或通过各种处理如六氟硅酸铵处理用于UZM-22HS。M是碱，碱土 ，或稀土金属如锂和锶，R是单电荷的有机铵阳离子，如胆碱阳离子，E是骨架元素如镓。

    MICROPOROUS UZM-5 INORGANIC ZEOLITE MEMBRANES FOR GAS, VAPOR, AND LIQUID SEPARATIONS
    52.
    发明申请
    MICROPOROUS UZM-5 INORGANIC ZEOLITE MEMBRANES FOR GAS, VAPOR, AND LIQUID SEPARATIONS 失效
    用于气体，蒸气和液体分离的微波UZM-5无机沸石膜

    公开(公告)号：US20120240763A1

    公开(公告)日：2012-09-27

    申请号：US13052720

    申请日：2011-03-21

    申请人： Chunqing Liu ,  Jaime G. Moscoso ,  Stephen T. Wilson

    发明人： Chunqing Liu ,  Jaime G. Moscoso ,  Stephen T. Wilson

    IPC分类号： B01D53/22 ,  B01J20/32

    CPC分类号： B01D71/028 ,  B01D53/228 ,  B01D67/0048 ,  B01D67/0051 ,  B01D67/0088 ,  B01D69/10 ,  B01D2323/14 ,  B01J20/186 ,  B01J20/28007 ,  B01J20/28035 ,  B01J20/3057 ,  B01J20/3078 ,  B01J20/3085 ,  B01J20/3238 ,  B01J20/3272 ,  B82Y30/00

    摘要： The present invention discloses microporous UZM-5 zeolite membranes, methods for making the same, and methods of separating gases, vapors, and liquids using the same. The small-pore microporous UZM-5 zeolite membrane is prepared by two different methods, including in-situ crystallization of one or more layers of UZM-5 zeolite crystals on a porous membrane support, and a seeding method by in-situ crystallization of a continuous second layer of UZM-5 zeolite crystals on a seed layer of UZM-5 zeolite crystals supported on a porous membrane support. The membranes in the form of disks, tubes, or hollow fibers have superior thermal and chemical stability, good erosion resistance, high CO2 plasticization resistance, and significantly improved selectivity over polymer membranes for gas, vapor, and liquid separations.

    摘要翻译： 本发明公开了微孔UZM-5沸石膜，其制造方法，以及使用其分离气体，蒸汽和液体的方法。 小孔微孔UZM-5沸石膜通过两种不同的方法制备，包括在多孔膜载体上的一层或多层UZM-5沸石晶体的原位结晶，以及通过原位结晶的接种方法 在支撑在多孔膜载体上的UZM-5沸石晶种的种子层上连续的第二层UZM-5沸石晶体。 圆盘，管或中空纤维形式的膜具有优异的热稳定性和化学稳定性，良好的抗侵蚀性，高的二氧化碳抗塑化性，并且对于气体，蒸汽和液体分离，在聚合物膜上显着提高了选择性。

    PROCESS OF MAKING ASYMMETRIC POLYBENZOXAZOLE MEMBRANES
    55.
    发明申请
    PROCESS OF MAKING ASYMMETRIC POLYBENZOXAZOLE MEMBRANES 审中-公开
    制备不对称聚苯并噻唑膜的方法

    公开(公告)号：US20110316181A1

    公开(公告)日：2011-12-29

    申请号：US12823154

    申请日：2010-06-25

    申请人： Chunqing Liu ,  Raisa Minkov ,  Syed A. Faheem ,  Jaime G. Moscoso

    发明人： Chunqing Liu ,  Raisa Minkov ,  Syed A. Faheem ,  Jaime G. Moscoso

    IPC分类号： B01D67/00 ,  B01D63/02

    CPC分类号： B01D71/62 ,  B01D53/228 ,  B01D67/0079 ,  B01D67/0083 ,  B01D67/0088 ,  B01D69/08 ,  B01D71/028 ,  B01D71/64 ,  D01D5/04 ,  D01D5/24 ,  D01F6/74

    摘要： The present invention provides a process for making an integrally skinned asymmetric polybenzoxazole hollow fiber membrane comprising spinning a dope solution via a dry-wet phase inversion technique to form a porous integrally skinned asymmetric o-hydroxy substituted polyimide or an o-hydroxy substituted polyamide hollow fiber membrane comprising microporous inorganic molecular sieve followed by thermal rearrangement at a temperature from about 250° to 500° C. to convert the polyimide or polyamide membrane into a polybenzoxazole membrane. These membranes contain microporous inorganic molecular sieve materials that can have a particle size from about 20 nm to 10 μm.

    摘要翻译： 本发明提供一种制备整体表皮的不对称聚苯并恶唑中空纤维膜的方法，包括通过干 - 湿相转化技术纺丝掺杂溶液以形成多孔整体表皮的不对称羟基取代的聚酰亚胺或邻羟基取代的聚酰胺中空纤维 膜，其包含微孔无机分子筛，随后在约250℃至500℃的温度下热重排，以将聚酰亚胺或聚酰胺膜转化为聚苯并恶唑膜。 这些膜含有可以具有约20nm至10μm的粒度的微孔无机分子筛材料。

    Aromatic alkylation process using UZM-37 aluminosilicate zeolite
    57.
    发明授权
    Aromatic alkylation process using UZM-37 aluminosilicate zeolite 有权
    使用UZM-37铝硅酸盐沸石的芳香族烷基化方法

    公开(公告)号：US08058495B2

    公开(公告)日：2011-11-15

    申请号：US13157026

    申请日：2011-06-09

    申请人： Deng-Yang Jan ,  Jaime G. Moscoso

    发明人： Deng-Yang Jan ,  Jaime G. Moscoso

    IPC分类号： C08C2/66

    CPC分类号： C07C2/66 ,  Y02P20/52 ,  C07C15/073 ,  C07C15/085 ,  C07C15/02

    摘要： A new family of crystalline aluminosilicate zeolites has been synthesized. These zeolites are represented by the empirical formula. Mmn+Rr+Al(1-x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the propyltrimethylammonium cation and E is a framework element such as gallium. These zeolites are similar to MWW but are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out alkylation processes.

    摘要翻译： 已经合成了一系列结晶硅铝酸盐沸石。 这些沸石由经验公式表示。 Mmn + Rr + Al（1-x）ExSiyOz其中M表示钾和钠可交换阳离子的组合，R是单电荷的有机铵阳离子，例如丙基三甲基铵阳离子，E是骨架元素如镓。 这些沸石类似于MWW，但是其特征在于独特的x射线衍射图案和组合物，并具有用于进行烷基化方法的催化性能。

    Process for alkylation of aromatic hydrocarbons using UZM-35
    59.
    发明授权
    Process for alkylation of aromatic hydrocarbons using UZM-35 有权
    使用UZM-35烷基化芳烃的方法

    公开(公告)号：US07982082B1

    公开(公告)日：2011-07-19

    申请号：US12820102

    申请日：2010-06-21

    申请人： Christopher P Nicholas ,  Deng-Yang Jan ,  Jaime G. Moscoso

    发明人： Christopher P Nicholas ,  Deng-Yang Jan ,  Jaime G. Moscoso

    IPC分类号： C07C2/66

    CPC分类号： C07C2/66 ,  C07C2529/70 ,  C07C2529/80 ,  C07C15/085 ,  C07C15/02

    摘要： Alkylation processes such as the alkylation of aromatics, are catalyzed by the UZM-35 family of crystalline aluminosilicate zeolitic compositions represented by the empirical formula: Mmn+Rr+Al(1-x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the dimethyldipropylammonium cation and E is a framework element such as gallium. These UZM-35 zeolitic compositions are active and selective in alkylation processes.

    摘要翻译： 烷基化方法如芳族化合物的烷基化由UZM-35族晶体硅铝酸盐沸石组合催化，由经验式表示：Mmn + Rr + Al（1-x）ExSiyOz，其中M表示钾和钠可交换阳离子的组合 R是单电荷的有机铵阳离子，例如二甲基二丙基铵阳离子，E是骨架元素如镓。 这些UZM-35沸石组合物在烷基化方法中是活性的和选择性的。