摘要:
A process for upgrading oils is disclosed, in which the oil to be upgraded is contacted with liquid phase water and free oxygen at an elevated temperature and at a pressure sufficient to maintain at least part of the water in the liquid phase.
摘要:
Disclosed are a catalytic composite, and a method of preparing a catalytic composite, useful in the treatment of sour mercaptan-containing petroleum distillates, and a method of using the catalytic composite in treating sour petroleum distillates. More specifically, the method of preparation comprises contacting a molecular sieve support with a specified substituted ammonium compound, drying the resulting composite, thereafter contacting the resulting composite with an alkali metal hydroxide and a metal chelate, the alkali metal hydroxide being in a weight ratio with the adsorptive support of from about 0.1:1 to about 1:1, and thereafter drying the resulting catalytic composite. A sour petroleum distillate can be treated with the catalytic composite by contacting the distillate at oxidation conditions with the catalytic composite.
摘要:
Petrolatums are oxidized to high acid numbers by agitating a liquid petrolatum charge with the halide salt of an alkali metal, alkali earth metal or substituted ammonium halide while forcing gaseous air or oxygen through the liquid charge.
摘要:
A transformer oil processing sequence is disclosed. The process comprises contacting a naphthenic based oil with an oxygen-containing gas in the presence of a permanganate under mild oxidation conditions of temperature and pressure and caustic washing the resultant product. The caustic washed product is then subjected to two pass hydrogenation to provide a transformer oil having superior Doble oxidation resistance values.
摘要:
A process for reducing the sulfur content of hydrocarbon material by contacting, e.g., heating, the sulfur-containing hydrocarbon material with at least one hydrocarbon hydrogen donor component capable of transferring hydrogen under conditions such that hydrogen transfer from said component to the sulfur-containing hydrocarbon material occurs to form hydrogen sulfide, oxidizing at least a portion of the remaining sulfur impurities contained in the hydrocarbon material and recovering a hydrocarbon material of reduced sulfur content.
摘要:
This invention relates to a method for improving the oxidative stability of hydrocarbon lubricating oils by contact with a gas containing free oxygen in the presence of a solid basic refractory oxide catalyst, characterized by the presence therein of a minor proportion of alkali metal, under specified conditions of temperature and pressure.
摘要:
ORGANIC COMPOUNDS ARE DEHYDROGENATED IN THE PRESENCE OF MOLECULAR OXYGEN WITH A CATALYST CONTAINING AT LEAST ONE OF THE ELEMENTS NICKEL, COBALT OR IRON IN ASSOCIATION WITH TIN, PHOSPHORUS, AND AT LEAST ONE OF ARSENIC, ANTIMONY OR BISMUTH TOGETHER WITH SUFFICIENT COMBINED OXYGEN TO SATISFY THE VALENCE REQUIREMENTS OF THE COMPONENTS OF THE CATALYST. OPTIONALLY, THE CATAYTIC COMPOSITIONS CAN CONTAIN MINOR AMOUNTS OF ALKALI METAL SUCH AS POTASSIUM. REPRESENTATIVE OF SUCH CONVERSIONS IS THE OXIDATIVE DEHYDROGENATION OF BUTANE TO BUTENES AND BUTADINE. THE CONVERSION PRODUCTS ARE VALUABLE COMPOUNDS PARTICULARLY USEFUL AS INTERMEDIATES FOR THE PREPARATION OF POLYMERIC MATERIALS SUCH AS SYNTHETIC RUBBERS AND THE LIKE.
摘要:
THE ON-STREAM LIFE IN A SWEETENING PROCESS USING A COPPER-IRON CATALYST IS EXTENDED BY INCORPORATING IN THE FEED A MINOR AMOUNT OF A NITROGEN CONTAINING COMPOUND HAVING THE FORMULA: R-N(-R'')-R" WHERE R, R'' AND R" CAN BE THE SAME OR DIFFERENT AND ARE SELECTED FROM HYDROGEN, A HYDROCARBON GROUP HAVING FROM 1 TO 10 CARBON ATOMS AND WHERE OPTIONALLY THE HYDROCARBON GROUPS CAN BE CYCLICIZED TO FORM A FIVE OR SIX MEMBERED HETEROCYCLIC COMPOUND. THE PREFERRED NITROGEN CONTAINING COMPOUNDS ARE AMMONIA AND PYRIDINE.
摘要:
PRODUCTION OF AN SO2 FREE GAS BY OXIDATION OF SULFUR CONTAINING MATERIALS IN A FLUIDIZED BED OF CALCIUM OR MAGNESIUM OXIDE WITH REGENERATION OF THE OXIDES FROM SULFATES FORMED IN THE OXIDATION.
摘要:
A COPPER-IRON GROUP METAL CATALYST USEFUL FOR THE CONVERSION OF THIOLS TO DISULFIDES IS PREPARED BY CO-IMPREGNATING A SUPPORT WITH A SOLUTION OF A COPPER SALT AND AN IRON GROUP METAL SALT BY THE METHOD OF MINIMUM EXCESS SOLUTION.