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    NON-PHTHALATE COMPOUNDS AS ELECTRON DONORS FOR POLYOLEFIN CATALYSTS
    46.
    发明申请
    NON-PHTHALATE COMPOUNDS AS ELECTRON DONORS FOR POLYOLEFIN CATALYSTS 有权
    作为聚烯烃催化剂的电子助剂的非对苯二甲酸酯化合物

    公开(公告)号：US20140275456A1

    公开(公告)日：2014-09-18

    申请号：US13827509

    申请日：2013-03-14

    申请人： Formosa Plastics Corporation, USA

    发明人： Demin Xu ,  Lei Zhang

    IPC分类号： C08F4/52

    CPC分类号： C08F4/52 ,  C08F4/6546 ,  C08F110/06 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/6548 ,  C08F4/651

    摘要： Non-phthalate compounds having a structure represented by the general formula and a method for using same are provided as electron donors in the Ziegler-Natta type catalyst system for the homopolymerization or copolymerization of alpha olefins. The non-phthalate compounds may be used in the preparation of the solid catalyst component, thus serving as “internal electron donors”, or employed during or prior to polymerization as “external electron donors,” and therefore they can be used to prepare phthalate-free polyolefins.

    摘要翻译： 在用于α-烯烃的均聚或共聚的齐格勒 - 纳塔型催化剂体系中，作为电子给体提供具有通式所示结构的非邻苯二甲酸酯化合物及其使用方法。 非邻苯二甲酸酯化合物可用于制备固体催化剂组分，因此用作“内电子供体”，或在聚合期间或之前用作“外电子供体”，因此它们可用于制备邻苯二甲酸酯 - 游离聚烯烃。

    SOLID CATALYST COMPONENT AND CATALYST FOR OLEFIN POLYMERIZATION
    48.
    发明申请
    SOLID CATALYST COMPONENT AND CATALYST FOR OLEFIN POLYMERIZATION 有权
    用于烯烃聚合的固体催化剂组分和催化剂

    公开(公告)号：US20130324682A1

    公开(公告)日：2013-12-05

    申请号：US13980359

    申请日：2012-01-19

    申请人： Zhong TAN ,  Lunjia Xie ,  Xiudong Xu ,  Yu Tian ,  Qilong Zhou ,  Zaixing Feng ,  Li'an Yan ,  Siyuan Zhao ,  Jinhua Yu ,  Zhufang Sun ,  Fengkui Li ,  Shanshan Yin ,  Weiwei Song

    发明人： Zhong TAN ,  Lunjia Xie ,  Xiudong Xu ,  Yu Tian ,  Qilong Zhou ,  Zaixing Feng ,  Li'an Yan ,  Siyuan Zhao ,  Jinhua Yu ,  Zhufang Sun ,  Fengkui Li ,  Shanshan Yin ,  Weiwei Song

    IPC分类号： C08F110/06

    CPC分类号： C08F110/06 ,  C08F10/06 ,  C08F4/651 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/15 ,  C08F4/6548

    摘要： Disclosed is a solid catalyst component for olefin polymerization. The catalyst component comprises a dialkoxy magnesium carrier, a titanium compound, and a product from an internal electron donor reacting in an inert solvent. Said internal electron donor compound comprises a 2,3-di-non-linear-alkyl-2-cyano succinic acid diester compound as presented in formula I: as in formula I, R1 and R2 radicals are independently chosen from linear or branched C1-C4 alkyl groups; R is chosen from C3-C6 iso-alkyl, sec-alkyl, or cycloalkyl groups. Also disclosed is another solid catalyst component. The catalyst component comprises a dialkoxy magnesium carrier, a titanium compound, and a product from an internal electron donor reacting in an inert solvent. In addition to a 2,3-di-non-linear-alkyl-2-cyano succinic acid diester compound as presented in formula I, the internal electron donor compound can also comprise 2-isopropyl-2-(3-methylbutyl)-1,3-dimethoxy propane and/or a carboxylic ester compound. Also disclosed is a catalyst containing the solid catalyst component. The catalyst is used for olefin polymerization, particularly propylene polymerization, and is relatively active during polymerization. The obtained polymer has the advantages of wide molecular weight distribution, high molecular bulk density, good hydrogen regulation sensitivity, good stereospecificity, good particle shape, and small fine powder content.

    摘要翻译： 公开了用于烯烃聚合的固体催化剂组分。 催化剂组分包括二烷氧基镁载体，钛化合物和在惰性溶剂中反应的内电子给体的产物。 所述内电子给体化合物包含式I所示的2,3-二 - 非线性 - 烷基-2-氰基琥珀酸二酯化合物：如式I所示，R 1和R 2基团独立地选自直链或支链C1- C4烷基; R选自C 3 -C 6异烷基，仲烷基或环烷基。 还公开了另一种固体催化剂组分。 催化剂组分包括二烷氧基镁载体，钛化合物和在惰性溶剂中反应的内电子给体的产物。 除了式I所示的2,3-二 - 非线性 - 烷基-2-氰基琥珀酸二酯化合物之外，内电子给体化合物还可以包含2-异丙基-2-（3-甲基丁基）-1 ，3-二甲氧基丙烷和/或羧酸酯化合物。 还公开了含有固体催化剂组分的催化剂。 该催化剂用于烯烃聚合，特别是丙烯聚合，并且在聚合期间相对有活性。 得到的聚合物具有分子量分布宽，分子体积密度高，调节灵敏度好，立体定向性好，粒子形状好，细粉含量低的优点。

    Ziegler-natta catalyst systems and polymers formed therefrom
    49.
    发明授权
    Ziegler-natta catalyst systems and polymers formed therefrom 有权
    齐格勒 - 纳塔催化剂体系和由其形成的聚合物

    公开(公告)号：US08592535B2

    公开(公告)日：2013-11-26

    申请号：US12685198

    申请日：2010-01-11

    申请人： Kayo Vizzini ,  David Knoeppel ,  Lei Zhang

    发明人： Kayo Vizzini ,  David Knoeppel ,  Lei Zhang

    IPC分类号： C08F4/46 ,  C08F4/18

    CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F4/6548 ,  C08F4/6555 ,  C08F2500/07 ,  C08F2500/26

    摘要： Processes of forming catalyst systems, catalyst systems and polymers formed therefrom are described herein. The processes generally include providing a first compound including a magnesium dialkoxide, contacting the first compound with a second compound to form a solution of reaction product “A”, wherein the second compound is generally represented by the formula: Ti(OR1)4; wherein R1 is selected from C1 to C10 linear to branched alkyls, contacting the solution of reaction product “A” with a first metal halide to form a solid reaction product “B”, contacting solid reaction product “B” with a second metal halide to form reaction product “C” and contacting reaction product “C” with reducing agent to form a catalyst component.

    摘要翻译： 本文描述了形成催化剂体系，催化剂体系和由其形成的聚合物的方法。 所述方法通常包括提供包含二烷氧基镁的第一化合物，使第一化合物与第二化合物接触以形成反应产物“A”的溶液，其中第二化合物通常由下式表示：Ti（OR 1）4; 其中R1选自C1至C10直链至支链烷基，使反应产物“A”的溶液与第一金属卤化物接触以形成固体反应产物“B”，使固体反应产物“B”与第二金属卤化物接触 形成反应产物“C”并使反应产物“C”与还原剂接触以形成催化剂组分。