Abstract:
Aqueous emulsion adhesives having a pH from 2 to 6 which comprise homo- or copolymeric polyvinyl esters, polymeric protective colloids, water-soluble compounds which can be complexed with the polymeric protective colloids, and at least partially masked polyaldehydes having at least 3 carbon atoms from which aldehyde groups can be released in a controlled manner in acidic media are suitable for bonding porous and semiporous substrates.
Abstract:
A water-resistant, anti-static pressure-sensitive adhesive tape suitable for use as a wafer dicing tape comprising a flexible substrate having opposing surfaces, at least one surface bearing thereon a removable, aziridine-crosslinked microparticulate adhesive comprised of microparticles having a surface bearing thereon an ionic conductive material formed from a polymer electrolyte base polymer, and at least one ionic salt selected from the group consisting of salts of alkali metals and salts of alkaline earth metals, wherein said microparticles have an average diameter of at least about 1 micrometer, said adhesive having an adhesion to steel of from about 0.5 Newtons/100 mm (N/100 mm) to about 10 N/100 mm.
Abstract:
Water resistant emulsions for woodworking adhesives may be prepared using an emulsion polymer, the polymer being prepared in the presence of 1 to 2.5% by weight of 88% hydrolyzed polyvinyl alcohol and 1 to 4% by weight of 95-99.5% (or above) hydrolyzed polyvinyl alcohol.
Abstract:
The invention relates to aqueous contact adhesive dispersions containing, based on the total weight of the dispersion, from 40 to 70% by weight of a copolymer prepared by emulsion polymerization, where the copolymer containsa) from 40 to 70% by weight of vinyl esters of aliphatic carboxylic acids having 2 to 12 carbon atoms,b) from 10 to 40% by weight of acrylic acid esters of aliphatic alcohols having 4 to 12 carbon atoms,c) from 8 to 15% by weight of methacrylic acid esters of aliphatic alcohols having 4 to 12 carbon atoms,d) from 0.1 to 3% by weight of ethylenically unsaturated compounds which cause cross-linking,e) from 0.1 to 5% by weight of ethylenically unsaturated carboxylic acids,f) from 0.1 to 2% by weight of substituted and unsubstituted (meth)acrylamides,g) from 0.5 to 3% by weight of ethylenically unsaturated hydroxyalkyl-functional compounds, andh) from 0.5 to 3% by weight of ethylenically unsaturated sulfates and/or sulfonates.The invention furthermore relates to a process for the preparation of the contact adhesive dispersions and to their use.
Abstract:
Formaldehyde free crosslinking emulsion polymers are prepared by the addition of N-(2,2-dialkoxy-1-hydroxy)ethyl acrylamide to a vinyl ester based polymer. The resultant emulsions can be used as binders for nonwovens or fiberfill or as woodworking adhesives.
Abstract:
Wet laminating adhesives capable of withstanding the stresses encountered during heat sealing operations are prepared from emulsion copolymers consisting essentially of 45 to 80% by weight of a vinyl ester of an alkanoic acid, 10 to 30% ethylene, 5 to 30% of dialkyl maleate, 0.5 to 2% of an N-methylol containing comonomer and 0.5 to 4% of an ethylenically unsaturated mono- or di-carboxylic acid. These specific emulsion copolymers are prepared utilizing standard emulsion polymerization procedures with hydroxyethylcellulose or polyvinyl alcohol as a protective colloid. The emulsion polymers thus produced provide superior wet laminating adhesive properties for use in substrates which are to be formed into microwavable packages or bags.
Abstract:
This invention provides an adhesive composition which comprises 1 part by weight of (a) a compound of the general formula: ##STR1## wherein R.sub.1 represents H, a hydrocarbon group of 1-6 carbon atoms optionally containing halogen, COOR', wherein R' represents a hydrocarbon group of 1-20 carbon atoms optionally containing halogen or halogen;R.sub.2 is as defined for R.sub.1 ;R.sub.3 represents H, a hydrocarbon group of 1-6 carbon atoms optionally containing halogen, halogen or CN;R.sub.4 represents (COX.sub.2).sub.m1 (CO).sub.m2 (ZCO).sub.m3 (Z).sub.m4 Ra wherein Ra represents an organic residue of 6-60 carbon atoms and a valency of m+n ; m1, m2, m3 and m4 each represents an integer of 0-4 and satisfies m1+m2+m3+m4.ltoreq.m; X.sub.2 represents O, S or NRb, (wherein Rb represents H or alkyl of 1-4 carbon atoms and Z represents O or S;X.sub.1 is as defined for X.sub.2 ;m is an integer of 1-4;n is an integer of 2-6; andk is 0 or 1,and 0-199 parts by weight of (b) a vinyl monomer copolymerizable with the aforesaid compound. Such an adhesive composition can strongly adhere to any of the hard tissues of the living body, such as teeth and bones, metal materials, organic polymer materials and ceramic materials, and, in particular, has an advantage in that it can maintain high adhesive strength for a long time under wet conditions. While the adhesive composition of this invention may be used in various fields, it is especially useful in the dentistry field.
Abstract:
Diallyl Phthalate compounds having a molecular weight of 250 to 20,000 and having at least one silyl group represented by the formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are each a hydrogen or a monovalent hydrocarbon radicals having 1 to 10 carbon atoms, such as alkyl, aryl or aralkyl radicals; X is a group selected from halogen, alkoxy, acryloxy, aminoxy, phenoxy, thioalkoxy and amino groups, and "a" is an integer 0, 1 or 2, in the molecule; and process for producing same wherein a diallyl phthalate monomer or prepolymer having molecular weight of 20,000 or less is reacted with a hydrosilane compound having the formula: ##STR2## wherein the designations are the same as above, and at a temperature within the range of 50.degree. to 150.degree. C.
Abstract:
Aqueous adhesive emulsions based on aqueous emulsion copolymers of vinyl esters such as vinyl acetate, especially with ethylene, are provided with improved solvent insolubility and adhesion characteristics in the presence of hydroxy functional protective colloid which is present during the copolymerization, by the inclusion in the copolymer of a monoethylenic carbamate, especially allyl carbamate.
Abstract:
This invention relates to vinyl acetate polymer adhesives which are room temperature curable under acidic conditions and more particularly to aqueous adhesives curable at room temperature comprising a vinyl acetate polymer, an N-hydroxymethyl reactive monomer copolymerizable with said polymer, an acidic curing agent, and a volatile curing inhibitor selected from the group consisting of substituted and unsubstituted C1-C5 aliphatic primary alcohols having a boiling point below about 150* C.