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31.发明授权Method for producing polydienes and polydiene copolymers with reduced cold flow 有权降低冷流的制备聚二烯和聚二烯共聚物的方法公开(公告)号：US09512263B2
公开(公告)日：2016-12-06
申请号：US14363944
申请日：2012-12-10
CPC分类号： C08G18/69 , C08C19/22 , C08C19/44 , C08G18/3206 , C08G18/73 , C08G2380/00
摘要： A method for preparing a coupled polymer, the method comprising the steps of: (i) polymerizing monomer to form a reactive polymer; (ii) reacting the reactive polymer with a polyisocyanate having a functionality of X to form an intermediate polymer product; and (iii) reacting the intermediate polymer product with a polyol having a functionality of Y to form the coupled polymer product, where X+Y≧5.
摘要翻译： 一种制备偶联聚合物的方法，所述方法包括以下步骤：（i）聚合单体以形成反应性聚合物; （ii）使反应性聚合物与官能度为X的多异氰酸酯反应以形成中间体聚合物产物; 和（iii）使中间聚合物产物与官能度为Y的多元醇反应，形成偶联聚合物产物，其中X +Y≥5。
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公开(公告)号：US20160340446A1
公开(公告)日：2016-11-24
申请号：US15115171
申请日：2014-12-22
IPC分类号： C08C19/22 , C08K3/36 , C07D233/64 , C07C251/48 , C07D213/53 , C08L9/06 , C08L7/00
CPC分类号： C08C19/22 , B60C1/0016 , C07C251/48 , C07D213/53 , C07D233/64 , C08K3/36 , C08L7/00 , C08L9/06 , C08L15/00 , C08L21/00 , C08L2205/025
摘要： The purpose of the present invention is to provide a modified polymer that significantly reduces heat build-up due to the modification when the modified polymer is formed into a rubber composition, a rubber composition containing the modified polymer, and a pneumatic tire in which the rubber composition is used. The modified polymer of the present invention is a modified polymer obtained by modifying a styrene-conjugated diene copolymer (A) with a nitrone compound (B). In the modified polymer, the content of styrene units in the styrene-conjugated diene copolymer (A) is 10% by mass or greater, and the proportion of vinyl bonds among all the double bonds contained in the styrene-conjugated diene copolymer (A) is 5 mol % or greater.
摘要翻译： 本发明的目的是提供一种改性聚合物，其在改性聚合物形成橡胶组合物时的改性，含有改性聚合物的橡胶组合物和充气轮胎显着降低发热，其中橡胶 使用组合。 本发明的改性聚合物是通过用硝酮化合物（B）改性苯乙烯 - 共轭二烯共聚物（A）而获得的改性聚合物。 在改性聚合物中，苯乙烯 - 共轭二烯共聚物（A）中苯乙烯单元的含量为10质量％以上，苯乙烯 - 共轭二烯共聚物（A）中所含的全部双键中的乙烯基键的比例为 为5摩尔％以上。
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公开(公告)号：US09493599B2
公开(公告)日：2016-11-15
申请号：US14443371
申请日：2013-11-15
发明人： Ryota Takahashi , Takahiro Okamatsu
IPC分类号： C08F8/30 , C08C19/22 , C08F236/10 , B60C1/00 , C08K5/32
CPC分类号： C08F236/10 , B60C1/00 , C08C19/22 , C08F8/30 , C08K5/32
摘要： The present technology provides a modified polymer which is modified with two or more types of nitrones that include a nitrone having at least one carboxy group and a nitrone having no carboxy group.
摘要翻译： 本技术提供了一种改性聚合物，其被两种或更多种类型的硝酸盐改性，其中包括具有至少一个羧基的硝酮和不含羧基的硝酮。
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34.发明授权Polymers functionalized with nitrile compounds containing a protected amino group 有权用含有保护氨基的腈化合物官能化的聚合物公开(公告)号：US09469710B2
公开(公告)日：2016-10-18
申请号：US14607173
申请日：2015-01-28
发明人： Steven Luo , Eiju Suzuki , Dennis R. Brumbaugh
CPC分类号： C08F212/08 , B60C1/00 , C08C19/22 , C08C19/25 , C08C19/44 , C08F8/30 , C08F8/42 , C08F2810/40 , C08K3/04 , C08L15/00
摘要： A method for preparing a functionalized polymer, the method comprising the steps of: (i) polymerizing monomer with an anionic initiator to form a reactive polymer; and (ii) reacting the reactive polymer with a nitrile compound containing a protected amino group, where the protected amino group is directly attached to a moiety selected from the group consisting of acyclic moieties, heterocyclic moieties, and non-aromatic cyclic moieties.
摘要翻译： 一种制备官能化聚合物的方法，所述方法包括以下步骤：（i）用阴离子引发剂聚合单体以形成反应性聚合物; 和（ii）使反应性聚合物与含有保护的氨基的腈化合物反应，其中保护的氨基直接连接到选自无环部分，杂环部分和非芳族环状部分的部分。
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35.发明申请公开(公告)号：US20160237219A1
公开(公告)日：2016-08-18
申请号：US15024136
申请日：2014-09-24
CPC分类号： C08G81/025 , B60C1/00 , B60C1/0016 , C08C19/22 , C08C19/25 , C08F297/044 , C08G65/336 , C08K3/36 , C08L53/005 , C08L53/02 , C08L71/02
摘要： The invention relates to a triblock diene elastomer, the central block of which is a polyether block having a number-average molecular weight ranging from 150 to 5000 g/mol and is connected via a silicon atom to each of the lateral blocks, and the chain ends of which are functionalized to at least 70 mol %, with respect to the number of moles of chain end, by an amine function.
摘要翻译： 本发明涉及一种三嵌段二烯弹性体，其中心嵌段是数均分子量为150-5000g / mol的聚醚嵌段，并通过硅原子连接到每个横向嵌段，链段 通过胺官能团，其末端相对于链端的摩尔数官能化为至少70mol％。
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公开(公告)号：US20160231305A1
公开(公告)日：2016-08-11
申请号：US15028550
申请日：2014-10-09
CPC分类号： G01N33/442 , C08C19/20 , C08C19/22 , C08C19/25 , C08L9/00 , G01N11/162
摘要： The invention relates to a process for determining the degree of branching of modified polymers wherein the polymers are modified in the sense that their degree of branching after polymerization was increased once more, wherein the modified polymers are treated with a polar transformation mixture comprising a compound of general formula (I) R1—S—S—R1 (I) wherein the Mooney viscosity (ML 1+4 at 100° C.) of the polymers is determined before and after the treatment with the polar transformation mixture and the degree of branching is determined.
摘要翻译： 本发明涉及一种确定改性聚合物支化度的方法，其中聚合物在聚合后的支化度再次增加的意义上被修饰，其中改性聚合物用极性转化混合物处理，所述极性转化混合物包含 在极性转化混合物处理之前和之后测定聚合物的门尼粘度（ML 1 + 4，100℃时）的通式（I）R1-S-S-R1（I） 决心，决意，决定。
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公开(公告)号：US09394380B2
公开(公告)日：2016-07-19
申请号：US13809840
申请日：2011-07-12
IPC分类号： C08F8/30 , C08C19/22 , C08C19/28 , C07D233/34 , C07D233/36 , C08F36/04
CPC分类号： C08C19/22 , C07D233/34 , C07D233/36 , C08C19/28 , C08F8/30 , C08F36/04
摘要： The present invention relates to a modified polymer obtained by grafting of a compound comprising at least one group Q and at least one group A, bonded together by at least, and preferably, one “spacer” group Sp in which: Q comprises a dipole containing at least, and preferably, one nitrogen atom, capable of being grafted onto the polymer chain by [1,3]-dipolar cycloaddition, A comprises an associative group comprising at least one nitrogen atom, Sp is an atom or a group of atoms forming a bond between Q and A.
摘要翻译： 本发明涉及通过接枝包含至少一个Q基团和至少一个基团A的化合物而获得的改性聚合物，其中至少一个，优选地由一个“间隔基”基团Sp结合在一起，其中：Q包括含有 至少，优选一个能够通过[1,3] - 双极环加成接枝到聚合物链上的氮原子，A包括包含至少一个氮原子的缔合基团，Sp是原子或一个原子基团 Q和A之间的纽带。
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38.发明申请MODIFIED CONJUGATED DIENE-BASED POLYMER, METHOD FOR PREPARING SAME, AND RUBBER COMPOSITION COMRISING SAME 有权改性的联合二烯基聚合物，其制备方法和与其组合的橡胶组合物公开(公告)号：US20160177011A1
公开(公告)日：2016-06-23
申请号：US14909915
申请日：2014-09-25
申请人： LG CHEM, LTD.
发明人： Jin-Young Kim , No-Ma Kim , Ro-Mi Lee , He-Seung Lee
IPC分类号： C08F236/10 , C07F7/18 , C08K3/36
CPC分类号： C08F236/10 , B60C1/0016 , C07F7/1804 , C08C19/22 , C08C19/25 , C08C19/44 , C08K3/013 , C08K3/36 , C08L15/00
摘要： Disclosed are a modified conjugated diene-based polymer represented by Chemical Formula 1, a method of preparing the same, and a rubber composition including the same.
摘要翻译： 公开了由化学式1表示的改性共轭二烯系聚合物及其制备方法，以及含有该共轭二烯系聚合物的橡胶组合物。
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公开(公告)号：US20160152805A1
公开(公告)日：2016-06-02
申请号：US15013702
申请日：2016-02-02
申请人： Chad Aaron Jasiunas , Frank P. Papp , Charles T. Rosenmayer , Adel Farhan Halasa , Glenn Denstaedt
发明人： Chad Aaron Jasiunas , Frank P. Papp , Charles T. Rosenmayer , Adel Farhan Halasa , Glenn Denstaedt
CPC分类号： C08L9/06 , B60C1/00 , B60C1/0016 , B60C9/02 , B60C11/0008 , B60C13/00 , B60C15/00 , C08C19/08 , C08C19/22 , C08J11/28 , C08J2319/00 , C08J2321/00 , C08K3/04 , C08K5/09 , C08K5/31 , C08K5/40 , C08K5/43 , C08K5/435 , C08K2003/2296 , C08L9/00 , C08L17/00 , C08L19/003 , C08L91/00 , C08L2201/08 , C08L2205/02 , C08L2205/03 , C08L2205/06 , C08L2207/24
摘要： This invention relates to certain rubber formulations which exhibit a low level of hysteresis which are comprised of a chemically functionalized renewed rubber and virgin solution styrene-butadiene rubber. These rubber formulations are loaded with a reinforcing silica. The rubber formulations of this invention can be utilized in making rubber products such as, tires, tracks, and conveyor belts which will promote energy savings by virtue of their low hysteretic properties. The present invention more specifically discloses a rubber composition which is comprised of (1) a solution styrene-butadiene rubber; (2) a functionalized renewed rubber composition which is comprised of an elastomeric polymer and a stabilizer; wherein the rubber composition has a crosslink density which is within the range of 0.05 to 2.0×10−5 mole/g, and wherein the rubber composition has a solubility fraction of less than 90 percent; and (3) a reinforcing filler including reinforcing silica.
摘要翻译： 本发明涉及由化学官能化的更新橡胶和原始溶液苯乙烯 - 丁二烯橡胶组成的具有低水平滞后的某些橡胶制剂。 这些橡胶制剂装有增强二氧化硅。 本发明的橡胶制剂可以用于制造橡胶制品，例如轮胎，轨道和传送带，这将通过其低滞后性能来促进节能。 本发明更具体地公开了一种橡胶组合物，其包含（1）丁苯橡胶溶液; （2）由弹性聚合物和稳定剂组成的功能化的更新橡胶组合物; 其中所述橡胶组合物的交联密度在0.05-2.0×10-5摩尔/ g的范围内，并且其中所述橡胶组合物的溶解度分数小于90％; 和（3）包含增强二氧化硅的增强填料。
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公开(公告)号：US20160152756A1
公开(公告)日：2016-06-02
申请号：US15014620
申请日：2016-02-03
IPC分类号： C08F236/10
CPC分类号： C08C19/25 , B60C1/00 , C08C19/22 , C08C19/44 , C08F4/48 , C08F8/42 , C08F36/04 , C08F36/06 , C08F236/10 , C08L15/00 , C08L19/006 , Y02T10/862
摘要： Disclosed herein are metallated aminosilane compounds for use as functional initiators in anionic polymerizations and processes for producing an aminosilane-functionalized polymer using the metallated aminosilane compounds to initiate anionic polymerization of at least one type of anionically polymerizable monomer. Preferred use of the metallated aminosilane compounds results in rubber compositions for use in tires comprising an aminosilane functionalized polymer. A telechelic polymer may result from use of the metallated aminosilane compound and a functional terminator.
摘要翻译： 本文公开了用作阴离子聚合中的官能引发剂的金属化氨基硅烷化合物和使用金属化氨基硅烷化合物制备氨基硅烷官能化聚合物以引发至少一种类型的阴离子聚合性单体的阴离子聚合的方法。 优选使用金属化的氨基硅烷化合物产生用于包含氨基硅烷官能化聚合物的轮胎的橡胶组合物。 使用金属化氨基硅烷化合物和功能性终止剂可产生遥爪聚合物。
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