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    Composite material having sliding property
    31.
    发明授权
    Composite material having sliding property 失效
    具有滑动性的复合材料

    公开(公告)号：US06677044B2

    公开(公告)日：2004-01-13

    申请号：US09423895

    申请日：1999-11-16

    申请人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Hisato Sanemasa ,  Tetsuo Shimizu

    发明人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Noritoshi Oka ,  Hisato Sanemasa ,  Tetsuo Shimizu

    IPC分类号： B32B1508

    CPC分类号： C08F214/184 ,  C09D127/12 ,  C09D127/18 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31547 ,  Y10T428/31678

    摘要： A composite material having sliding property is produced by applying, to a substrate, a material comprising a fluorine-containing ethylenic polymer having functional group which is prepared by copolymerizing (a) 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having at least one functional group selected from the group consisting of hydroxyl, carboxyl, a carboxylic salt group, a carboxylic ester group and epoxy, and (b) 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers having no functional group mentioned above. The composite material having sliding property which is produced by applying, to the substrate, the material comprising the fluorine-containing polymer having an excellent adhesive property to the substrate without necessitating complicated steps.

    摘要翻译： 通过向基材施加含有具有官能团的含氟乙烯性聚合物的材料，制造具有滑动性的复合材料，该材料通过（a）将0.05〜30摩尔％的含氟乙烯性聚合物 具有选自羟基，羧基，羧酸盐基，羧酸酯基和环氧基中的至少一种官能团的单体，和（b）70〜99.95摩尔％的至少一种含氟乙烯性单体， 没有上述功能组。 具有滑动性的复合材料，其通过向基材施加包含具有优异的粘附性的含氟聚合物的材料而不需要复杂的步骤而制备。

    Fluorine-containing adhesive and adhesive film and laminated article made by using same
    32.
    发明授权
    Fluorine-containing adhesive and adhesive film and laminated article made by using same 有权
    含氟粘合剂和粘合剂膜和使用它们制成的层压制品

    公开(公告)号：US06599997B2

    公开(公告)日：2003-07-29

    申请号：US10189415

    申请日：2002-07-08

    申请人： Takayuki Araki ,  Shigehito Sagisaka ,  Yoshito Tanaka ,  Masahiro Kumegawa

    发明人： Takayuki Araki ,  Shigehito Sagisaka ,  Yoshito Tanaka ,  Masahiro Kumegawa

    IPC分类号： C08F21418

    CPC分类号： B32B1/08 ,  B32B7/12 ,  B32B15/043 ,  C09J127/16 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31649 ,  Y10T428/31699 ,  Y10T428/31743 ,  Y10T428/3175 ,  Y10T428/31855 ,  Y10T428/31909

    摘要： A fluorine-containing adhesive comprising a fluorine-containing ethylenic polymer (A) having functional group which has a crystalline melting point or glass transition temperature of not more than 270° C. and is prepared by copolymerizing (a) 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having at least one functional group selected from the group consisting of carboxyl and a carboxylic salt group and (b) 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers which do not have the above-mentioned functional group and is copolymerizable with the component (a). To provide the fluorine-containing adhesive maintaining chemical resistance, solvent resistance, weather resistance and stain-proofing property and giving direct strong adhesion particularly to a substrate of metal, glass, resin, etc. and an adhesive film and laminated article which are produced from the fluorine-containing adhesive.

    摘要翻译： 含有具有官能团的含氟乙烯性聚合物（A）的含氟粘合剂，其具有结晶熔点或玻璃化转变温度不高于270℃，并且通过（a）0.05〜30摩尔％ 的至少一种具有至少一个选自羧基和羧酸盐基团的官能团的含氟乙烯性单体和（b）70〜99.95摩尔％的至少一种含氟乙烯性单体，其中， 不具有上述官能团并且可与组分（a）共聚。 提供维持耐化学性，耐溶剂性，耐候性和防污性的含氟粘合剂，特别是对金属，玻璃，树脂等的基材和粘合剂膜和层压制品的直接强粘合性，其由 含氟粘合剂。

    Heat-resistant material and coating material for OA equipments having flexibility
    33.
    发明授权
    Heat-resistant material and coating material for OA equipments having flexibility 失效
    具有柔性的OA设备的耐热材料和涂料

    公开(公告)号：US06476151B1

    公开(公告)日：2002-11-05

    申请号：US09582417

    申请日：2000-08-11

    申请人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Norihito Otsuki ,  Masami Kato ,  Tetsuo Shimizu

    发明人： Takayuki Araki ,  Yoshito Tanaka ,  Masahiro Kumegawa ,  Norihito Otsuki ,  Masami Kato ,  Tetsuo Shimizu

    IPC分类号： C08F25900

    CPC分类号： C08F214/262 ,  C08F293/00 ,  C08L53/00 ,  C09D153/00 ,  G03G15/2057 ,  Y10T428/1352

    摘要： It is possible to provide the heat resistant material and coating material for OA equipments which comprise a fluorine-containing multi-segment polymer having heat resistance, abrasion resistance, non-sticking property against toner and oil resistance in addition to flexibility and are used particularly on surfaces of fuser roll and belt. Those materials comprise a fluorine-containing multi-segment polymer having an elastomeric fluorine-containing polymer chain segment A and a non-elastomeric fluorine-containing polymer chain segment B, and the elastomeric fluorine-containing polymer chain segment A comprises not less than 90% by mole of perhaloolefin unit as a recurring unit and imparts flexibility to the whole polymer.

    摘要翻译： 可以提供包含具有耐热性，耐磨性，对调色剂的不粘附性和耐油性的含氟多段聚合物的OA设备的耐热材料和涂料以及柔软性，并且特别地用于 定影辊和皮带的表面。 这些材料包括具有弹性体含氟聚合物链段A和非弹性含氟聚合物链段B的含氟多段聚合物，弹性体含氟聚合物链段A包含不少于90％ 的全卤代烯烃单元作为重复单元，并赋予整个聚合物柔性。

    METHOD OF FORMING THIN FILM
    35.
    发明申请
    METHOD OF FORMING THIN FILM 有权
    形成薄膜的方法

    公开(公告)号：US20100093962A1

    公开(公告)日：2010-04-15

    申请号：US12641183

    申请日：2009-12-17

    申请人： Takayuki Araki ,  Tetsuhiro Kodani

    发明人： Takayuki Araki ,  Tetsuhiro Kodani

    IPC分类号： C08F214/22

    CPC分类号： C08F114/22 ,  C07C21/18 ,  Y10T428/3154 ,  Y10T428/31544

    摘要： There is provided a method of forming a thin film of vinylidene fluoride homopolymer having crystal form I which is applicable to various substrates in relatively easy way (coating conditions, application method, etc.), a process for preparing a vinylidene fluoride homopolymer having crystal form I efficiently at high purity, and novel vinylidene fluoride homopolymers which can give a thin film being excellent in ferroelectricity. The method of forming a thin film of vinylidene fluoride homopolymer comprises (i) a step for preparing a green powder product of vinylidene fluoride homopolymer comprising crystal form I alone or as main component by subjecting vinylidene fluoride to radical polymerization in the presence of a bromine compound or iodine compound having 1 to 20 carbon atoms which contains at least one moiety represented by —CRf1Rf2X1, wherein X1 is iodine atom or bromine atom; Rf1 and Rf2 are the same or different and each is selected from fluorine atom or perfluoroalkyl groups having 1 to 5 carbon atoms and (ii) a step for forming a thin film on a substrate surface by using vinylidene fluoride homopolymer which comprises crystal form I alone or as main component and is obtained from the green powder product of vinylidene fluoride homopolymer comprising crystal form I alone or as main component.

    摘要翻译： 提供一种以相对容易的方式（涂布条件，涂布方法等）形成可以适用于各种基材的结晶形式I的偏二氟乙烯均聚物的薄膜的方法，制备具有结晶形式的偏二氟乙烯均聚物 我高效率地得到高纯度的新型偏二氟乙烯均聚物，可以得到铁电性优异的薄膜。 形成偏氟乙烯均聚物薄膜的方法包括（i）通过在溴化合物的存在下使偏二氟乙烯进行自由基聚合，制备单晶或单体晶形的偏二氟乙烯均聚物的生粉产物的步骤 或含有至少一个由-CR f 1 R f 2 X 1表示的部分的碳原子数为1〜20的碘化合物，其中X1为碘原子或溴原子; Rf1和Rf2相同或不同，分别选自具有1〜5个碳原子的氟原子或全氟烷基，（ii）通过使用仅含有晶型I的偏二氟乙烯均聚物在基板表面上形成薄膜的步骤 或作为主要成分，并且由包含单晶晶体I或主要成分的偏二氟乙烯均聚物的绿色粉末产品获得。

    Solid electrolyte comprising fluorine-containing polymer having fluorine-containing ether chains
    36.
    发明授权
    Solid electrolyte comprising fluorine-containing polymer having fluorine-containing ether chains 有权
    含有含氟醚链的含氟聚合物的固体电解质

    公开(公告)号：US07682753B2

    公开(公告)日：2010-03-23

    申请号：US11096056

    申请日：2005-04-01

    申请人： Meiten Koh ,  Takayuki Araki

    发明人： Meiten Koh ,  Takayuki Araki

    IPC分类号： H01M10/40

    CPC分类号： G02F1/1508 ,  H01B1/122 ,  H01G9/025 ,  H01G9/028 ,  H01G9/038 ,  H01G11/56 ,  H01M8/0289 ,  H01M8/1025 ,  H01M8/1039 ,  H01M8/1044 ,  H01M8/1048 ,  H01M8/1072 ,  Y02E60/13 ,  Y02P70/56

    摘要： There is provided a fluorine-containing polymer solid electrolyte which has an excellent ion-conducting property, is high in oxidation resistance, is stable electrochemically and thermally, has sufficient strength and is applicable to various electrochemical devices. The electrolyte comprises (A) a non-crystalline fluorine-containing polymer having, in a trunk chain and/or side chain of the polymer molecule, a structural unit D having five or more chained units derived from a fluorine-containing ether, (B) an electrolytic compound and (C) a solvent, and has an ionic conductivity of from 10−10 to 101 S/cm measured at 25° C. by an alternating current complex impedance method. The electrolyte is useful for various electrochemical devices.

    摘要翻译： 提供了具有优异的离子传导性，耐氧化性高，电化学和热稳定性好的含氟聚合物固体电解质，具有足够的强度并适用于各种电化学装置。 电解质包含（A）在聚合物分子的主链和/或侧链中具有5个以上来自含氟醚的链状单元的结构单元D（B）的非结晶性含氟聚合物 ）电解化合物和（C）溶剂，并且通过交流复阻抗法在25℃下测得的离子电导率为10-10至101S / cm。 电解质可用于各种电化学装置。

    Functional material comprising fluorine-containing compound
    38.
    发明申请
    Functional material comprising fluorine-containing compound 审中-公开

    公开(公告)号：US20070179263A1

    公开(公告)日：2007-08-02

    申请号：US10591860

    申请日：2005-03-03

    申请人： Meiten Koh ,  Mamoru Miyata ,  Takayuki Araki

    发明人： Meiten Koh ,  Mamoru Miyata ,  Takayuki Araki

    IPC分类号： C08F214/18 ,  C07C215/28

    CPC分类号： H01M14/005 ,  C07C235/16 ,  C07D239/42 ,  C07D249/14 ,  C07D251/18 ,  C07D251/22 ,  C07D251/24 ,  C08F214/18 ,  C08F216/1408 ,  C10N2220/04

    摘要： There is provided an ionic liquid type functional material which is useful for a lubricant, acid-removing agent, various ionic liquid materials, electrolyte for solar cell and actuator material. The ionic liquid type functional material contains an aromatic compound which has a fluorine-containing ether chain and is represented by the formula (1): [Ra-DmRy  (1)wherein -D- is a fluoroether unit represented by the formula (1-1): O—Rn or R—On  (1-1) in which R is at least one selected from divalent fluorine-containing alkylene groups having 1 to 5 carbon atoms in which at least one of hydrogen atoms is replaced by fluorine atom; n is an integer of from 1 to 20; when m is not less than 2, two or more of D may be the same or different; Ra is a monovalent organic group which has 1 to 20 carbon atoms and does not contain D; when m is not less than 2, two or more of Ra may be the same or different; m is an integer of from 1 to 4; Ry is a mono-, di-, tri- or tetra-valent organic group having 2 to 30 carbon atoms which has at least one selected from a basic functional group Y1 and/or a salt Y2 of the basic functional group and contains an aromatic ring structure, provided that a unit of —O—O— is not contained in the formulae (1) and (1-1).

    Process for preparing fluorine-containing norbornene derivative
    39.
    发明申请
    Process for preparing fluorine-containing norbornene derivative 失效
    含氟降冰片烯衍生物的制备方法

    公开(公告)号：US20070129576A1

    公开(公告)日：2007-06-07

    申请号：US11649265

    申请日：2007-01-04

    申请人： Takayuki Araki ,  Takuji Ishikawa ,  Takuji Kume ,  Akinori Yamamoto

    发明人： Takayuki Araki ,  Takuji Ishikawa ,  Takuji Kume ,  Akinori Yamamoto

    IPC分类号： C07C45/45

    CPC分类号： G03F7/0395 ,  C07C33/44 ,  C07C43/313 ,  C07C45/45 ,  C07C49/567 ,  C07C61/28 ,  C07C69/96 ,  C07C2602/42 ,  C07C2603/86 ,  G03F7/0046 ,  G03F7/0382

    摘要： There are provided a novel norbornene derivative which is a material for a chemically amplifying type photoresist for F2 laser, possesses excellent transparency and improved dry etching resistivity and has a fluorine-containing ketone unit or fluorine-containing tertiary alcohol unit directly bonded to the norbornene backbone; a fluorine-containing polymer obtained by using the norbornene derivative as a copolymerizable monomer; and a chemically amplifying type photoresist composition comprising the fluorine-containing polymer, a photoacid generator and a solvent.

    摘要翻译： 提供了一种新颖的降冰片烯衍生物，其是用于F 2激光的化学放大型光致抗蚀剂的材料，具有优异的透明度和改善的干蚀刻电阻率，并且具有含氟酮单元或含氟三级 直接与降冰片烯骨架结合的醇单元; 通过使用降冰片烯衍生物作为可共聚单体得到的含氟聚合物; 以及包含含氟聚合物，光致酸产生剂和溶剂的化学放大型光致抗蚀剂组合物。

    Process for preparing fluorine-containing polymer and method of forming fine pattern using same
    40.
    发明授权
    Process for preparing fluorine-containing polymer and method of forming fine pattern using same 失效
    制备含氟聚合物的方法和使用其形成精细图案的方法

    公开(公告)号：US07163982B2

    公开(公告)日：2007-01-16

    申请号：US10914203

    申请日：2004-08-10

    申请人： Takayuki Araki ,  Tetsuhiro Kodani ,  Takuji Ishikawa

    发明人： Takayuki Araki ,  Tetsuhiro Kodani ,  Takuji Ishikawa

    IPC分类号： C08F8/32

    CPC分类号： C08F12/20 ,  G03F7/0046 ,  G03F7/0395

    摘要： There is provided a method of forming a fine pattern by using a practicable fluorine-containing polymer which has a high transparency to exposure light having a short wavelength such as F2 laser and can undergo resolution of a fine pattern. The method comprises (I) a step for preparing a fluorine-containing polymer (A) having OH group which has a structural unit derived from a fluorine-containing norbornene derivative having OH group, (II) a step for preparing a fluorine-containing polymer (B) having a protective group by reacting a compound represented by X—CH2OR, wherein X is Cl, Br or I; R is a hydrocarbon group having 1 to 30 carbon atoms in which a part or the whole of hydrogen atoms may be substituted with fluorine atoms, with the above-mentioned fluorine-containing polymer (A) having OH group in the presence of a base, (III) a step for preparing a resist composition comprising (a) the above-mentioned fluorine-containing polymer (B) having a protective group, (b) a photoacid generator and (c) a solvent, (IV) a step for forming a resist film comprising the above-mentioned resist composition on a substrate or on a given layer on the substrate, (V) a step for exposing by selectively irradiating a given area of the resist film with energy rays, and (VI) a step for subjecting the exposed resist film to developing to selectively remove the exposed portion of the resist film, thus forming a fine pattern.

    摘要翻译： 提供了通过使用对具有短波长的曝光光如F 2激光具有高透明度的可行的含氟聚合物来形成精细图案的方法，并且可以经历精细图案的分辨 。 该方法包括：（I）具有OH基的含氟聚合物（A）的制备步骤，其具有衍生自具有OH基的含氟降冰片烯衍生物的结构单元，（II）制备含氟聚合物的步骤 （B）通过使由X-CH 2 OR表示的化合物与其中X为Cl，Br或I的化合物反应而具有保护基; R是具有1至30个碳原子的烃基，其中一部分或全部氢原子可以被氟原子取代，上述含碱基的含氟聚合物（A）具有OH基团， （III）制备抗蚀剂组合物的步骤，包括（a）具有保护基的上述含氟聚合物（B），（b）光致酸产生剂和（c）溶剂，（IV）形成步骤 在基板上或基板上的给定层上包含上述抗蚀剂组合物的抗蚀剂膜，（V）通过用能量射线选择性地照射抗蚀剂膜的给定区域来曝光的步骤，以及（VI） 使曝光的抗蚀剂膜显影以选择性地除去抗蚀剂膜的暴露部分，从而形成精细图案。