公开(公告)号：US11649303B2

公开(公告)日：2023-05-16

申请号：US17040322

申请日：2019-03-29

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Paul Tu Quang Nguyen ,  David J. Freas ,  Tu N. Pham ,  Yuan-Ju Chen ,  Edward J. Blok ,  Anthony J. Dias

IPC: C08F8/34 ,  C08F8/32

CPC classification number: C08F8/34 ,  C08F8/32 ,  C08F2810/50 ,  C08F210/10 ,  C08F212/21 ,  C08F212/12

Abstract: Methods of post-polymerization modification of a polymer are provided herein. The present methods comprise the step of reacting a polymer with at least one nucleophile in a nucleophilic substitution reaction performed without a solvent to produce a functionalized polymer. The nucleophile can be selected from the group consisting of thioacetate, phenoxide, alkoxide, carboxylate, thiolate, thiocarboxylate, dithiocarboxylate, thiourea, thiocarbamate, dithiocarbamate, xanthate, thiocyanate. Nucleophilic substitution reaction can be performed in the presence of a phase transfer catalyst. Nucleophilic substitution reaction can also be performed via a two-step in-situ reactive mixing process with the initial formation of the polymer-amine ionomer (polymer-NR3+Br) which catalyzes the subsequent nucleophilic substitution with a second nucleophile to form a bi-functional polymer.

公开(公告)号：US20230034592A1

公开(公告)日：2023-02-02

申请号：US17783032

申请日：2020-12-09

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Paul T.Q. Nguyen ,  Edward J. Blok ,  Anthony J. Dias ,  Ranjan Tripathy ,  Jason A. Mann

IPC: C08L9/00

Abstract: An elastomeric composition is disclosed. The elastomeric composition includes, per 100 parts by weight of rubber (phr): about 60 to about 100 phr of polybutadiene having a cis-1,4 linkage content of at least 95%; about 5 to 40 phr of a styrene/butadiene copolymer; a curative agent; an antioxidant; about 50 to about 80 phr hydrocarbon resin; about 100 to about 140 phr silica; about 1 to about 20 phr silane coupling agent and about 5 to about 30 phr of a polymer selected from the group consisting of ethylene-propylene-diene terpolymer, butyl rubber, poly(isobutylene-co-para-methylstyrene) and poly(isobutylene-co-para-methyl-styrene-co-isoprene) terpolymer. The polymer based on ethylene-propylene-diene terpolymer, butyl rubber, poly(isobutylene-co-para-methylstyrene) and poly(isobutylene-co-para-methylstyrene-co-isoprene) terpolymer may be functionalized.

公开(公告)号：US10988563B2

公开(公告)日：2021-04-27

申请号：US15843698

申请日：2017-12-15

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Edward J. Blok ,  Anthony J. Dias ,  Robert J. Claassen, II ,  Eugene R. Uhl

IPC: C08F279/00 ,  C08F240/00 ,  B60C1/00 ,  C08L101/02 ,  C08L47/00 ,  C08L45/00 ,  C08K3/36 ,  B29D30/06 ,  C08L51/00 ,  C08L101/10 ,  C08L23/22 ,  C08J3/12 ,  C08C19/25 ,  B29B9/06 ,  C08F8/42 ,  B29B7/90 ,  C08J3/24 ,  B29B7/00 ,  C08J3/20 ,  C08F10/14 ,  B29K9/00 ,  C08L23/08

Abstract: An elastomeric composition and method incorporating a hydrocarbon polymer modifier with improved permanence. The composition comprises elastomer, filler and silane-functionalized hydrocarbon polymer modifier (Si-HPM) made in a pre-reaction adapted to couple the Si-HPM to the elastomer, filler or both, wherein the Si-HPM comprises an interpolymer of monomers chosen from piperylenes, cyclic pentadienes, aromatics, limonenes, pinenes, amylenes, and combinations thereof.

公开(公告)号：US20210032389A1

公开(公告)日：2021-02-04

申请号：US17043274

申请日：2019-04-09

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Edward J. Blok ,  Anthony J. Dias ,  Paul T.Q. Nguyen ,  Erick E. Wurzinger

IPC: C08F236/06 ,  C08F236/08 ,  C08F236/10 ,  C08L7/00 ,  C08L25/08 ,  C08L91/00 ,  C08K3/04 ,  C08K3/36 ,  C08K5/00 ,  C08K5/01 ,  C08K5/5419 ,  B60C1/00

Abstract: An elastomeric composition is disclosed. The elastomeric composition includes, per 100 parts by weight of rubber (phr): about 30 to about 50 phr of polybutadiene having a cis-1,4 linkage content of at least 95%; about 40 to about 70 phr of styrene/butadiene copolymer; about 0 to about 20 phr of natural rubber or polyisoprene; about 0 to about 30 phr of a processing oil; about 10 to about 30 phr of a hydrocarbon resin; about 50 to about 75 phr of a filler; a curative agent; an antioxidant; a silane coupling agent; and about 5 to about 30 phr of a butyl copolymer rubber containing about 85 to about 99.5 mol % C4-C7 isoolefin(s) and from about 0.5 to about 15 mol % C4-C14 conjugated dienes.

公开(公告)号：US20210024734A1

公开(公告)日：2021-01-28

申请号：US17040845

申请日：2019-03-29

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Paul Tu Quang Nguyen ,  Ranjan Tripathy ,  Jason A. Mann ,  Yuan-Ju Chen ,  Edward J. Blok ,  Anthony J. Dias ,  Abdul M. Jangda

IPC: C08L23/22 ,  C08K5/44 ,  C08K5/435 ,  C08K5/40 ,  C08K5/31 ,  C08K5/00 ,  C08K3/06 ,  C08F8/44 ,  C08F8/40 ,  C08F8/32

Abstract: Provided herein are isobutylene-based polymer compositions comprising functionalized isobutylene-based polymer with olefinic side chain substituents, and a sulfur donor and/or accelerator cure system. The functionalized polymer is produced via nucleophilic substitution reaction in solution. The present functionalized isobutylene-based polymer compositions together with various accelerators and sulfur donors can form thermosets useful for pharmaceutical and tire applications without the use of zinc or a zinc oxide activator.

公开(公告)号：US20210024668A1

公开(公告)日：2021-01-28

申请号：US17043235

申请日：2019-04-09

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Edward J. Blok ,  Anthony J. Dias ,  Gabor Kiss ,  Paul T.Q Nguyen

IPC: C08F210/06 ,  C08K3/04 ,  C08K3/22 ,  C08K3/06 ,  C08K5/09 ,  C08K5/17 ,  C08L9/06 ,  B60C1/00

Abstract: An elastomeric composition is disclosed. The elastomeric composition includes, per 100 parts by weight of rubber (phr): about 0 to about 25 phr of poly butadiene having a cis-1,4 linkage content of at least 95%; about 75 to 100 phr of a styrene/butadiene copolymer; about 10 to about 30 phr of a processing oil; about 50 to about 70 phr of a filler; a curative agent; an antioxidant; a silane coupling agent; and about 5 to about 30 phr of a propylene-ethylene-diene terpolymer.

公开(公告)号：US20180105631A1

公开(公告)日：2018-04-19

申请号：US15843698

申请日：2017-12-15

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Edward J. Blok ,  Anthony J. Dias ,  Robert J. Claassen, II ,  Eugene R. Uhl

IPC: C08F279/00 ,  C08L101/10 ,  B29B9/06 ,  B29D30/06 ,  B60C1/00 ,  C08L101/02 ,  C08L51/00 ,  C08L47/00 ,  C08L45/00 ,  C08L23/22 ,  C08K3/36 ,  C08J3/12 ,  C08F240/00 ,  C08F8/42 ,  C08C19/25 ,  B29K9/00 ,  C08F10/14

CPC classification number: C08F279/00 ,  B29B7/005 ,  B29B7/90 ,  B29B9/065 ,  B29D30/06 ,  B29K2009/00 ,  B60C1/00 ,  B60C1/0008 ,  B60C1/0016 ,  B60C1/0041 ,  C08C19/25 ,  C08F8/42 ,  C08F10/14 ,  C08F240/00 ,  C08J3/12 ,  C08J3/201 ,  C08J3/246 ,  C08J2321/00 ,  C08J2325/10 ,  C08J2351/00 ,  C08J2400/108 ,  C08J2425/18 ,  C08J2455/00 ,  C08K3/36 ,  C08L23/0892 ,  C08L23/22 ,  C08L45/00 ,  C08L47/00 ,  C08L51/003 ,  C08L101/02 ,  C08L101/10 ,  Y02T10/862 ,  Y10T156/10

Abstract: An elastomeric composition and method incorporating a hydrocarbon polymer modifier with improved permanence. The composition comprises elastomer, filler and silane-functionalized hydrocarbon polymer modifier (Si-HPM) made in a pre-reaction adapted to couple the Si-HPM to the elastomer, filler or both, wherein the Si-HPM comprises an interpolymer of monomers chosen from piperylenes, cyclic pentadienes, aromatics, limonenes, pinenes, amylenes, and combinations thereof.

公开(公告)号：US09909004B2

公开(公告)日：2018-03-06

申请号：US14390808

申请日：2013-02-19

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Edward J. Blok ,  Anthony J. Dias ,  Martin E. Levine

IPC: C08L23/00 ,  C08L65/00 ,  B60C1/00 ,  C08F240/00 ,  C08K5/01 ,  C08L9/00 ,  C08L9/06 ,  C08L21/00 ,  C08L23/16 ,  C08L23/22 ,  C08L23/28 ,  C08L101/00

CPC classification number: C08L65/00 ,  B60C1/0016 ,  B60C1/0025 ,  C08F240/00 ,  C08K5/01 ,  C08L9/00 ,  C08L9/06 ,  C08L21/00 ,  C08L23/16 ,  C08L23/22 ,  C08L23/283 ,  C08L101/00 ,  C08L57/02

Abstract: A composition including at least one elastomer, and a hydrocarbon polymer additive having a dicyclopentadiene, cyclopentadiene, and methylcyclopentadiene derived content of about 40 wt % to about 80 wt % of the total weight of the hydrocarbon polymer additive, a weight average molecular weight of about 100 g/mole to about 800 g/mole, and a softening point of about 110° C. to about 150° C. as determined in accordance with ASTM D6090.

公开(公告)号：US20170292013A1

公开(公告)日：2017-10-12

申请号：US15507400

申请日：2015-08-31

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Edward J. Blok ,  Anthony J. Dias ,  Sunny Jacob ,  lan C. Stewart ,  Yong Yang ,  Jingwen Zhang

IPC: C08L9/06

CPC classification number: C08L9/06 ,  B60C1/0016 ,  C08L7/00 ,  C08L9/00 ,  C08L2205/06 ,  C08L2312/00 ,  C08L23/16

Abstract: A tire tread composition is disclosed. The tire tread composition includes components, by weight of the composition, within the range from: 5 to 75 wt % of a diene elastomer; 0 to 40 wt % of processing oil; 20 to 80 wt % of filler; a curative agent; and 5 to 30 wt % of a propylene-ethylene-diene terpolymer containing from 2 wt % to 40 wt % of ethylene and/or C4-C20 α-olefins derived units, from 0.5 to 10 wt % of diene derived units, and having a heat of fusion, as determined by DSC, of from 0 J/g to 80 J/g.

公开(公告)号：US20160289352A1

公开(公告)日：2016-10-06

申请号：US15035059

申请日：2014-08-11

Applicant: ExxonMobil Chemical Patents Inc.

Inventor： Edward J. Blok ,  Ian C. Stewart ,  Anthony J. Dias ,  Yuan-Ju Chen

IPC: C08F132/08 ,  C08L9/06

CPC classification number: C08F132/08 ,  B60C1/0016 ,  C08K5/5425 ,  C08L9/00 ,  C08L9/06

Abstract: This invention relates to a dicyclopentadiene (DCPD)-based resin functionalized with groups capable of reacting with silica or carbon black for use in high performance tires and a preferred method of preparing the functionalized resin comprising ruthenium-catalyzed ring-opening cross metathesis. The functionalized resin may comprise the reaction product obtained by contacting a polymer comprising units derived from (DCPD) and a vinyl monomer or vinylene monomer in the presence of a metathesis catalyst, wherein the vinyl monomer or vinylene monomer comprises at least one of the following functional groups: a silyl group, a siloxy group, or an alkoxysilyl group. This invention further relates to a tire tread composition comprising the functionalized resin and which exhibits enhanced durability, traction, handling, and extractability properties.

Abstract translation: 本发明涉及用能够与高性能轮胎中使用的二氧化硅或炭黑反应的基团官能化的二环戊二烯（DCPD）系树脂，以及制备包含钌催化的开环交叉复分解的官能化树脂的优选方法。 官能化树脂可以包含通过在复分解催化剂存在下使包含衍生自（DCPD）的单体和乙烯基单体或亚乙烯基单体的聚合物接触而获得的反应产物，其中乙烯基单体或亚乙烯基单体包含以下功能性的至少一种 基团：甲硅烷基，甲硅烷氧基或烷氧基甲硅烷基。 本发明还涉及包含官能化树脂并且具有增强的耐久性，牵引力，处理性和可萃取性能的轮胎胎面组合物。