公开(公告)号：US20060153763A1

公开(公告)日：2006-07-13

申请号：US10524435

申请日：2003-08-14

申请人： Henri Cramail ,  Alain Deffieux ,  Cedric Dever ,  Sergio Mastroianni

发明人： Henri Cramail ,  Alain Deffieux ,  Cedric Dever ,  Sergio Mastroianni

IPC分类号： C01B33/00

CPC分类号： C07F17/00 ,  C01B33/12 ,  C01B33/16 ,  C01G1/00 ,  C01G25/00 ,  C07B2200/11 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65927 ,  C08F110/02 ,  C08F4/65916 ,  C08F2500/03

摘要： A process for the preparation of a silicon containing transition metal compound comprises the steps of (a) non-hydrolytic sol-gel condensation of a silane of formula LxSiQn wherein L is a π-bonded ligand, Q is an anionic ligand, and x+n=4 with a halogenated silane (or siloxane) and an alkoxysilane, (b) optionally alkylation, (c) deprotonation and (d) addition of a transition metal compound. The novel process allows for the preparation of transition metal compounds which may suitably be used with cocatalysts for the polymerisation of olefins, in particular for such processes carried out in the gas phase.

摘要翻译： 一种制备含硅过渡金属化合物的方法包括以下步骤：（a）式L 1 x SiQ n的硅烷的非水解溶胶 - 凝胶缩合，其中L是π键合的配体， Q是阴离子配体，x + n = 4，卤代硅烷（或硅氧烷）和烷氧基硅烷，（b）任选烷基化，（c）去质子化和（d）加入过渡金属化合物。 该新方法允许制备适合与助催化剂一起使用的烯烃聚合的过渡金属化合物，特别是用于在气相中进行的这些方法。

公开(公告)号：US07067598B2

公开(公告)日：2006-06-27

申请号：US10432032

申请日：2001-11-16

申请人： Jean-Jacques Kuhlburger ,  Kenneth John Rowley

发明人： Jean-Jacques Kuhlburger ,  Kenneth John Rowley

IPC分类号： C08F4/69 ,  C08F2/34

CPC分类号： C08F10/02 ,  C08F210/16 ,  Y10S526/901 ,  C08F4/24 ,  C08F2/40 ,  C08F210/08 ,  C08F2500/12 ,  C08F2500/14 ,  C08F2500/07

摘要： The present invention relates to a process for the gas-phase (co-)polymerization of olefins in a fluidized bed reactor using a chromium oxide catalyst characterized in that the polymerization is performed in the presence of a polymer structure modifier.

摘要翻译： 本发明涉及使用铬氧化物催化剂的流化床反应器中烯烃的气相（共）聚合方法，其特征在于在聚合物结构改性剂存在下进行聚合。

公开(公告)号：US07022788B2

公开(公告)日：2006-04-04

申请号：US10062673

申请日：2002-02-05

申请人： Duncan Frank Wass

发明人： Duncan Frank Wass

IPC分类号： C08F4/26 ,  C08F4/70

CPC分类号： C07F9/46 ,  C07F15/045 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F2500/03 ,  C08F2500/10 ,  C08F2500/04 ,  C08F210/14 ,  C08F4/7004 ,  C08F4/7016

摘要： A process for the polymerization and copolymerization of olefins is disclosed, comprising contacting the monomeric olefin under polymerization conditions with a polymerization catalyst or catalyst system which comprises (a) a source of a Group VIII metal; (b) a bidentate phosphine ligand having the formula (R1)(R1)P—X—P(R1)(R1), where each R1 is independently selected from a phenyl group or a substitued phenyl group with the proviso that at least one of the R1 groups is a phenyl group having at least one ortho substituent, and X is a bridging group of the structure —[N]x—[P]y—[N]— where x and y are independently 0 or 1, or —C(R4)2— where R4 may be the same or different and is hydrogen or a monovavlent hydrocarbyl, substituted hydrocarbyl or hetero-hydrocarbyl group; and optionally (c) a promoter.

摘要翻译： 公开了一种用于烯烃聚合和共聚的方法，包括在聚合条件下使单体烯烃与聚合催化剂或催化剂体系接触，所述聚合催化剂或催化剂体系包含（a）Ⅷ族金属源; （b）具有下式（R 1）的二齿膦配体（R 1）（PX 1）（R 1）（R 1） 其中每个R 1独立地选自苯基或取代的苯基，条件是至少一个R 1基团是 具有至少一个邻位取代基的苯基，X是结构的桥连基团 - [N] - [N - ] - [P] Y - - - - - [N] - 其中x和 y独立地为0或1，或-C（R 4）2 - ，其中R 4可以相同或不同，为氢或 单不饱和烃基，取代的烃基或杂烃基; 和任选地（c）启动子。

公开(公告)号：US07012121B2

公开(公告)日：2006-03-14

申请号：US10880582

申请日：2004-07-01

申请人： Edmund M Carnahan ,  David R Neithamer ,  Ravi B Shankar

发明人： Edmund M Carnahan ,  David R Neithamer ,  Ravi B Shankar

IPC分类号： C08F4/44 ,  C08F4/06

CPC分类号： C08F10/02 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F210/16 ,  C08F4/6592 ,  C08F4/025 ,  C08F210/14

摘要： Supported catalyst compositions use for use in the gas-phase polymerization of one or more α-olefins and methods for making and using the same, the catalyst composition including A) an inert support; B) a Group 4–10 metal complex corresponding to the formula: where M is a metal from one of Groups 4 to 10 of the Periodic Table of the Elements in the +2 or +4 formal oxidation state, Cp is a π-bonded anionic ligand group, Z is divalent moiety bound to Cp and bound to M by either covalent or coordinate/covalent bonds and contains boron or a member of Group 14 of the Periodic Table of the Elements, and also nitrogen, phosphorus, sulfur or oxygen, and X is a neutral conjugated diene ligand group having up to 60 atoms, or a dianionic derivative thereof; and C) an ionic cocatalyst capable of converting the metal complex into an active polymerization catalyst represented by the formula: [L*-H]+[(C6F5)3BC6H4—O—MORCx-1Xay]−, wherein L* is a neutral Lewis base, Mo is a metal or metalloid selected from Groups 1–14 of the Periodic Table of the Elements, RC independently each occurrence is a hydrogen or a hydrocarbyl, hydrocarbylsilyl, or hydrocarbysilylhydrocarbyl group having from 1 to 80 nonhydrogen atoms; Xa is a halo-substituted hydrocarbyl, hydrocarbylamino-substituted hydrocarbyl, hydrocarbyloxy-substituted hydrocarbyl, hydrocarbylamino, di(hydrocarbyl)amino, hydrocarbyloxy or halide noninterfering group having from 1 to 100 nonhydrogen atoms; x is an integer which ranges from 1 to an integer equal to the valence of MO; y is an integer which ranges from 0 to an integer equal to 1 less than the valence of MO; and x+y equals the valence of MO.

公开(公告)号：US20050065364A1

公开(公告)日：2005-03-24

申请号：US10897769

申请日：2004-07-22

申请人： Alexis Bell ,  Sudip Mukhopadhyay ,  Mark Zerella ,  John Sunley ,  Sander Gaemers ,  Michael Muskett

发明人： Alexis Bell ,  Sudip Mukhopadhyay ,  Mark Zerella ,  John Sunley ,  Sander Gaemers ,  Michael Muskett

IPC分类号： C07C51/56 ,  C07C67/08 ,  C07C309/00 ,  C07C381/00 ,  C07C67/24 ,  C07C51/54

CPC分类号： C07C309/00 ,  C07C51/56 ,  C07C67/08 ,  C07C381/00 ,  C07C53/18 ,  C07C69/14

摘要： Acetyl anhydrides such as acetyl sulfate are produced by a process for comprising contacting methane and carbon dioxide in an anhydrous environment in the presence of effective amounts of a transition metal catalyst and a reaction promoter, and an acid anhydride compound, and optionally an acid. The acetyl anhydride can be contacted with water to produce acetic acid or with an alcohol to produce a product comprising an acetate ester and that may also comprise acetic acid. Optionally, water in stoichiometric amounts or less, with respect to the acetic anhydride, may be fed to a continuous process of this type to produce some acetic acid in situ.

公开(公告)号：US20030125195A1

公开(公告)日：2003-07-03

申请号：US10222811

申请日：2002-08-19

申请人： BP Chemicals Limited

发明人： George Johan Peter Britovsek ,  Birgit Angelika Dorer ,  Vernon Charles Gibson ,  Brian Stephen Kimberley ,  Gregory Adam Solan

IPC分类号： B01J031/00

CPC分类号： C07D213/53 ,  C07F13/005 ,  C07F15/0053 ,  C07F15/025 ,  C07F15/065 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  C08F2410/04 ,  C08F4/61904 ,  C08F2500/04 ,  C08F2500/07 ,  C08F2500/12 ,  C08F210/14 ,  C08F2500/10 ,  C08F2500/26 ,  C08F2500/03 ,  C08F4/60089 ,  C08F4/7042 ,  C08F4/6546

摘要： Catalyst systems useful for the polymerization of 1-olefins are disclosed, which contain nitrogen-containing transition metal compounds comprising the skeletal unit depicted in Formula (B), wherein M is FenullIInull, FenullIIInull, RunullIInull, RunullIIInull or RunullIVnull; X represents an atom or group covalently or ionically bonded to the transition metal M; T is the oxidation state of the transition metal M and b is the valency of the atom or group X; R1, R2, R3, R4 and R6 are independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl; R5 and R7 are independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl.

摘要翻译： 公开了可用于1-烯烃聚合的催化剂体系，其含有含式（B）所示骨架单元的含氮过渡金属化合物，其中M为Fe [II]，Fe [III]，Ru [II]， Ru [III]或Ru [IV]; X表示与过渡金属M共价或离子键合的原子或基团; T是过渡金属M的氧化态，b是原子或基团X的化合价; R 1，R 2，R 3，R 4和R 6独立地选自氢，卤素，烃基，取代的烃基，杂烃基或取代的杂烃基; R5和R7独立地选自氢，卤素，烃基，取代的烃基，杂烃基或取代的杂烃基。

公开(公告)号：US20010056201A1

公开(公告)日：2001-12-27

申请号：US09894792

申请日：2001-06-28

申请人： BP Chemicals Limited

发明人： John William Couves ,  Simon James Kitchen

IPC分类号： C07C067/05 ,  C07C067/02

CPC分类号： B01J23/52 ,  B01J23/44 ,  B01J23/63 ,  B01J23/89 ,  B01J37/16 ,  C07C67/055 ,  C07C69/01 ,  C07C69/15

摘要： A process for the production of vinyl acetate which comprises contacting ethylene, acetic acid and an oxygen-containing gas with a supported palladium catalyst prepared by a process comprising the steps of (a) impregnating a catalyst support with a palladium compound, (b) converting the palladium compound to substantially metallic palladium, and (c) sintering the supported palladium at a temperature of greater than 500null C.

摘要翻译： 一种制备乙酸乙烯酯的方法，其包括使乙烯，乙酸和含氧气体与负载的钯催化剂接触，所述负载的钯催化剂通过包括以下步骤的方法制备，所述方法包括以下步骤：（a）用钯化合物浸渍催化剂载体，（b）转化 钯化合物至基本上金属的钯，和（c）在大于500℃的温度下烧结负载的钯。

公开(公告)号：US20010012818A1

公开(公告)日：2001-08-09

申请号：US09817064

申请日：2001-03-27

申请人： BP Chemicals Limited.

发明人： Simon James Kitchen ,  Daiyi Qin

IPC分类号： B01J031/00

CPC分类号： B01J23/66 ,  B01J23/44 ,  B01J23/52 ,  B01J23/56 ,  B01J23/58 ,  C07C67/055 ,  C07C69/01 ,  C07C69/15

摘要： A catalyst for use in the production of vinyl acetate which comprises (1) a catalyst support, (2) palladium, (3) an acid, (4) at least one acetic acid catalyst promoter and (5) at least one vinyl acetate promoter and/or co-promoter. A process for the production of vinyl acetate from ethylene and an oxygen-containing gas using the catalyst.

摘要翻译： 一种用于生产乙酸乙烯酯的催化剂，其包括（1）催化剂载体，（2）钯，（3）酸，（4）至少一种乙酸催化剂促进剂和（5）至少一种乙酸乙烯酯促进剂 和/或共促进剂。 使用该催化剂从乙烯和含氧气体生产乙酸乙烯酯的方法。

公开(公告)号：US6056927A

公开(公告)日：2000-05-02

申请号：US915565

申请日：1997-08-21

申请人： Jean-Claude Chinh ,  Robert Pes

发明人： Jean-Claude Chinh ,  Robert Pes

IPC分类号： B01J8/00 ,  B01J8/24 ,  C08F2/34 ,  C08F10/00

CPC分类号： B01J8/1872 ,  B01J8/003 ,  C08F10/00 ,  B01J2208/00256 ,  B01J2208/00274

摘要： The invention relates to an equipment for gas-phase polymerization of olefin(s), including a reactor with a fluidized and optionally mechanically stirred bed, and a conduit for withdrawing polymer, provided with an isolation valve, and a conduit for emptying polymer, provided with an isolation valve, the said conduits connecting the side wall of the reactor to a single recovery gas lock equipped with a discharge valve, equipment characterized in that the withdrawal conduit leaves the side wall of the reactor at a height of the reactor wall, above the fluidization grid, ranging from 0.60.times.H to 0.95.times.H, while being directed downwards, with the result that any part of the said conduit forms with a horizontal plane an angle A ranging from 35 to 90.degree., and in that the emptying conduit leaves the side wall of the reactor at a height of the reactor wall, above the fluidization grid, ranging from 0.01.times.H to 0.20.times.H.

摘要翻译： 本发明涉及一种用于烯烃气相聚合的设备，包括具有流化和任选机械搅拌床的反应器和用于提取聚合物的导管，设有隔离阀，以及用于排空聚合物的管道 具有隔离阀，所述管道将反应器的侧壁连接到装备有排放阀的单个回收气体锁，其特征在于，所述排出导管在反应器壁的高度处离开反应器的侧壁，上方 流化栅格范围从0.60xH到0.95xH，同时向下指向，结果是所述导管的任何部分的水平面形成角度A为35至90°，并且排空导管离开 在反应器壁的高度处，在流化网格上方的反应器的侧壁范围为0.01xH至0.20xH。

公开(公告)号：US6025425A

公开(公告)日：2000-02-15

申请号：US766297

申请日：1996-12-13

申请人： Neil Shearer Davidson

发明人： Neil Shearer Davidson

IPC分类号： C08K3/34 ,  C08L73/00 ,  C08J5/10

CPC分类号： C08K3/34

摘要： A polymer composition comprises (a) a major amount of a polyketone and (b) a minor amount of an amorphous silicate. The amorphous silicate preferably a trisilicate can be a silicate of a Group II metal, for example magnesium. The amorphous silicate is used as a stabilizer in polymer compositions comprising polyketones.

摘要翻译： 聚合物组合物包含（a）主要量的聚酮和（b）少量的无定形硅酸盐。 无定形硅酸盐优选三硅酸盐可以是II族金属的硅酸盐，例如镁。 无定形硅酸盐用作包含聚酮的聚合物组合物中的稳定剂。