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21.发明授权Process of producing nonaqueous resin dispersion and liquid developer for electrostatic photography 失效制备非水性树脂分散体和静电摄影用液体显影剂的方法
公开(公告)号：US5409795A
公开(公告)日：1995-04-25
申请号：US158588
申请日：1993-11-29
申请人： Eiichi Kato
发明人： Eiichi Kato
摘要： A process of producing a nonaqueous resin dispersion, particularly useful for a liquid developer in electrostatic photographic, which comprises subjecting to photopolymerization a system containing at least a monomer (A) having one polymerizable double bond, which is soluble in a nonaqueous solvent but becomes insoluble upon polymerization thereof, and at least a dispersion stabilizing resin (P) which is a polymer having a weight average molecular weight of from 1.times.10.sup.4 to 1.times.10.sup.6 and containing a specific repeating unit represented by formula (I) in an amount of at least 50% by weight based on the weight of the polymer and has a specific functional group represented by formula (II) bonded to the side chain of the polymer and/or only one terminal of the main chain of the polymer, the photopolymerization reaction being carried out in the nonaqueous solvent by irradiating the system with ultraviolet rays having a wavelength of not longer than 400 n.m.: ##STR1##
摘要翻译： 一种特别可用于静电照相液体显影剂的非水树脂分散体的方法，其包括使至少含有一个可聚合双键的单体（A）的系统进行光聚合，所述单体（A）可溶于非水溶剂但不溶于 至少一种分散稳定树脂（P），它是重均分子量为1×10 4至1×10 6的聚合物，并且含有式（I）表示的特定重复单元的量至少为50％ 以聚合物的重量为基准，并具有与聚合物的侧链键合的式（II）表示的特定官能团和/或仅聚合物主链的一个末端，光聚合反应在 （II）的紫外线照射系统的非水溶剂。
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公开(公告)号：US5236965A
公开(公告)日：1993-08-17
申请号：US5756
申请日：1993-01-19
CPC分类号： A61L15/425 , A61L15/60 , C08F2/08 , C08F20/04 , Y10S604/904
摘要： The present invention relates to hydrophilic, swellable polymers which consist of radicals of the general formula I ##STR1## wherein R.sup.1 to R.sup.3 are defined as stated in the description, and of radicals of a crosslinking agent which have originated from monomers having at least two olefinically unsaturated double bonds, and which are characterized in that they are in the form of a highly porous, foam-like polyhedral structure, their preparation and their use as absorption agents for water and aqueous solutions.
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23.发明授权Copolymers based on C.sub.1 -C.sub.8 -alkyl acrylates and/or methacrylates and their use in sizing agent compositions 失效基于C1-C8-烷基丙烯酸酯和/或甲基丙烯酸酯的共聚物及其在尺寸试剂组合物中的应用
公开(公告)号：US5231145A
公开(公告)日：1993-07-27
申请号：US679275
申请日：1991-04-02
IPC分类号： C08F2/08 , C08F2/06 , C08F2/24 , C08F2/30 , C08F2/44 , C08F220/10 , C08F220/12 , C08F261/04 , D06M15/263 , D06M15/333
CPC分类号： D06M15/333 , C08F220/12 , C08F261/04 , D06M15/263
摘要： Copolymers suitable for use as temporary surface protection for two- or three-dimensional structures and as sizing agents are based on C.sub.1 -C.sub.8 -alkyl acrylates and/or methacrylates and are obtainable by free radical emulsion or solution polymerization ofA) from 50 to 95% by weight of a C.sub.1 -C.sub.8 -alkyl acrylate or methacrylate,B) from 5 to 20% by weight of an unsaturated carboxylic acid or anhydride,C) from 0 to 20% by weight of further water-soluble comonomer, andD) from 0 to 10% by weight of other comonomer in the presence ofE) from 2 to 60 parts by weight of a polyvinyl alcohol per 100 parts by weight of the monomer mixture of A) to D).
摘要翻译： 适用于二维或三维结构和上胶剂的临时表面保护的共聚物基于丙烯酸C1-C8烷基酯和/或甲基丙烯酸酯，可通过自由基乳液或溶液聚合得到A）50至95 重量％的丙烯酸酯或甲基丙烯酸C 1 -C 8烷基酯，B）5至20重量％的不饱和羧酸或酸酐，C）0-20重量％的其它水溶性共聚单体，和D） 在E的存在下，0至10重量％的其它共聚单体）每100重量份的A）至D）的单体混合物为2至60重量份的聚乙烯醇。
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公开(公告)号：US5182312A
公开(公告)日：1993-01-26
申请号：US589808
申请日：1990-09-24
IPC分类号： A61L15/42 , A61L15/60 , C08F2/08 , C08F2/24 , C08F20/04 , C08F20/12 , C08F20/52 , C08F20/58 , C08F20/60 , C08F26/00 , C08F26/06 , C08F26/08 , C08F26/10 , C08F28/00 , C08F28/02 , C08F30/02 , C08F220/04 , C08F220/10 , C08F290/00 , C08F299/00
CPC分类号： A61L15/425 , A61L15/60 , C08F2/08 , C08F20/04
摘要： The present invention relates to hydrophilic, swellable polymers which consists of radicals of the general formula I ##STR1## wherein R.sup.1 to R.sup.3 are defined as stated in the description, and of radicals of a crosslinking agent which have originated from monomers having at least two olefinically unsaturated double bonds, and which are characterized in that they are in the form of a highly porous, foam-like polyhedral structure, their preparation and their use as absorption agents for water and aqueous solutions.
摘要翻译： 本发明涉及亲水性，可溶胀的聚合物，其由通式I（I）的基团组成，其中R 1至R 3如描述中所述定义，并且交联剂的自由基源自具有 至少两个烯属不饱和双键，其特征在于它们是高度多孔，泡沫状多面体结构的形式，它们的制备及其作为水和水溶液吸收剂的用途。
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公开(公告)号：US4902772A
公开(公告)日：1990-02-20
申请号：US143705
申请日：1988-01-14
CPC分类号： C08G63/605 , C08G63/78
摘要： A process of polymerizing a polymerizable material in an inert organic liquid medium, in which the polymer formed from the monomer or monomers is insoluble, comprising dispersing the polymerizable material in the organic liquid in the presence of a finely, divided particulate material comprising an inorganic portion insoluble in the organic liquid medium and in combination therewith, preferably by covalent or ionic bonding, hydrocarbon chains containing at least 8 carbon atoms, the hydrocarbon chains being soluble in the organic liquid medium and heating the mixture to polymerize the polymerizable material to a required degree of polymerization. The process provides a means of stabilizing dispersion polymerizations which need to be carried out at very high temperatures to effect the polymerization.
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公开(公告)号：US4883698A
公开(公告)日：1989-11-28
申请号：US141728
申请日：1988-01-11
CPC分类号： B32B15/08 , C08F2/08 , G03G9/08702 , Y10S428/91 , Y10T428/1359 , Y10T428/24975 , Y10T428/2826 , Y10T428/31663 , Y10T428/31667 , Y10T428/31913
摘要： For packaging purposes, metallized multilayer films containing a biaxially oriented polypropylene film as a base layer should have high scratch resistance, good heat-sealing properties, such as low heat-sealing temperature, attractive visual properties, such as high metallic luster, excellent metallizability of the base layer or of a covering layer, and also good processing properties during metallization, printing, slitting, and during processing on fast-running packaging machines. This requirement profile is fulfilled by a multilayer film of asymmetric structure containing a biaxially oriented base layer 4 composed of polypropylene, a heat-sealing layer 3 which contains an additive combination composed of pigment in platelet form and siloxane and which is optionally modified by an addition of polypropylene and a hydrocarbon resin, and of a corona-treated polypropylene covering layer 2 which is not capable of being heat-sealed. A corona-treated, heat-sealable copolymer may also be used as the covering layer 2, instead of a covering layer 2 composed of non-heat-sealable polypropylene. The covering layer 2 can also be omitted; in that case the surface of the base layer 4 is metallized. Tubular bags, jackets, containers of various shape for packaging foodstuffs, including the vacuum packaging of foodstuffs, are manufactured from this multilayer film.
摘要翻译： 为了包装目的，含有作为基层的双轴取向聚丙烯薄膜的金属化多层膜应具有高的耐擦伤性，良好的热封性能，例如低的热封温度，有吸引力的视觉特性，例如高的金属光泽，优异的金属化性 基层或覆盖层，以及在快速运行的包装机器的金属化，印刷，切割和加工过程中也具有良好的加工性能。 该需求曲线通过包含由聚丙烯构成的双轴取向基底层4的不对称结构的多层膜来实现，该热封层3含有由片状的颜料和硅氧烷组成的添加剂组合，并且其任选地通过加成 的聚丙烯和烃树脂，以及不能被热密封的经电晕处理的聚丙烯覆盖层2。 也可以使用电晕处理的可热封的共聚物作为覆盖层2，而不是由不可热封的聚丙烯构成的覆盖层2。 覆盖层2也可以省略; 在这种情况下，基底层4的表面被金属化。 用这种多层膜制造包装食品的各种形状的管状袋，夹克，容器，包括食品的真空包装。
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27.发明授权Stabilized high solids low Ig copolymer nonaqueous dispersion for clear coat finishes 失效稳定的高固含量低Ig共聚物非水分散体，用于透明涂层漆
公开(公告)号：US4818792A
公开(公告)日：1989-04-04
申请号：US51254
申请日：1987-04-14
IPC分类号： C08F2/08 , C08F2/14 , C08F265/04 , C08F267/02 , C08F267/06 , C08L51/06
CPC分类号： C08F265/04 , C08F2/08 , C08F2/14 , Y10S525/91 , Y10S525/911 , Y10S525/912 , Y10S525/913 , Y10S525/925
摘要： A high solids, stable, nonaqueous dispersion, comprising a low Tg copolymer, having a Tg between about -10.degree. C. and about 30.degree. C., particularly adapted for use as a clear coat automotive finish. The copolymer is the copolymerization product of monomers whose Tg is above about 50.degree. C., polar monomers whose Tg is up to about 15.degree. C. and .alpha., .beta. ethylenically unsaturated stabilizer copolymers. The stabilizer copolymers are formed from .alpha., .beta. ethylenically unsaturated monomers and at least one oxirane containing compound and have a molecular weight of about 2,000 to about 25,000, are soluble in aliphatic solvents and have a Tg of about -60.degree. C. to about 0.degree. C. These nonaqueous dispersions result in coatings having high % solids, ease of application, minimal sagging and good gloss and DOI. They are preferably made by copolymerizing ethylenically unsaturated monomers with about 0.5% to about 4% acid functional chain transfer agents and reacting the thus formed copolymer with about 1% to about 4% oxirane containing .alpha., .beta. ethylenically unsaturated monomers to modify the copolymer resulting in a stabilizer copolymer. The nonaqueous dispersion is made by a free radical copolymerization of the monomers whose Tg is above about 50.degree. C., polar monomers whose Tg is up to about 15.degree. C., and the stabilizer copolymers in a nonpolar solvent at reflux temperatures.
摘要翻译： 高固体，稳定的非水分散体，包含Tg在约-10℃至约30℃之间的低Tg共聚物，特别适用于透明涂层汽车漆。 共聚物是Tg高于约50℃的单体的共聚产物，Tg高达约15℃的极性单体和α，β烯属不饱和稳定剂共聚物。 稳定剂共聚物由α，β烯键式不饱和单体和至少一种含环氧乙烷的化合物形成，分子量约为2,000至约25,000，可溶于脂族溶剂，Tg约为-60℃至约0℃ DEG。这些非水分散体导致具有高固含量，易于使用，最小流挂和良好的光泽度和DOI的涂层。 它们优选通过使烯属不饱和单体与约0.5％至约4％的酸官能链转移剂共聚而制备，并使由此形成的共聚物与约1％至约4％的含有α，β-烯键式不饱和单体的环氧乙烷反应以改性共聚物， 稳定剂共聚物。 非水分散体通过Tg高于约50℃的单体，Tg高达约15℃的极性单体和稳定剂共聚物在非极性溶剂中在回流温度下进行自由基共聚而制备。
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公开(公告)号：US4810763A
公开(公告)日：1989-03-07
申请号：US138509
申请日：1987-12-23
申请人： Prakash Mallya , Yehuda Ozari
发明人： Prakash Mallya , Yehuda Ozari
IPC分类号： C08F2/14 , C08F2/00 , C08F2/08 , C08F2/18 , C08F2/20 , C08F20/10 , C08F212/00 , C08F212/08 , C08F220/12 , C09J7/02 , C09J133/04 , C09J133/06 , C09J133/08
CPC分类号： C09J7/0217 , C08F2/08 , Y10S526/931
摘要： Inherently tacky infusible pressure-sensitive adhesive microspheres are prepared by polymerizing at least one monomer which when polymerized will form a pressure-sensitive adhesive having a glass transition temperature less than abotu -20.degree. C. in an organic medium in which the monomer is substantially insoluble and in the presence of a surfactant and a suspension stabilizer which are soluble in the organic medium and substantially insoluble in the monomer under conditions of shear sufficient to form suspended particles of a size less than 200 microns. A monomer soluble initiator is preferably employed. The preferred media are ethylene glycol and glycerol and the preferred monomers are 2-ethyl hexyl acrylate and methacrylic acid.
摘要翻译： 通过聚合至少一种单体来制备固有粘性的不可压敏粘合剂微球，所述单体当聚合时将形成玻璃化转变温度低于-20℃的压敏粘合剂，其中单体基本上不溶于有机介质 并且在表面活性剂和悬浮稳定剂存在下，其可溶于有机介质并且在剪切条件下基本上不溶于单体的悬浮稳定剂足以形成小于200微米的悬浮颗粒。 优选使用单体可溶性引发剂。 优选的介质是乙二醇和甘油，优选的单体是丙烯酸2-乙基己酯和甲基丙烯酸。
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29.发明授权Method of forming a nonaqueous stable emulsion of rubber in polymerizable monomer, and the polymerization process and thermoplastic copolymers produced thereby 失效在可聚合单体中形成橡胶的非水稳定乳液的方法，以及由此制备的聚合方法和热塑性共聚物
公开(公告)号：US4767822A
公开(公告)日：1988-08-30
申请号：US90817
申请日：1987-08-28
IPC分类号： C08F2/08 , C08F287/00 , C08F291/02 , C08L51/00 , C08L51/04 , C08L53/00
CPC分类号： C08L51/006 , C08F2/08 , C08F287/00 , C08F291/02 , C08L51/04
摘要： A process for the production of a nonaqueous stable emulsion feedstock comprising a rubber, a block copolymer having at least one component miscible with the rubber and at least one component miscible with the monomer, and at least two unsaturated organic monomers capable of free radical polymerization is disclosed. At least one of the monomers must be miscible with the rubber and the mixture of the monomers is substantially a nonsolvent for the rubber. The block copolymer maintains the rubber or rubber-rich particles in emulsified form within the mixture of monomers. In general, the process comprises (1) mixing the rubber, block copolymer and at least a portion of the rubber miscible monomers to form a first nonaqueous solution, (2) mixing the remaining monomers and the remaining portion of the rubber miscible monomers to form a second solution, and (3) combining the two solutions to form the nonaqueous stable emulsion feedstock. A process for polymerizing this feedstock material and the polymerization product produced thereby is also disclosed.
摘要翻译： 一种制备非水稳定乳液原料的方法，包括橡胶，具有至少一种可与橡胶混合的组分的嵌段共聚物和可与该单体混溶的至少一种组分和至少两种能够进行自由基聚合的不饱和有机单体， 披露 至少一种单体必须与橡胶混溶，单体的混合物基本上是橡胶的非溶剂。 嵌段共聚物将橡胶或富含橡胶的颗粒在单体混合物中保持乳化形式。 通常，该方法包括（1）将橡胶，嵌段共聚物和至少一部分可与橡胶混溶的单体混合以形成第一非水溶液，（2）将剩余单体和剩余部分的可混溶橡胶混合形成 第二溶液，和（3）组合两种溶液以形成非水稳定乳液原料。 还公开了一种用于聚合该原料的方法和由其制备的聚合产物。
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30.发明授权Process for preparing a non-aqueous liquid dispersion of polymer made with a polymeric peroxide 失效制备由聚合物过氧化物制成的聚合物的非水性液体分散体的方法
公开(公告)号：US4659769A
公开(公告)日：1987-04-21
申请号：US465074
申请日：1983-02-09
申请人： Hiroshi Ohmura , Masaharu Nakayama
发明人： Hiroshi Ohmura , Masaharu Nakayama
IPC分类号： C08F2/08 , C08F2/14 , C08F4/36 , C08F4/38 , C08F293/00 , C08F299/00
CPC分类号： C08F4/36 , C08F293/00
摘要： A specialized polymeric peroxide is copolymerized with vinyl type monomers in the presence of organic liquid, thereby obtaining a solution of a copolymer having peroxy bonds therein.This solution is admixed with vinyl type monomers which are different in composition from the ones used in the first copolymerization, and the resultant mixture is subjected to block copolymerization.The obtained block copolymer solution is admixed with an organic liquid which exert solubility to one of polymers of the vinyl type monomers which are employed in the first or second copolymerization, whereby a non aqueous system liquid dispersion is obtained.This dispersion contains a block copolymer in a high concentration and it also is splendid in uniformity of dispersion and dispersion stability.
摘要翻译： 在有机液体存在下，将特殊的聚合过氧化物与乙烯基类单体共聚，从而得到其中具有过氧键的共聚物的溶液。 将该溶液与在第一共聚合中使用的组合物不同的乙烯基类单体混合，将所得混合物进行嵌段共聚。 将获得的嵌段共聚物溶液与在第一次或第二次共聚中使用的乙烯基型单体的聚合物之一中溶解度的有机液体混合，从而得到非水系统液体分散体。 该分散体含有高浓度的嵌段共聚物，并且还具有分散稳定性和分散稳定性的均匀性。
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