公开(公告)号：US11697626B2

公开(公告)日：2023-07-11

申请号：US17054906

申请日：2019-05-06

Applicant: SABIC Global Technologies B.V.

Inventor： Mohammed Bismillah Ansari ,  Guillermo Leal ,  Vijay Dinkar Bodas ,  Naif Mohammed Al-Naddah Al-Otaibi

IPC: C07C5/05 ,  C07C7/08 ,  C07C29/08 ,  C10G11/00 ,  C10L1/16

CPC classification number: C07C5/05 ,  C07C7/08 ,  C07C29/08 ,  C10G11/00 ,  C10L1/1608 ,  C10L2200/0423 ,  C10L2230/22

Abstract: A method of producing a fuel additive includes: passing a raffinate stream comprising C4 hydrocarbons through a hydrogenation unit, forming a first process stream; passing the first process stream through an extractive distillation unit, forming a C4 olefin stream; passing the C4 olefin stream through a stripper column, forming a purified C4 olefin stream; and forming the fuel additive by passing the purified C4 olefin stream through a hydration unit.

公开(公告)号：US11591532B2

公开(公告)日：2023-02-28

申请号：US17600447

申请日：2020-03-27

Applicant: SABIC Global Technologies B.V.

Inventor： Guillermo Leal ,  Vinodkumar Vasudevan ,  Somak Paul ,  Kamalakar Gunda

IPC: C10L1/02 ,  C10L1/10 ,  C10L1/182 ,  C10L10/10

Abstract: An unleaded gasoline composition comprises, based on the total volume of the unleaded gasoline composition, 50 to 96 vol. % of an unleaded gasoline; 2 to 20 vol. % of a mixed butanol; and 2 to 30 vol. % of a distillate oil fraction comprising a paraffin, an olefin, a naphthene, and an aromatic at an initial boiling point cut of 180° C., wherein the unleaded gasoline, the mixed butanol, and the distillate oil fraction are selected to provide the unleaded gasoline composition with a Research Octane Number of 90 to 101, determined in accordance with ASTM D 2699; and a Motor Octane Number of 81.4 to 90, determined in accordance with ASTM D 2700.

公开(公告)号：US11578034B2

公开(公告)日：2023-02-14

申请号：US16496497

申请日：2018-03-07

Applicant: SABIC Global Technologies B.V.

Inventor： Mohammed Bismillah Ansari ,  Vijay Dinkar Bodas ,  Guillermo Leal

IPC: C07C273/04 ,  C07C269/00 ,  C07C273/14 ,  C07D317/36 ,  C01C1/08

Abstract: Systems and methods for integrated glycerol carbonate and/or urea production. This disclosure pertains to development of a process for production of glycerol carbonate and/or urea from ammonia, carbon dioxide and glycerol. The process integrates glycerol carbonate production into a urea production process. The urea produced in the production facility may be used to produce glycerol carbonate by reacting urea with glycerol. The ammonia generated by glycerol carbonate production may be recycled back to urea production. Unreacted urea from the glycerol carbonate production may be separated and recycled to the urea product stream. The systems and methods can reduce the cost for urea production and increase product value of the excessive glycerol produced from other chemical plants.

公开(公告)号：US11518951B2

公开(公告)日：2022-12-06

申请号：US16981189

申请日：2019-03-18

Applicant: SABIC Global Technologies B.V. ,  Saudi Arabian Oil Company

Inventor： Guillermo Leal ,  Naif Mohammed Al-Naddah Al-Otaibi ,  Kareemuddin Mahaboob Shaik ,  Mohammed Bismillah Ansari ,  Vijay Dinkar Bodas

IPC: C10L1/16 ,  C07C5/05 ,  C07C7/00 ,  C07C7/04 ,  C07C7/13 ,  C07C29/04 ,  C10L10/10 ,  C10L1/182

Abstract: A method of producing a fuel additive includes passing a feed stream comprising C4 hydrocarbons through a hydrogenation unit producing a hydrogenated stream; passing the hydrogenated stream through a distillation unit producing a first stream and a second stream; producing an isobutylene stream by passing the first stream through a molecular sieve unit; passing the isobutylene stream to a hydration unit as a feedstock for the fuel additive; and forming the fuel additive in the hydration unit.

公开(公告)号：US11248181B2

公开(公告)日：2022-02-15

申请号：US17042614

申请日：2019-04-11

Applicant: SABIC Global Technologies B.V. ,  Saudi Arabian Oil Company

Inventor： Guillermo Leal ,  Kareemuddin Mahaboob Shaik ,  Hiren Shethna ,  Naif Mohammed Al-Naddah Al-Otaibi ,  Mohammed Bismillah Ansari ,  Zhonglin Zhang

IPC: C10G67/04 ,  C07C7/08 ,  C10G69/06 ,  C10G69/04 ,  C07C5/22 ,  C10L1/182 ,  C10L1/185

Abstract: A method of producing a fuel additive includes passing a feed stream comprising C4 hydrocarbons through a butadiene extraction unit producing a first process stream; passing the first process stream through a methyl tertiary butyl ether unit producing a second process stream and a methyl tertiary butyl ether product; passing the second process stream through a hydration unit producing the fuel additive and a recycle stream; passing the recycle stream through a hydrogenation unit; and recycling the recycle stream to a steam cracker unit and/or to the feed stream

公开(公告)号：US20210246088A1

公开(公告)日：2021-08-12

申请号：US17264430

申请日：2019-09-16

Applicant: SABIC Global Technologies B.V.

Inventor： Guillermo Leal ,  Mohammed Bismillah Ansari ,  Vijay Dinkar Bodas ,  Sultan Eid Al-Otaibi ,  Mohammed A. Al-Ghamdi ,  Naif Mohammed Al-Naddah Al-Otaibi

IPC: C07C5/05 ,  C07C7/04 ,  C07C29/04

Abstract: A method for the production of a fuel additive includes passing a hydrocarbon stream comprising crude mixed C4 hydrocarbons through a first hydrogenation unit to produce a first product stream; passing the first product stream from the first hydrogenation unit to a methyl tert-butyl ether synthesis unit forming methyl tert-butyl ether and a byproduct stream; passing the byproduct stream through a first distillation unit to separate the byproduct stream into a first 1-butene stream, an isobutane stream, and a 2-butene and n-butane stream; forming a second product stream by passing the 2-butene and n-butane stream to a selective conversion unit; passing the second product stream into a second distillation unit to form an n-butane stream and a second 1-butene stream; passing the second 1-butene stream to a fuel additive production unit; and passing the first 1-butene stream to the fuel additive production unit to form the fuel additive.

公开(公告)号：US11008525B2

公开(公告)日：2021-05-18

申请号：US16493203

申请日：2018-03-19

Applicant: SABIC Global Technologies B.V.

Inventor： Vijay Dinkar Bodas ,  Sultan Eid Al-Otaibi ,  Guillermo Leal ,  Mohammed Bismillah Ansari ,  Naif Mohammed Al Naddah Al-Otaibi

IPC: C10L1/185 ,  C10L1/02 ,  C10L10/10

Abstract: A method of manufacturing an octane-boosting fuel additive, the method comprises reacting n-butyraldehyde, iso-butyraldehyde, or a combination comprising at least one of the foregoing with glycerol in the presence of an acidic catalyst to obtain an octane-boosting product mixture comprising 2-propyl-5-hydroxy-1,3-dioxane, 2-isopropyl-5-hydroxy-1,3-dioxane, 2-propyl-5-hydroxymethyl-1,3-dioxolane, 2-isopropyl-5-hydroxymethyl-1,3-dioxolane, or a combination comprising at least one of the foregoing.

公开(公告)号：US20210002185A1

公开(公告)日：2021-01-07

申请号：US16981183

申请日：2019-03-18

Applicant: SABIC Global Technologies B.V. ,  Saudi Arabian Oil Company

Inventor： Guillermo Leal ,  Naif Mohammed Al-Naddah Al-Otaibi ,  Mohammed Bismillah Ansari ,  Kareemuddin Mahaboob Shaik ,  Hiren Shethna ,  Zhonglin Zhang

IPC: C07C4/04 ,  C07C5/05 ,  C07C29/04 ,  C10L1/182 ,  C07C5/03 ,  C10L1/16 ,  C10L10/10

Abstract: A method of producing a fuel additive includes producing a first product stream comprising butadiene by passing a feed stream comprising C4 hydrocarbons through a steam cracker; transforming greater than or equal to 90 weight % of the butadiene in the first product stream into a second product stream by passing the first product stream through a first hydrogenation unit, wherein the second product stream comprises 1-butene, 2-butene, n-butane, isobutylene, isobutane, or a combination thereof; and converting the second product stream into the fuel additive by passing the second product stream through a fuel additive synthesis unit with an acid catalyst.

公开(公告)号：US20200157450A1

公开(公告)日：2020-05-21

申请号：US16633311

申请日：2018-07-27

Applicant: SABIC GLOBAL TECHNOLOGIES B.V. ,  SAUDI ARABIAN OIL COMPANY

Inventor： Guillermo Leal ,  Kareemuddin Mahaboob Shaik ,  Mohammed Bismillah Ansari ,  Hiren Shethna ,  Zhonglin Zhang

IPC: C10L10/10 ,  C07C41/06 ,  C07C1/22 ,  C07C5/25 ,  C07C29/04 ,  C10L1/182 ,  C07C6/04 ,  C07C4/06

Abstract: A method of producing a fuel additive includes passing a feed stream comprising C4 hydrocarbons through a methyl tertiary butyl ether unit producing a first process stream; passing the first process stream through a selective hydrogenation unit producing a second process stream; passing the second process stream through an isomerization unit producing a third process stream; and passing the third process stream through a hydration unit producing the fuel additive and a recycle stream.

公开(公告)号：US09957211B2

公开(公告)日：2018-05-01

申请号：US15308884

申请日：2015-05-07

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Guillermo Leal ,  Zeeshan Nawaz ,  Renaat Hennus ,  Antonio Matarredona ,  Faisal Baksh

IPC: C07C41/06 ,  C07C7/167 ,  C07C7/163 ,  C07C7/13 ,  C07C7/00 ,  C07C7/04

CPC classification number: C07C41/06 ,  C07C7/005 ,  C07C7/04 ,  C07C7/13 ,  C07C7/163 ,  C07C7/167 ,  C07C43/046 ,  C07C11/08 ,  C07C11/09

Abstract: The present invention provides, among other things, new processes for separating and purifying C4 fractions from a crude C4 stream. Compared to prior methods, the processes of the present invention simplify the C4 separation processes, afford more possible configurations for separation and purification, and are more cost effective. The processes and systems provided herein can be used as part of a cost-effective and efficient method for synthesizing methyl tertiary-butyl ether.