公开(公告)号：US20210246088A1

公开(公告)日：2021-08-12

申请号：US17264430

申请日：2019-09-16

Applicant: SABIC Global Technologies B.V.

Inventor： Guillermo Leal ,  Mohammed Bismillah Ansari ,  Vijay Dinkar Bodas ,  Sultan Eid Al-Otaibi ,  Mohammed A. Al-Ghamdi ,  Naif Mohammed Al-Naddah Al-Otaibi

IPC: C07C5/05 ,  C07C7/04 ,  C07C29/04

Abstract: A method for the production of a fuel additive includes passing a hydrocarbon stream comprising crude mixed C4 hydrocarbons through a first hydrogenation unit to produce a first product stream; passing the first product stream from the first hydrogenation unit to a methyl tert-butyl ether synthesis unit forming methyl tert-butyl ether and a byproduct stream; passing the byproduct stream through a first distillation unit to separate the byproduct stream into a first 1-butene stream, an isobutane stream, and a 2-butene and n-butane stream; forming a second product stream by passing the 2-butene and n-butane stream to a selective conversion unit; passing the second product stream into a second distillation unit to form an n-butane stream and a second 1-butene stream; passing the second 1-butene stream to a fuel additive production unit; and passing the first 1-butene stream to the fuel additive production unit to form the fuel additive.

公开(公告)号：US11008525B2

公开(公告)日：2021-05-18

申请号：US16493203

申请日：2018-03-19

Applicant: SABIC Global Technologies B.V.

Inventor： Vijay Dinkar Bodas ,  Sultan Eid Al-Otaibi ,  Guillermo Leal ,  Mohammed Bismillah Ansari ,  Naif Mohammed Al Naddah Al-Otaibi

IPC: C10L1/185 ,  C10L1/02 ,  C10L10/10

Abstract: A method of manufacturing an octane-boosting fuel additive, the method comprises reacting n-butyraldehyde, iso-butyraldehyde, or a combination comprising at least one of the foregoing with glycerol in the presence of an acidic catalyst to obtain an octane-boosting product mixture comprising 2-propyl-5-hydroxy-1,3-dioxane, 2-isopropyl-5-hydroxy-1,3-dioxane, 2-propyl-5-hydroxymethyl-1,3-dioxolane, 2-isopropyl-5-hydroxymethyl-1,3-dioxolane, or a combination comprising at least one of the foregoing.

公开(公告)号：US11161796B2

公开(公告)日：2021-11-02

申请号：US17264430

申请日：2019-09-16

Applicant: SABIC Global Technologies B.V.

Inventor： Guillermo Leal ,  Mohammed Bismillah Ansari ,  Vijay Dinkar Bodas ,  Sultan Eid Al-Otaibi ,  Mohammed A. Al-Ghamdi ,  Naif Mohammed Al-Naddah Al-Otaibi

IPC: C07C5/00 ,  C07C7/00 ,  C07C29/04 ,  C07C5/05 ,  C07C7/04

Abstract: A method for the production of a fuel additive includes passing a hydrocarbon stream comprising crude mixed C4 hydrocarbons through a first hydrogenation unit to produce a first product stream; passing the first product stream from the first hydrogenation unit to a methyl tert-butyl ether synthesis unit forming methyl tert-butyl ether and a byproduct stream; passing the byproduct stream through a first distillation unit to separate the byproduct stream into a first 1-butene stream, an isobutane stream, and a 2-butene and n-butane stream; forming a second product stream by passing the 2-butene and n-butane stream to a selective conversion unit; passing the second product stream into a second distillation unit to form an n-butane stream and a second 1-butene stream; passing the second 1-butene stream to a fuel additive production unit; and passing the first 1-butene stream to the fuel additive production unit to form the fuel additive.

公开(公告)号：US10829706B2

公开(公告)日：2020-11-10

申请号：US16631100

申请日：2018-07-17

Applicant: SABIC Global Technologies B.V.

Inventor： Vijay Dinkar Bodas ,  Sultan Eid Al-Otaibi ,  Guillermo Leal ,  Mohammed Bismillah Ansari ,  Naif Mohammed Al Naddah Al-Otaibi

IPC: C10L1/185 ,  C07C41/56 ,  C10L10/12 ,  B01J39/20

Abstract: A method of manufacturing a cetane-boosting fuel additive includes reacting formaldehyde and 2-ethylhexanol at a mole ratio of 10:1 to 1:1, or 5:1 to 1.5:1, or 4:1 to 2:1, or 3.5:1 to 2.5:1 in the presence of a heterogeneous acid catalyst at a temperature of 300 to 375° K to obtain a cetane-boosting product mixture comprising H3C(CH2)3CH(CH2CH3)CH2(OCH2)nOH, H3C(CH2)3CH(CH2CH3)CH2(OCH2)nOCH2CH(CH2CH3)(CH2)3CH3, or a combination thereof, wherein n has an average value of 2.8 to 3.2, preferably an average value of 3.

公开(公告)号：US20200157444A1

公开(公告)日：2020-05-21

申请号：US16631100

申请日：2018-07-17

Applicant: SABIC Global Technologies B.V.

Inventor： Vijay Dinkar Bodas ,  Sultan Eid Al-Otaibi ,  Guillermo Leal ,  Mohammed Bismillah Ansari ,  Naif Mohammed Al Naddah Al-Otaibi

IPC: C10L1/185 ,  C10L10/12 ,  C07C41/56

Abstract: A method of manufacturing a cetane-boosting fuel additive includes reacting formaldehyde and 2-ethylhexanol at a mole ratio of 10:1 to 1:1, or 5:1 to 1.5:1, or 4:1 to 2:1, or 3.5:1 to 2.5:1 in the presence of a heterogeneous acid catalyst at a temperature of 300 to 375° K to obtain a cetane-boosting product mixture comprising H3C(CH2)3CH(CH2CH3)CH2(OCH2)nOH, H3C(CH2)3CH(CH2CH3)CH2(OCH2)nOCH2CH(CH2CH3)(CH2)3CH3, or a combination thereof, wherein n has an average value of 2.8 to 3.2, preferably an average value of 3.