公开(公告)号：US5434004A

公开(公告)日：1995-07-18

申请号：US338791

申请日：1994-11-08

申请人： Masanobu Ajioka ,  Katashi Enomoto ,  Akihiro Yamaguchi ,  Hosei Shinoda

发明人： Masanobu Ajioka ,  Katashi Enomoto ,  Akihiro Yamaguchi ,  Hosei Shinoda

IPC分类号： B32B27/06 ,  B32B3/10 ,  A61K31/74 ,  B32B3/26

CPC分类号： B32B27/06 ,  Y10S428/913 ,  Y10T428/2969 ,  Y10T428/31504 ,  Y10T428/31993 ,  Y10T442/3854

摘要： A laminate comprising a thermoplastic polymer essentially consisting of polylactic acid, a copolymer of lactic acid and hydroxycarboxylic acid or a mixture of polylactic acid with a copolymer of lactic acid and hydroxycarboxylic acid, and a regenerated cellulose film, paper, leather, cloth, or fiber. The laminate undergoes degradability in the natural environment, is excellent in transparency, gloss and moisture-proofness, has high strength and can be used for various packaging materials.

摘要翻译： 包含基本由聚乳酸，乳酸和羟基羧酸的共聚物或聚乳酸与乳酸和羟基羧酸的共聚物的混合物的热塑性聚合物和再生纤维素膜，纸，皮革，布或纤维组成的层压体 。 层压体在自然环境中经历降解性，透明性，光泽和防湿性优异，强度高，可用于各种包装材料。

公开(公告)号：US5340646A

公开(公告)日：1994-08-23

申请号：US871651

申请日：1992-04-21

申请人： Kenji Morita ,  Kohichi Uchiki ,  Hosei Shinoda

发明人： Kenji Morita ,  Kohichi Uchiki ,  Hosei Shinoda

IPC分类号： C08J5/18 ,  B32B3/06 ,  C08G63/08

CPC分类号： C08J5/18 ,  C08J2367/04 ,  Y10S428/91 ,  Y10T428/249956 ,  Y10T428/25 ,  Y10T428/258

摘要： A breathable, hydrolyzable, porous film which is obtained by the process comprising adding from 40 to 250 parts by weight of a finely-powdered filler having an average particle size of from 0.3 to 4 .mu.m to 100 parts by weight of a polylactic acid-based resin composition comprising from 80 to 100% by weight of polylactic acid or a lactic acid-hydroxycarboxylic acid copolymer and from 0 to 20% by weight of a plasticizer, melting and film-forming the resultant mixture, and successively stretching the thus-obtained film 1.1 times or more at least in the direction of the axis; and which is consequently useful as a material for leakproof films of sanitary materials such as a paper diaper and packaging materials, and does not accumulate as wastes because of hydrolyzability in the natural environment in the case of being abandoned after use.

摘要翻译： 一种透气的，可水解的多孔膜，其通过该方法获得，包括将40至250重量份的平均粒度为0.3至4μm的细粉末填料加入到100重量份的聚乳酸 - 包含80-100重量％的聚乳酸或乳酸 - 羟基羧酸共聚物和0-20重量％的增塑剂，熔融和成膜所得混合物，并依次拉伸由此获得的 至少在轴的方向上为1.1倍以上的膜; 因此可用作纸尿布和包装材料等卫生材料的防漏膜的材料，并且由于在使用后放弃的情况下由于自然环境中的水解性而不会作为废物积聚。

公开(公告)号：US07847021B2

公开(公告)日：2010-12-07

申请号：US10589431

申请日：2005-02-09

申请人： Hosei Shinoda ,  Takeshi Kashima ,  Masahiro Enna ,  Shinichi Kojoh ,  Hideyuki Kaneko ,  Shingo Matsuo ,  Nobuo Kawahara ,  Tomoaki Matsugi ,  Yuichi Matsuda ,  Takayuki Onogi ,  Fumio Kageyama

发明人： Hosei Shinoda ,  Takeshi Kashima ,  Masahiro Enna ,  Shinichi Kojoh ,  Hideyuki Kaneko ,  Shingo Matsuo ,  Nobuo Kawahara ,  Tomoaki Matsugi ,  Yuichi Matsuda ,  Takayuki Onogi ,  Fumio Kageyama

IPC分类号： C08G67/00 ,  C08L67/00 ,  C08L67/04 ,  C08L23/10 ,  C08L23/26

CPC分类号： C08L51/06 ,  C08L23/00 ,  C08L23/02 ,  C08L67/02 ,  C08L69/00 ,  Y10T428/31786 ,  Y10T428/31855 ,  Y10T428/31935 ,  Y10T428/31938 ,  C08L2666/24 ,  C08L2666/18 ,  C08L2666/14 ,  C08L2666/02

摘要： A modified polyolefin resin comprising a copolymer having a structure that a propylene-based polyolefin segment (a) and a segment (b) containing a lactic acid as a constituent are bonded in a block state and/or a graft state through a vinyl monomer having a hydroxyl group, wherein a number average molecular weight of the propylene-based polyolefin segment (a) is from 1,000 to 100,000, a number average molecular weight of the segment (b) containing lactic acid as a constituent is from 1,000 to 200,000, and a weight composition of the propylene-based polyolefin segment (a) and the segment (b) containing lactic acid as a constituent is from 10/90 to 90/10. The modified polyolefin resin can be used in a resin composition containing an aliphatic polyester resin (A), a polyolefin resin (B) and the modified polyolefin resin (C). The composition can exhibit excellent heat resistance and impact resistance and can be used for molding various parts.

摘要翻译： 包含具有丙烯类聚烯烃链段（a）和含有乳酸作为组分的链段（b）的结构的共聚物的改性聚烯烃树脂以嵌段状态和/或接枝状态通过具有 羟基，其中丙烯类聚烯烃链段（a）的数均分子量为1,000〜100,000，以乳酸为成分的链段（b）的数均分子量为1,000〜200,000，以及 丙烯类聚烯烃链段（a）和含有乳酸作为成分的链段（b）的重量组成为10/90〜90/10。 改性聚烯烃树脂可用于含有脂族聚酯树脂（A），聚烯烃树脂（B）和改性聚烯烃树脂（C）的树脂组合物中。 该组合物可以表现出优异的耐热性和抗冲击性，并且可用于各种部件的成型。

公开(公告)号：US20050107505A1

公开(公告)日：2005-05-19

申请号：US10503225

申请日：2003-01-31

申请人： Hosei Shinoda ,  Takeshi Kashima ,  Takayuki Kuroki ,  Akinori Takehara ,  Shoji Obuchi

发明人： Hosei Shinoda ,  Takeshi Kashima ,  Takayuki Kuroki ,  Akinori Takehara ,  Shoji Obuchi

IPC分类号： C08L67/06 ,  C08F299/02 ,  C08G69/40 ,  C08J5/18 ,  C08K5/00 ,  C08K5/05 ,  C08K5/09 ,  C08K5/14 ,  C08L1/12 ,  C08L29/04 ,  C08L67/00 ,  C08L67/02 ,  C08L67/04 ,  C08L77/00 ,  C08L77/08 ,  C08L101/00 ,  C08L101/12 ,  C08L101/16

CPC分类号： C08L67/02 ,  C08G69/40 ,  C08J5/18 ,  C08J2367/04 ,  C08K5/00 ,  C08K5/14 ,  C08L1/12 ,  C08L29/04 ,  C08L67/00 ,  C08L67/04 ,  C08L67/06 ,  C08L77/00 ,  C08L101/00 ,  C08L2201/06 ,  C08L2666/02 ,  C08L2666/14

摘要： A resin composition (AA) comprising an aliphatic polyester or aliphatic polyamide (component (A)), a plastic having a melting point or glass transition temperature (Tg) of −10° C. or more (component (B)) and a radical generating agent (C), wherein the compounding ratio of the component (A), the component (B) and the radical generating agent (C), based on the total weight thereof, is: 1 to 98.995% by weight of the component (A), 98.995 to 1% by weight of the component (B), and 0.005 to 5% by weight of the radical generating agent (C), and an aliphatic unsaturated polybasic acid (a) is contained in the polymer constituent of the component (A) and/or the component (B). The resin composition is suitable as a starting material of biodegradable material which maintains transparency, is free of bleeding of a plasticizer, is endowed with flexibility and has other advantageous characteristics so that it can be used in various fields.

摘要翻译： 包含脂族聚酯或脂肪族聚酰胺（组分（A））的树脂组合物（AA），熔点或玻璃化转变温度（Tg）为-10℃以上的组分（组分（B））和基团 （C），其中组分（A），组分（B）和自由基产生剂（C）的配混比基于其总重量计为：组分（1）的1-98.995重量％ A），98.995〜1重量％的组分（B）和0.005-5重量％的自由基产生剂（C）和脂族不饱和多元酸（a）包含在组分 （A）和/或组分（B）。 该树脂组合物适合作为可保持透明性，不含增塑剂渗色性的生物降解材料的起始材料，具有柔软性并具有其它有利特征，因此可用于各种领域。

公开(公告)号：US06419951B1

公开(公告)日：2002-07-16

申请号：US09985874

申请日：2001-11-06

申请人： Hosei Shinoda ,  Yukiko Asou ,  Hiroaki Tamatani

发明人： Hosei Shinoda ,  Yukiko Asou ,  Hiroaki Tamatani

IPC分类号： A61K952

CPC分类号： C08G73/1092 ,  A61K9/1641 ,  C08G73/16

摘要： A sustained releasing drug which includes an effective component and a copolymer having a weight-average molecular weight of 1,000 to 100,000 which comprises, as repeating structure units, both of a succinimide unit represented by the structural formula (1) and a hydroxycarboxylic acid unit represented by the structural formula (2) wherein R is a methyl group or a hydrogen atom, and a process for preparing a copolymer which comprises a polymerization step of heating a mixture of aspartic acid and a cyclic ester compound.

摘要翻译： 一种持续释放药物，其包含有效成分和重均分子量为1,000〜100,000的共聚物，其包含作为重复结构单元的由结构式（1）表示的琥珀酰亚胺单元和表示的结构式（1）所示的羟基羧酸单元 通过其中R是甲基或氢原子的结构式（2），以及包括加热天冬氨酸和环状酯化合物的混合物的聚合步骤的共聚物的制备方法。

公开(公告)号：US5444107A

公开(公告)日：1995-08-22

申请号：US917351

申请日：1992-07-23

申请人： Masanobu Ajioka ,  Katashi Enomoto ,  Akihiro Yamaguchi ,  Hosei Shinoda

发明人： Masanobu Ajioka ,  Katashi Enomoto ,  Akihiro Yamaguchi ,  Hosei Shinoda

IPC分类号： C08L3/00 ,  C08L3/04 ,  C08L67/00 ,  C08L67/04 ,  C08L101/16 ,  C08K5/00

CPC分类号： C08L3/00 ,  C08L3/04 ,  C08L67/04 ,  C08L2201/06

摘要： A degradable polymer composition essentially consisting of a mixture of a thermoplastic polymer composition primarily comprising polylactic acid or lactic acid-hydroxycarboxylic acid copolymer and one or more substance selected from starch and modified starch, and is a degradable polymer which does not cause problems such as environmental pollution and can be used for films, filaments and packaging materials, food packaging materials in particular.

摘要翻译： 一种可降解聚合物组合物，其主要由主要包含聚乳酸或乳酸 - 羟基羧酸共聚物的热塑性聚合物组合物和选自淀粉和改性淀粉的一种或多种物质的混合物组成，并且是不会引起诸如环境的问题的可降解聚合物 污染，可用于薄膜，细丝和包装材料，特别是食品包装材料。

公开(公告)号：US5272221A

公开(公告)日：1993-12-21

申请号：US863085

申请日：1992-04-03

申请人： Toshio Kitao ,  Yoshiharu Kimura ,  Hideki Yamane ,  Hiroki Nakata ,  Hosei Shinoda

发明人： Toshio Kitao ,  Yoshiharu Kimura ,  Hideki Yamane ,  Hiroki Nakata ,  Hosei Shinoda

IPC分类号： A61L31/04 ,  C08L77/00 ,  C08G69/48

CPC分类号： A61L31/041 ,  C08L77/00 ,  Y10S525/937

摘要： The present invention provides a nylon composition having increased hydrolyzability which is obtained by physically mixing 100 parts by weight of a nylon with 1 to 50 parts by weight of at least one polymer selected from the group consisting of polylactic acid, polyglycolic acid and a copolymer containing 50 mol % or more of a lactic acid unit or a glycolic acid unit as a repeating unit in its chain; and a method for increasing the hydrolyzability of a nylon by preparing such a composition. High hydrolyzability can be imparted to the nylon inherently having extremely low hydrolyzability without impairing its original mechanical strength. Therefore, various molded articles made from the nylon can be hydrolyzed under natural circumstances, and thus the wastes are not stored.

摘要翻译： 本发明提供了具有增加的水解性的尼龙组合物，其通过将100重量份的尼龙与1至50重量份的至少一种选自聚乳酸，聚乙醇酸和含有 50重量％以上的乳酸单元或乙醇酸单元作为其链中的重复单元; 以及通过制备这种组合物来提高尼龙的水解性的方法。 可以将高水解性赋予固有地具有极低水解性的尼龙，而不损害其原始的机械强度。 因此，由尼龙制成的各种成型体在自然条件下可以水解，因此不会将废物进行储存。

公开(公告)号：US5238968A

公开(公告)日：1993-08-24

申请号：US5375

申请日：1993-01-15

申请人： Kenji Morita ,  Kohichi Uchiki ,  Hosei Shinoda

发明人： Kenji Morita ,  Kohichi Uchiki ,  Hosei Shinoda

IPC分类号： B29C44/56 ,  C08J9/06 ,  C08J9/12

CPC分类号： B29C44/5672 ,  B29C44/5627 ,  C08J9/06 ,  C08J9/12 ,  C08J2300/16 ,  C08J2367/04

摘要： A degradable polymer network obtained by adding from 0.2 to 10 parts by weight of a foaming agent to 100 parts by weight of a polylactic acid-base resin composition comprising from 80 to 100% by weight of polylactic acid or a lactic acid-hydroxycarboxylic acid copolymer and from 0 to 20% by weight of a plasticizer, conducting melt-foaming extrusion of resulting mixture, and opening the foam cells in the extrudate. The high polymer network is characterized in suitable flexibility and hydrolyzability and thus useful as a material for absorbing of oils and body fluids, screens for sunlight, heat-insulating materials, filter media and packaging materials; and does not accumulate as industrial wastes because of hydrolyzability in the natural environment, even though abandoned after use.

摘要翻译： 通过将0.2〜10重量份的发泡剂加入到100重量份的包含80至100重量％的聚乳酸或乳酸 - 羟基羧酸共聚物的聚乳酸基树脂组合物中获得的可降解聚合物网络 和0至20重量％的增塑剂，对所得混合物进行熔融发泡挤出，以及在挤出物中打开泡沫细胞。 高聚物网络的特征在于具有合适的柔性和水解性，因此可用作吸收油和体液，阳光屏蔽，绝热材料，过滤介质和包装材料的材料; 并且由于天然环境中的水解性而不会作为工业废物积累，即使在使用后放弃。

公开(公告)号：US5206318A

公开(公告)日：1993-04-27

申请号：US855159

申请日：1992-03-20

申请人： Kazukiyo Kobayashi ,  Toshihiro Akaike ,  Hosei Shinoda ,  Kazushi Morimoto

发明人： Kazukiyo Kobayashi ,  Toshihiro Akaike ,  Hosei Shinoda ,  Kazushi Morimoto

IPC分类号： C07H15/04 ,  C07H15/10 ,  C07H15/18 ,  C08F12/26 ,  C12N5/00

CPC分类号： C07H15/04 ,  C07H15/10 ,  C07H15/18 ,  C08F12/26 ,  C12N5/0068

摘要： A styrene derivative carrying N-acethylchito-oligosaccharide chains, a polystyrene derivative carrying N-acetylchito-oligosaccharide chains on the side chains as well as a method for preparing these compounds are herein disclosed. The method for preparing the styrene derivative comprises reacting N-acetylchito-oligosaccharide lactone with vinylbenzylamine or a derivative thereof while the method for preparing the polystyrene derivative comprises polymerizing the styrene derivative. These derivatives can be employed as biomedical materials, in particular as materials for cell culture.

摘要翻译： 本文公开了携带N-乙酰壳寡糖链的苯乙烯衍生物，侧链上携带N-乙酰基 - 寡糖链的聚苯乙烯衍生物以及这些化合物的制备方法。 制备苯乙烯衍生物的方法包括使N-乙酰基壳寡糖内酯与乙烯基苄胺或其衍生物反应，而制备聚苯乙烯衍生物的方法包括使苯乙烯衍生物聚合。 这些衍生物可以用作生物医学材料，特别是作为细胞培养的材料。