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    Highly active, supported ziegler-natta catalyst systems for olefin polymerization, methods of making and using the same
    21.
    发明授权
    Highly active, supported ziegler-natta catalyst systems for olefin polymerization, methods of making and using the same 失效
    用于烯烃聚合的高活性，支持的齐格勒 - 纳塔催化剂体系，其制备和使用方法

    公开(公告)号：US06413901B1

    公开(公告)日：2002-07-02

    申请号：US09581327

    申请日：2000-06-09

    申请人： Akhlaq Moman ,  Atieh Abu-Raqabah ,  Navin Nallaveerapan

    发明人： Akhlaq Moman ,  Atieh Abu-Raqabah ,  Navin Nallaveerapan

    IPC分类号： B01J3100

    CPC分类号： C08F10/02 ,  C08F10/00 ,  C08F4/027 ,  C08F4/6546 ,  C08F4/6555

    摘要： A catalyst composition for alpha olefin polymerization is provided. The catalyst composition is prepared by a process including treating PVC containing particles with an organomagnesium compound in an inert solvent, contacting the treated PVC containing particles with a transition metal compound from the group TiCl4, VCl4 or ZrCl4, in the absence of an electron donor, and activating the product particles with a cocatalyst. An organoaluminum compound can also be mixed with the organomagnesium compound prior to treating the PVC containing particles.

    摘要翻译： 提供了一种用于α-烯烃聚合的催化剂组合物。 催化剂组合物通过包括用有机镁化合物在惰性溶剂中处理含PVC颗粒的方法制备，在不存在电子给体的情况下使经处理的含PVC颗粒与来自TiCl 4，VCl 4或ZrCl 4的过渡金属化合物接触， 并用助催化剂活化产物颗粒。 有机铝化合物也可以在处理含有PVC的颗粒之前与有机镁化合物混合。

    Process for the polymerizaion of olefins
    24.
    发明申请
    Process for the polymerizaion of olefins 有权
    烯烃聚合方法

    公开(公告)号：US20090203859A1

    公开(公告)日：2009-08-13

    申请号：US11921616

    申请日：2006-05-12

    申请人： Wei Xu ,  Vugar O. Aliyev ,  Sirajudeen Mohamed ,  Atieh Abu-Raqabah

    发明人： Wei Xu ,  Vugar O. Aliyev ,  Sirajudeen Mohamed ,  Atieh Abu-Raqabah

    IPC分类号： C08F4/52

    CPC分类号： C08F10/02 ,  C08F110/02 ,  C08F210/16 ,  Y10S526/943 ,  C08F2/002 ,  C08F210/14

    摘要： The present invention relates to a process for the polymerization of olefins, comprising the steps of introducing at least one olefin, at least one polymerization catalyst, at least one cocatalyst and at least one cocatalyst aid, and optionally a scavenger, into a polymerization reactor, and polymerizing the olefin, wherein the cocatalyst aid is a reaction product prepared separately prior to the introduction into the reactor by reacting at least one metal alkyl compound of group IIA or IIIA of the periodic system of elements and at least one compound (A) of the formula RmXR′n, wherein R is a branched, straight, or cyclic, substituted or unsubstituted, hydrocarbon group having 1 to 30 carbon atoms, R′ is hydrogen or any functional group with at least one active hydrogen, X is at least one heteroatom selected from the group of O, N, P or S or a combination thereof, and wherein n and m are each at least 1 and are such that the formula has no net charge.

    摘要翻译： 本发明涉及一种烯烃聚合方法，包括以下步骤：将至少一种烯烃，至少一种聚合催化剂，至少一种助催化剂和至少一种助催化剂助剂以及任选的清除剂引入聚合反应器中， 并且使所述烯烃聚合，其中所述助催化剂是通过使至少一种元素周期系统的IIA族或IIIA族的至少一种金属烷基化合物与至少一种元素周期系统的至少一种化合物（A）反应，在引入反应器之前分别制备的反应产物 式RmXR'n，其中R是具有1至30个碳原子的支链，直链或环状的取代或未取代的烃基，R'是氢或具有至少一个活性氢的任何官能团，X是至少一个 选自O，N，P或S或其组合的杂原子，并且其中n和m各自为至少1并且使得该式不具有净电荷。

    Catalyst compositions for polymerizing olefins to multimodal molecular weight distribution polymer, processes for production and use of the catalyst
    27.
    发明授权
    Catalyst compositions for polymerizing olefins to multimodal molecular weight distribution polymer, processes for production and use of the catalyst 失效
    用于将烯烃聚合成多峰分子量分布聚合物的催化剂组合物，催化剂的生产和使用方法

    公开(公告)号：US06784263B2

    公开(公告)日：2004-08-31

    申请号：US10052326

    申请日：2002-01-18

    申请人： Orass Hamed ,  Akhlaq Moman ,  Atieh Abu-Raqabah

    发明人： Orass Hamed ,  Akhlaq Moman ,  Atieh Abu-Raqabah

    IPC分类号： C08F444

    CPC分类号： C08F10/00 ,  C08F4/65912 ,  C08F4/65925 ,  C08F110/02 ,  C08F210/16 ,  C08F4/65904 ,  C08F4/65916 ,  C08F2500/05 ,  C08F210/14

    摘要： A solid catalyst component comprises a transition metal-containing metallocene compound, a non-cyclopentadienyl transition metal compound, a magnesium compound and a polymeric material which acts as a support. The catalyst component is combined with co-catalyst organoaluminum compound or a mixture of organoaluminum compounds to provide a catalyst composition useful for olefin polymerization, e.g., to produce linear low, medium and high density polyethylenes or copolymerization of ethylene with alpha-olefins. Product polyolefin polymers have a varied range of molecular weight distributions. The catalyst composition is prepared by a process comprising combining polymer support particles, magnesium compound, transition metal-containing metallocene compound, and non-cyclopentadienyl transition metal compound to provide a solid catalyst component, and, combining the solid catalyst component with a cocatalyst compound to provide a polyolefin polymerization catalyst composition.

    摘要翻译： 固体催化剂组分包含含过渡金属的茂金属化合物，非环戊二烯基过渡金属化合物，镁化合物和作为载体的聚合物。 将催化剂组分与助催化剂有机铝化合物或有机铝化合物的混合物组合以提供可用于烯烃聚合的催化剂组合物，例如产生线性低，中和高密度聚乙烯或乙烯与α-烯烃的共聚。 产品聚烯烃聚合物具有不同范围的分子量分布。催化剂组合物通过包括将聚合物载体颗粒，镁化合物，含过渡金属的茂金属化合物和非环戊二烯基过渡金属化合物组合以提供固体催化剂组分的方法制备， 并且将固体催化剂组分与助催化剂化合物组合以提供聚烯烃聚合催化剂组合物。