公开(公告)号：US20220162143A1

公开(公告)日：2022-05-26

申请号：US17611320

申请日：2020-05-06

申请人： thyssenkrupp Industrial Solutions AG ,  thyssenkrupp AG

发明人： Alexander SCHULZ ,  Nicolas VON WINNING ,  Sina KUNZ

IPC分类号： C07C29/152 ,  B01J19/24 ,  B01D53/047 ,  B01D53/22

摘要： A process for synthesizing methanol may involve supplying a CO2 stream consisting predominantly of carbon dioxide and an H stream consisting predominantly of hydrogen to a methanol reactor arrangement for conversion to methanol. A tail gas stream comprising unreacted hydrogen may be obtained from the methanol reactor arrangement. The unreacted hydrogen may be at least partly recycled to the methanol reactor arrangement. The tail gas stream is supplied to a hydrogen recovery arrangement to obtain a return stream comprising the unreacted hydrogen. The molar proportion of hydrogen in the return stream may be higher than in the tail gas stream.

公开(公告)号：US11249446B2

公开(公告)日：2022-02-15

申请号：US16663737

申请日：2019-10-25

申请人： Dow Global Technologies LLC

发明人： Rahul Bindlish

IPC分类号： G05B13/04 ,  C07C29/152 ,  G05B13/02 ,  G05B19/05 ,  G06F17/18

摘要： A chemical system for an operation exhibiting steady-state gain inversion is provided herein and includes a reactor configured to receive a feed stream and produce an outlet stream to form a process and a control device configured to control a process. The control device receives inputs indicative of an operational parameter and output variables and, in response to the inputs and output variables, provides a steady-state manipulated input configured to control or optimize the process. The control device includes an input disturbance model, a state estimator, a non-linear steady-state target calculator, and a regulator configured to provide a signal for adjustment of one or more inputs based on the steady-state manipulated input and associated output variables.

公开(公告)号：US20210188747A1

公开(公告)日：2021-06-24

申请号：US17055284

申请日：2019-06-11

申请人： HALDOR TOPSØE A/S

发明人： Søren Grønborg ESKESEN ,  Per Juul DAHL ,  Emil Andreas TJÄRNEHOV ,  Max THORHAUGE

IPC分类号： C07C29/154 ,  B01J23/80 ,  B01J19/00 ,  C07C29/152

摘要： A process for the production of methanol from synthesis gas via an equilibrium reaction is conducted in a methanol preconverter within a certain operational window, said operational window being defined by the area below an approximately linear curve of the partial pressure of carbon monoxide vs. the boiling water temperature for water temperatures between 210 and 270° C. Methanol of different product grades may be obtained by operating in specific areas of the operational window.

公开(公告)号：US20210046442A1

公开(公告)日：2021-02-18

申请号：US16963545

申请日：2019-01-28

申请人： Nederlandse Organisatie voor toegepast-natuurwetenschappelijk onderzoek TNO

发明人： Earl Lawrence Vincent Goetheer ,  Marco Johannes Gerardus Linders ,  Juliana Garcia Moretz-Sohn Monteiro ,  Rajat Bhardwaj

IPC分类号： B01J8/00 ,  B01J8/06 ,  C07C29/152 ,  C07C41/01

摘要： The present invention is directed to a membrane reactor for the hydrogenation of carbon dioxide, said membrane reactor comprising a reaction compartment (2) comprising a catalyst bed, a permeate compartment (4) and a membrane separating the reaction compartment and the permeate compartment, wherein said permeate compartment comprises a condensing surface.

公开(公告)号：US10913698B2

公开(公告)日：2021-02-09

申请号：US16612537

申请日：2018-04-26

申请人： L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude

发明人： Frank Castillo-Welter ,  Stephane Haag ,  Robert Frind ,  Timm Schuhmann ,  Andreas Ochs ,  Marc Wagner ,  Solene Valentin

IPC分类号： B01J8/04 ,  B01J19/24 ,  C07C29/152 ,  C07C31/04

摘要： A process for conducting exothermic equilibrium reactions, especially for the performance of methanol synthesis by heterogeneously catalysed conversion of synthesis gas, is proposed, which enables readjustment and hence optimization of the reaction conditions along the longitudinal coordinate of the reactor. For this purpose, in the process according to the invention, a reactor is used which is divided into a multitude of series-connected reaction cells, each of which comprises a preheating zone, a cooled reaction zone, one or more cooling zones and a deposition zone for condensable reaction products. In this way, the reaction conditions are adjustable to the respective, local composition of the reaction mixture and variable over the reactor length.

公开(公告)号：US10676799B2

公开(公告)日：2020-06-09

申请号：US15236958

申请日：2016-08-15

申请人： ExxonMobil Research and Engineering Company

发明人： Paul J. Berlowitz ,  Timothy A. Barckholtz ,  Frank Hershkowitz

IPC分类号： H01M8/06 ,  H01M8/04 ,  C01B3/50 ,  C01B3/34 ,  H01M8/04089 ,  H01M8/04746 ,  H01M8/0612 ,  H01M8/0637 ,  H01M8/0668 ,  H01M8/14 ,  H01M8/0662 ,  H01M8/04791 ,  H01M8/04119 ,  C21B15/00 ,  F02C3/22 ,  H01M8/04111 ,  C10G2/00 ,  C10K3/04 ,  C01C1/04 ,  C04B7/36 ,  C07C29/151 ,  C07C1/04 ,  C01B3/16 ,  C25B3/02 ,  C01B3/48 ,  C07C29/152 ,  F02C6/18 ,  H01M8/04014 ,  H01M8/04828

摘要： In various aspects, systems and methods are provided for operating a molten carbonate fuel cell, such as a fuel cell assembly, with increased production of syngas while also reducing or minimizing the amount of CO2 exiting the fuel cell in the cathode exhaust stream. This can allow for improved efficiency of syngas production while also generating electrical power.

公开(公告)号：US10450512B2

公开(公告)日：2019-10-22

申请号：US15428956

申请日：2017-02-09

申请人： PRIMUS GREEN ENERGY INC.

发明人： Meifang Qin ,  Howard L. Fang ,  Zhong He ,  Ricardo Orench ,  Zhiyi Wu ,  Arie Toren

IPC分类号： C10G3/00 ,  C10G35/095 ,  C10L1/06 ,  C07C29/152 ,  C07C41/09

摘要： The present invention provides apparatuses and processes for producing high octane fuel from synthesis gas. The process combines transalkylation and zeolite-forming/aromatization in conjunction with a single recycle loop configuration in order to effectively promote the fuel quality, particularly octane rating. The process involves adding a step for enriching octane of the fuel coming from the single recycle loop process. Preferably, the enrichment step takes place in an octane enrichment reactor containing two different catalysts, a zeolite-forming/aromatization catalyst followed by a transalkylation catalyst. The final fuel product preferably has an octane of about 92 to about 112.

公开(公告)号：US20190224641A1

公开(公告)日：2019-07-25

申请号：US16329107

申请日：2017-08-29

申请人： FuelCell Energy, Inc.

发明人： Fred C. JAHNKE ,  Matthew LAMBRECH

IPC分类号： B01J19/24 ,  C01B3/38 ,  H01M8/0612 ,  B01J12/00 ,  C07C29/152

摘要： A system for producing liquid fuel including a hydrocarbon source, a fuel cell unit configured to output anode exhaust gas containing a predetermined amount of C02, and a reformer configured to receive a first hydrocarbon feed portion from the hydrocarbon source and the anode exhaust gas from the fuel cell unit, such that the reformer is configured to output a syngas having a first H2/CO ratio of at most 2:1.

公开(公告)号：US10227901B2

公开(公告)日：2019-03-12

申请号：US14904033

申请日：2014-07-08

申请人： Mitsubishi Hitachi Power Systems Europe GmbH

发明人： Christian Bergins ,  Torsten Buddenberg ,  Emmanouil Kakaras

IPC分类号： C07C1/12 ,  C10L3/00 ,  C25B1/02 ,  F01K13/00 ,  F01K17/02 ,  F01K23/18 ,  F01K25/10 ,  C25B1/04 ,  C25B15/02 ,  C25B15/08 ,  C07C29/00 ,  F01K3/18 ,  C07C29/152

摘要： One embodiment relates to a methanation method comprising the conversion into methane (CH4) of CO2, in particular CO2 gas, originating from, in particular diverted or obtained from, power plant flue gas from a power plant fired with carbon-containing fuel, in particular carbon-containing gas, and having a connected water/steam circuit, said method being performed in a methanation plant. Some embodiments provide a solution that makes it possible to couple a power plant and a methanation plant to one another in an energetically favorable manner.

公开(公告)号：US20180333695A1

公开(公告)日：2018-11-22

申请号：US15777732

申请日：2016-11-18

申请人： SABIC Global Technologies B.V.

发明人： Zeeshan Nawaz ,  Khalid Karim

IPC分类号： B01J19/24 ,  B01J19/00 ,  C10G2/00 ,  C07C29/152

摘要： A reactor for efficient control of endothermic and exothermic catalytic reactions, including, for example, Fischer Tropsch reactions. Also disclosed are methods of delivering coolant materials and gasification source materials to the reactor.