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公开(公告)号:US20170129996A1
公开(公告)日:2017-05-11
申请号:US15319896
申请日:2015-06-19
Applicant: SABIC Global Technologies B.V.
Inventor: Amanda Marie Flores , James Franklin Hoover
CPC classification number: C08G64/10 , C08G64/14 , C08K5/0066 , C08K5/02 , C08K5/03 , C08K5/136 , C08K5/42 , C08K5/526 , C08L69/00 , C08L2205/02 , C08L63/00
Abstract: Polymeric compositions having improved flame retardance properties are disclosed. The compositions comprise a cross-linkable polycarbonate resin having a photoactive group derived from a benzophenone, a bromine source, and optionally a non-brominated and non-chlorinated flame retardant. The composition contains a minimum amount of bromine. Articles formed from the compositions have robust flame retardance properties and enhanced chemical resistance.
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公开(公告)号:US09023912B2
公开(公告)日:2015-05-05
申请号:US14137292
申请日:2013-12-20
Applicant: SABIC Global Technologies B.V.
Inventor: Jean-Francois Morizur , Paul Dean Sybert , Peter Johnson , Thomas L. Evans , James Franklin Hoover , Amanda Marie Flores
CPC classification number: C08G64/1666 , C08G64/14 , C08G79/04 , C08L69/00 , C08L2205/03 , C08L83/10 , C08L23/0884 , C08L67/02 , C08L25/06 , C08L33/12 , C08L51/04 , C08L55/02
Abstract: Polymeric blends having improved flame retardance properties and good ductility at low temperatures are disclosed. The blend is formed from (A) a photoactive additive containing a photoactive group derived from a monofunctional benzophenone; and (B) a polymer resin which is different from the photoactive additive. The additive can be a compound, oligomer, or polymer. When exposed to ultraviolet light, crosslinking will occur between the photoactive additive and the polymer resin, enhancing the chemical resistance and flame retardance while maintaining ductility.
Abstract translation: 公开了具有改进的阻燃性能和低温下良好延展性的聚合物共混物。 共混物由(A)含有衍生自单官能二苯甲酮的光活性基团的光活性添加剂形成; 和(B)与光活性添加剂不同的聚合物树脂。 添加剂可以是化合物,低聚物或聚合物。 当暴露于紫外线下时,光活性添加剂和聚合物树脂之间会发生交联,提高耐化学性和阻燃性,同时保持延展性。
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公开(公告)号:US10544259B2
公开(公告)日:2020-01-28
申请号:US15748198
申请日:2016-08-31
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Abstract: An aromatic polycarbonate, having an aromatic polycarbonate backbone, can comprise: less than or equal to 5 ppm of polymeric chlorine attached to the aromatic polycarbonate backbone; less than 0.5 ppm of dichloromethane, less than 5 ppm of monohydric phenols, and less than 0.5 ppm of aromatic compounds containing no chlorine based on the total weight of the aromatic polycarbonate, wherein the aromatic compounds are compounds other than the aromatic polycarbonate.
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公开(公告)号:US20170240710A1
公开(公告)日:2017-08-24
申请号:US15519197
申请日:2015-10-16
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Nathalie Gonzalez Vidal , James Franklin Hoover , Fabrizio Micciche , Robert van de Grampel
IPC: C08G77/448
CPC classification number: C08G77/448 , C08G64/186 , C08G64/24
Abstract: Polysiloxane-polycarbonates and improved methods for preparing the polysiloxane-polycarbonates are provided. Also provided are blend compositions including the polysiloxane-polycarbonates. The blend compositions can include one or more additional polymers. The blend compositions can include one or more additives. The blend compositions can be used to prepare articles of manufacture.
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公开(公告)号:US09688855B2
公开(公告)日:2017-06-27
申请号:US14943681
申请日:2015-11-17
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Ramon Groote , James Franklin Hoover , Robert Dirk Van De Grampel , Mark Adrianus Johannes Van Der Mee , Remco Wirtz , Jian Yang , Junhua Zhang
CPC classification number: C08L69/00 , C08G64/186 , C08G77/448 , C08L2205/02
Abstract: A polycarbonate composition comprises: 30 to 95 wt % of one or more bisphenol A polycarbonate homopolymers; and 5 to 70 wt % of a poly(carbonate-siloxane) copolymer with a siloxane content of 10 wt. % to 25 wt. % based on the total weight of the poly(carbonate-siloxane), in an amount effective to provide a total siloxane content of 0.5 wt. % to 17.5 wt. % based on the total weight of the composition; the poly(carbonate-siloxane) copolymer comprising bisphenol carbonate units and siloxane units of the formulas or a combination comprising at least one of the foregoing, wherein E has an average value of 10 to 100, preferably 20 to 60, more preferably 30 to 50; wherein in the poly(carbonate-siloxane) copolymer less than 0.5 mol % of the siloxane units are directly coupled to another siloxane units.
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公开(公告)号:US20170166708A1
公开(公告)日:2017-06-15
申请号:US15320133
申请日:2015-06-19
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Amanda Marie Flores , James Franklin Hoover , Peter Johnson , Jean-Francois Morizur , Thomas Evans
CPC classification number: C08J3/24 , C08G64/04 , C08G64/06 , C08J3/28 , C08J2369/00 , C08K5/42 , C08K5/5435 , C08K5/549 , C08L69/00
Abstract: Articles having improved flame retardance and chemical resistance properties can be made from blends containing a cross-linkable polycarbonate resin having repeating units derived from a dihydroxybenzophenone. Predictive equations can be used to relate properties of the blend and the polycarbonate resin to the fmal properties of the article, and permit design of articles with desired combinations of properties.
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公开(公告)号:US09598578B1
公开(公告)日:2017-03-21
申请号:US14943714
申请日:2015-11-17
Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
Inventor: Ramon Groote , James Franklin Hoover , Robert Dirk Van De Grampel , Mark Adrianus Johannes Van Der Mee , Remco Wirtz , Jian Yang , Junhua Zhang
CPC classification number: C08L83/10 , C08G64/186 , C08G77/448 , C08L69/00 , C08L2205/025 , C08L2205/03 , C08L2205/035 , C08L83/00
Abstract: A polycarbonate composition comprises: a first poly(carbonate-siloxane) copolymer comprising carbonate units and siloxane units, wherein less than 0.5 mol % of the siloxane units are directly coupled to another siloxane unit; the first poly(carbonate-siloxane) copolymer comprising siloxane units with an average block length of about 10 to about 100, and a siloxane content from 5 wt % to 8 wt %; a second poly(carbonate-siloxane) copolymer comprising carbonate units and siloxane units, wherein less than 0.5 mol % of the siloxane units are directly coupled to another siloxane unit; the second poly(carbonate-siloxane) copolymer comprising siloxane units with an average block length of 10 to 100, a siloxane content from 10 wt % to 30 wt %, and wherein the weight ratio of the first poly(carbonate-siloxane) copolymer to the second poly(carbonate-siloxane) copolymer is 2 to 20; and optionally a bisphenol polycarbonate; wherein the polycarbonate composition has a total siloxane content of 2.5 wt % to 10 wt % and a molded part of 1 mm thickness has a haze of less than 2% as measured by HazeGard (ASTM D1003-00).
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公开(公告)号:US09481761B2
公开(公告)日:2016-11-01
申请号:US14701620
申请日:2015-05-01
Applicant: SABIC Global Technologies B.V.
Inventor: Jean-Francois Morizur , Paul Dean Sybert , James Franklin Hoover , Derek Lake
IPC: C08G64/00 , C08G64/14 , C08J3/28 , B29C35/08 , B29C45/00 , C08G64/04 , C08K5/3475 , C08K5/42 , C08K5/5393 , C08K5/549 , C08L69/00 , C08G64/24 , C08G67/00 , B05D3/06 , C08J7/12 , C08K5/52 , C08G63/02 , B29K269/00 , B29K69/00 , B29K105/00 , B29K105/24
CPC classification number: C08G64/14 , B05D3/067 , B29C35/08 , B29C35/0805 , B29C45/0001 , B29C2035/0827 , B29K2069/00 , B29K2105/0026 , B29K2105/24 , B29K2269/00 , C08G64/045 , C08G64/24 , C08G67/00 , C08J3/28 , C08J7/123 , C08J2369/00 , C08J2469/00 , C08K5/3475 , C08K5/42 , C08K5/52 , C08K5/5393 , C08K5/549 , C08L69/00 , C08L2201/02 , C08L2205/02 , C08L2205/025 , C08L2312/06
Abstract: Disclosed herein are compositions including a cross-linked polycarbonate. The cross-linked polycarbonate may be derived from a polycarbonate having about 0.5 mol % to about 5 mol % endcap groups derived from a monohydroxybenzophenone. A plaque including the composition can achieve a UL94 5VA rating. Also disclosed herein are articles including the compositions, methods of using the compositions, and processes for preparing the compositions.
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公开(公告)号:US20150259472A1
公开(公告)日:2015-09-17
申请号:US14723967
申请日:2015-05-28
Applicant: SABIC Global Technologies B.V.
Inventor: James Franklin Hoover , Derek Lake , Jean-Francois Morizur , Paul Dean Sybert
IPC: C08G64/28
Abstract: Different interfacial processes for producing photoactive additives are disclosed. Generally, the photoactive additives are formed from a photoactive moiety, a first linker moiety, and a diol chain extender. The resulting additives can be crosslinked with other polymers upon exposure to UV radiation.
Abstract translation: 公开了用于制备光活性添加剂的不同界面方法。 通常,光活性添加剂由光活性部分,第一连接体部分和二醇扩链剂形成。 所得添加剂可以在暴露于紫外线辐射下与其它聚合物交联。
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公开(公告)号:US20150232614A1
公开(公告)日:2015-08-20
申请号:US14701704
申请日:2015-05-01
Applicant: SABIC Global Technologies B.V.
Inventor: Jean-Francois Morizur , Paul Dean Sybert , Peter Johnson , Thomas L. Evans , James Franklin Hoover , Amanda Marie Flores
CPC classification number: C08G64/1666 , C08G64/14 , C08G79/04 , C08L69/00 , C08L2205/03 , C08L83/10 , C08L23/0884 , C08L67/02 , C08L25/06 , C08L33/12 , C08L51/04 , C08L55/02
Abstract: Polymeric blends having improved flame retardance properties and good ductility at low temperatures are disclosed. The blend is formed from (A) a photoactive additive containing a photoactive group derived from a monofunctional benzophenone; and (B) a polymer resin which is different from the photoactive additive. The additive can be a compound, oligomer, or polymer. When exposed to ultraviolet light, crosslinking will occur between the photoactive additive and the polymer resin, enhancing the chemical resistance and flame retardance while maintaining ductility.
Abstract translation: 公开了具有改进的阻燃性能和低温下良好延展性的聚合物共混物。 共混物由(A)含有衍生自单官能二苯甲酮的光活性基团的光活性添加剂形成; 和(B)与光活性添加剂不同的聚合物树脂。 添加剂可以是化合物,低聚物或聚合物。 当暴露于紫外线下时,光活性添加剂和聚合物树脂之间会发生交联,提高耐化学性和阻燃性,同时保持延展性。
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