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公开(公告)号：US20180354209A1
公开(公告)日：2018-12-13
申请号：US15781294
申请日：2015-12-04
Applicant: ESSILOR INTERNATIONAL
Inventor： Ronald A. Berzon , Haipeng Zheng
CPC classification number: B29D7/01 , C08K3/041 , C08K3/042 , C08K3/16 , C08K3/22 , C08K2003/166 , C08K2201/001 , C08K2201/005 , C08K2201/017 , C08L1/12 , C08L29/04 , C08L2201/10 , C08L2203/16 , G02B1/16 , G02B5/3033
Abstract: Embodiments of the disclosure relate to an antistatic film structure which comprises a transparent antistatic support structure and at least one antistatic component. The transparent antistatic support structure and antistatic component may be combined by imbibing, melt extruding, blown film extruding, calendaring, solvent casting, mold casting, wet transfer, sublimation, and solidification of a liquid to a solid using heat, UV or other means.
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公开(公告)号：US09709707B2
公开(公告)日：2017-07-18
申请号：US14688104
申请日：2015-04-16
Inventor： Haipeng Zheng
CPC classification number: G02B1/14 , G02B1/041 , G02B1/10 , G02B1/105 , Y10T428/265
Abstract: The present invention is drawn to an optical article comprising: (a) a transparent optical polymer substrate, (b) a transparent intermediate abrasion-resistant coating obtained from at least one epoxysilane by a sol-gel process, and (c) a transparent outer coating comprising a polythiolene matrix obtained by curing a liquid monomer mixture comprising at least one polyfunctional thiol and at least one polyfunctional allyl monomer, said cured polythiol-ene matrix having a glass transition temperature comprised in the range from 40° C. to 70° C. and a thickness from 3.5 μm to less than 10 μm. It is also drawn to a method for preparing such an optical article and to a method for repairing scratches in such an optical article by heating.
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公开(公告)号：US20170158878A1
公开(公告)日：2017-06-08
申请号：US15325591
申请日：2014-07-11
Inventor： Haipeng Zheng
CPC classification number: C09D7/65 , C08G77/14 , C08G77/26 , C08K3/36 , C08K5/06 , C08K5/42 , C08K5/43 , C08L71/02 , C08L71/126 , C09D5/00 , C09D5/24 , C09D7/40 , C09D7/63 , C09D183/06 , G02B1/16
Abstract: Described is a curable composition that includes a salt comprising an alkali cation or rare earth metal ion and a counter ion which is the conjugate base of a superacid, a silicon containing binder, and an additive having a formula R1-O—[(CH2—CHR3)-O]n—R2, in which R1 and R2 represent H or an alkyl group, R3 is H or methyl, and n is an integer ranging from 2 to 200. Said composition is typically provided as a coating or hard coating. When cured, the composition provides good antistatic performance on its surface or to a surface on which it is applied. The composition when formed may also provide high optical transparency. The composition when formed exhibits low haze and good mechanical properties, such as good abrasion resistance, or good scratch resistance, or good mar resistance to its surface or to the surface on which it is applied.
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14.发明授权Curable coating compositions providing antistatic abrasion resistant coated articles 有权提供抗静电耐磨涂层制品的可固化涂料组合物公开(公告)号：US09188703B2
公开(公告)日：2015-11-17
申请号：US13720500
申请日：2012-12-19
Inventor： Haipeng Zheng
IPC: C09D135/06 , G02B1/10 , B82Y30/00 , C09D5/24 , C09D183/06 , C08K3/36 , C08K5/5435 , C08L65/00
CPC classification number: G02B1/16 , B82Y30/00 , C08G2261/3223 , C08G2261/51 , C08K3/36 , C08K5/5435 , C09D5/24 , C09D183/06 , G02B1/105 , G02B1/11 , G02B1/14 , G02B1/18 , Y10T428/24413 , Y10T428/24975 , Y10T428/254 , Y10T428/257 , Y10T428/259 , Y10T428/265 , C08L2666/14 , C08L65/00 , C08K5/5419
Abstract: Curable composition providing, upon curing, an abrasion resistant, transparent, antistatic coating comprising: a) at least one conductive polymer, b) colloidal particles of at least one non-conductive oxide, c) at least one binder comprising at least one epoxysilane having at least two hydrolysable groups directly linked to the Si atom of the epoxysilane, and/or its hydrolysis product, said at least one conductive polymer and said colloidal particles of at least one non-conductive oxide being substantially not agglomerated, the content of said conductive polymer in the dry extract of said curable composition ranging from 0.1 to 10% by weight, preferably from 0.2 to 10% by weight and the content of the dry extract of said at least one epoxysilane in the dry extract of said curable composition ranging from 20 to 80% preferably 25 to 60% by weight based on the total weight of the dry extract.
Abstract translation: 固化组合物，其在固化时提供耐磨，透明的抗静电涂层，其包含：a）至少一种导电聚合物，b）至少一种非导电氧化物的胶体颗粒，c）至少一种包含至少一种环氧硅烷的粘合剂， 至少两个直接与环氧硅烷的Si原子连接的可水解基团和/或其水解产物，所述至少一种导电聚合物和至少一种非导电氧化物的胶体颗粒基本上不附聚，所述导电 所述可固化组合物的干提取物中的聚合物的量为0.1至10重量％，优选0.2至10重量％，所述可固化组合物的干提取物中所述至少一种环氧硅烷的干提取物的含量范围为20 至80重量％，优选25至60重量％，基于干提取物的总重量。
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15.发明授权公开(公告)号：US11214695B2
公开(公告)日：2022-01-04
申请号：US16463148
申请日：2017-10-25
Applicant: Essilor International
Inventor： Haipeng Zheng
IPC: C09D5/32 , C09D7/41 , C09D163/00 , G02C7/10 , B29D11/00 , C08K5/3415 , C08K5/29
Abstract: The present invention relates to an optical filtering coating composition, comprising at least one dye that at least partially inhibits transmission of light within the 400-500 nm wavelength range and has a conjugated chromophore, one or more epoxy compounds comprising at least one cycloaliphatic or aryl group, the ratio of the number of carbon atoms/the number of oxygen atoms in said epoxy compound being higher than or equal to 3, and the dry extract weight of such epoxy compounds present in the composition representing more than 33% of the dry extract weight of the composition. The coating composition can be applied on the main surface of the substrate of an optical article.
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Patent Agency Ranking
公开(公告)号：US11214026B2
公开(公告)日：2022-01-04
申请号：US15781294
申请日：2015-12-04
Applicant: ESSILOR INTERNATIONAL
Inventor： Ronald A. Berzon , Haipeng Zheng
Abstract: Embodiments of the disclosure relate to an antistatic film structure which comprises a transparent antistatic support structure and at least one antistatic component. The transparent antistatic support structure and antistatic component may be combined by imbibing, melt extruding, blown film extruding, calendaring, solvent casting, mold casting, wet transfer, sublimation, and solidification of a liquid to a solid using heat, UV or other means.
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公开(公告)号：US10371868B2
公开(公告)日：2019-08-06
申请号：US14906814
申请日：2013-07-23
Inventor： Haipeng Zheng
Abstract: The invention relates to a process for the manufacturing of an optical article comprising forming a multilayered coating on at least one face of an uncoated or coated substrate,and forming on the outermost layer of said multilayered coating, a layer-by-layer (LbL) coating exposed to environment, said LbL coating comprising at least two bilayers, each bilayer being formed successively by: i) applying a first layer composition comprising at least one compound A having a first electrical charge; ii) applying, directly onto the first layer resulting from i), a second layer composition comprising at least one compound B having a second electrical charge, said second electrical charge being opposite to said first electrical charge; iii) repeating at least once steps i) and ii), with the provisos that: -each of compounds A and B is independently chosen from polysaccharide polymers and colloids of metal oxide such as TiO2 and ZrO2 or silicon oxide, with the proviso that at least one of the compounds A and B is a polysaccharide polymer, -each of said compounds A and B is positively or negatively charged respectively, and d) crosslinking the first and second layers of said bilayers of the LbL coating by treatment with an aqueous composition comprising at least tetrakis(2-hydroxyethyl) orthosilicate (THEOS) as crosslinking agent to induce chemical linkages between compounds A and B. The invention also relates to the optical substrate obtained according to this process.
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18.发明授权公开(公告)号：US09791597B2
公开(公告)日：2017-10-17
申请号：US14330348
申请日：2014-07-14
Inventor： Haipeng Zheng
CPC classification number: G02B1/16 , C03C17/007 , C03C17/008 , C03C2217/475 , C03C2217/78 , C08K3/04 , C08K3/041 , C08K7/00 , C09D5/00 , C09D5/24 , C09D7/70 , G02B1/105 , G02B1/14 , Y10T428/24975 , Y10T428/26
Abstract: The present invention relates to a curable composition, providing, upon curing, an abrasion-resistant, transparent, antistatic coating, comprising carbon nanotubes and a binder comprising at least one epoxysilane compound, preferably an epoxyalkoxysilane, and optionally fillers such as nanoparticles of non electrically conductive oxides and/or additional binder components such as tetraethoxysilane. The invention further relates to optical articles comprising a substrate, and, starting from the substrate, an abrasion- and/or scratch-resistant coating, and an antistatic coating formed by depositing directly onto said abrasion- and/or scratch-resistant coating the above referred curable composition. The obtained optical articles exhibit antistatic properties, high optical transparency with about 91-92% of transmittance, low haze and improved abrasion resistance.
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公开(公告)号：US20150219800A1
公开(公告)日：2015-08-06
申请号：US14688104
申请日：2015-04-16
Inventor： Haipeng Zheng
CPC classification number: G02B1/14 , G02B1/041 , G02B1/10 , G02B1/105 , Y10T428/265
Abstract: The present invention is drawn to an optical article comprising: (a) a transparent optical polymer substrate, (b) a transparent intermediate abrasion-resistant coating obtained from at least one epoxysilane by a sol-gel process, and (c) a transparent outer coating comprising a polythiolene matrix obtained by curing a liquid monomer mixture comprising at least one polyfunctional thiol and at least one polyfunctional allyl monomer, said cured polythiol-ene matrix having a glass transition temperature comprised in the range from 40° C. to 70° C. and a thickness from 3.5 μm to less than 10 μm. It is also drawn to a method for preparing such an optical article and to a method for repairing scratches in such an optical article by heating.
Abstract translation: 本发明涉及一种光学制品，其包括：（a）透明光学聚合物基材，（b）通过溶胶 - 凝胶法由至少一种环氧硅烷获得的透明中间耐磨涂层，和（c）透明外部 包含通过固化包含至少一种多官能硫醇和至少一种多官能烯丙基单体的液体单体混合物获得的多硫醇基体的涂层，所述固化的多硫醇 - 烯基体的玻璃化转变温度为40℃至70℃ ，厚度从3.5μm到小于10μm。 还描述了制备这种光学制品的方法以及通过加热来修复这种光学制品中的划痕的方法。
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公开(公告)号：US11009724B2
公开(公告)日：2021-05-18
申请号：US16317762
申请日：2016-07-15
Applicant: Essilor International
Inventor： Haifeng Shan , Aref Jallouli , Hao-Wen Chiu , Srini Balasubramanian , Haipeng Zheng
Abstract: Disclosed are polarized films containing specific light filters that block transmission of harmful electromagnetic radiation. Also disclosed are methods of producing said films as well as ophthalmic lenses having increased eye health.
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