Process for preparing at least one organic target compound by heterogeneously catalyzed gas phase partial oxidation
    12.
    发明授权
    Process for preparing at least one organic target compound by heterogeneously catalyzed gas phase partial oxidation 有权
    通过非均相催化气相部分氧化制备至少一种有机靶化合物的方法

    公开(公告)号:US07439389B2

    公开(公告)日:2008-10-21

    申请号:US11357300

    申请日:2006-02-21

    IPC分类号: C07C51/16 C07C69/52

    CPC分类号: C07C51/252 C07C57/04

    摘要: A process for preparing an organic target compound by heterogeneously catalyzed gas phase partial oxidation of an organic precursor compound with molecular oxygen in two oxidation reactor lines operated in parallel and removal of the target compound from the mixture of the product gas streams in a workup line, wherein the catalyst charge of one of the oxidation lines comprises a portion of catalyst over which the heterogeneously catalyzed gas phase partial oxidation has already been carried out for longer than over the portions of catalyst of the catalyst charge of the other oxidation reactor line.

    摘要翻译: 通过在两个平行操作的氧化反应器管线中的有机前体化合物与分子氧的非均相催化气相部分氧化来制备有机靶化合物的方法,并且从处理线中的产物气流的混合物中除去目标化合物, 其中一个氧化线的催化剂装料包括催化剂的一部分,在该部分的催化剂上已经进行非均相催化的气相部分氧化比在另一个氧化反应器管线的催化剂装料的催化剂部分上的时间长。

    Heterogeneously catalyzed partial gas phase oxidation of acrolein to acrylic acid
    18.
    发明授权
    Heterogeneously catalyzed partial gas phase oxidation of acrolein to acrylic acid 有权
    丙烯醛的异相催化部分气相氧化成丙烯酸

    公开(公告)号:US06982347B2

    公开(公告)日:2006-01-03

    申请号:US10806460

    申请日:2004-03-23

    IPC分类号: C07C51/235

    CPC分类号: C07C51/252 C07C57/04

    摘要: In a process for partially oxidizing acrolein to acrylic acid in the gas phase under heterogeneous catalysis, the starting reaction gas mixture is oxidized at an acrolein loading of ≦145 and ≧70 l (STP) of acrolein/l of fixed catalyst bed·h over a fixed catalyst bed which is accommodated in two successive reaction zones A, B, the highest temperature of the reaction gas mixture within reaction zone A being above the highest temperature of the reaction gas mixture within reaction zone B.

    摘要翻译: 在非均相催化下在气相中将丙烯醛部分氧化为丙烯酸的方法中,起始反应气体混合物以丙烯醛负载<= 145和> = 70l(STP)的丙烯醛/ l固定催化剂床进行氧化。 h在固定的催化剂床上,其被容纳在两个连续的反应区A,B中,反应区A内的反应气体混合物的最高温度高于反应区B内的反应气体混合物的最高温度。