Aromatic amine curatives and their use
    14.
    发明授权
    Aromatic amine curatives and their use 失效
    芳香胺固化剂及其用途

    公开(公告)号:US06509434B1

    公开(公告)日:2003-01-21

    申请号:US09528837

    申请日:2000-03-20

    IPC分类号: C08G1832

    CPC分类号: C08G18/3868 C08G18/10

    摘要: Mixtures of isomeric alkylthiated mononuclear aromatic amines comprising in the range of about 30 to about 70 mole percent of (i) at least one 3,5-di(alkyl-thio)-2,6-diamino-1-alkylbenzene and in the range of about 30 to about 70 mole percent of at least one 3,5-di(alkylthio)-2,4-diamino-1-alkylbenzene, such mixture containing at least about 90 mole percent of (i) and (ii), and optionally containing up to 10 mole percent of one or more isomers of (i) and/or (ii). An alkyl group may be present as a substituent in lieu of a hydrogen atom in the remaining ring position. These mixtures are useful as curatives or extenders in processes for making polyurethanes, polyurethane-ureas, and polyureas.

    摘要翻译: 异构烷基化的单核芳香族胺的混合物,其包含(i)至少一种3,5-二(烷基 - 硫代)-2,6-二氨基-1-烷基苯的约30至约70摩尔%范围内, 约30至约70摩尔%的至少一种3,5-二(烷硫基)-2,4-二氨基-1-烷基苯,该混合物含有至少约90摩尔%的(ⅰ)和(ⅱ),和 任选地含有至多10摩尔%的(i)和/或(ii)的一种或多种异构体。 烷基可以作为取代基代替其余环位置上的氢原子。 这些混合物可用作制备聚氨酯,聚氨酯 - 脲和聚脲的方法中的固化剂或增量剂。

    Stabilization of (hydrocarbylthio) aromatic amines against odor formation
    15.
    发明授权
    Stabilization of (hydrocarbylthio) aromatic amines against odor formation 失效
    (烃基硫代)芳族胺对气味形成的稳定化

    公开(公告)号:US5840984A

    公开(公告)日:1998-11-24

    申请号:US880547

    申请日:1997-06-23

    CPC分类号: C07C319/26

    摘要: Odor formation during storage of (hydrocarbylthio)aromatic amines due to formation and release of odoriferous sulfur-containing species such as dihydrocarbyldisulfides, is suppressed. To accomplish this, a small amount of N,N-dihydrocarbylhydroxylamine odor-inhibitor (e.g., N,N-diethylhydroxylamine) is blended with the (hydrocarbylthio)aromatic amine. This enables products such as a mixture of 3,5-di(methylthio)-2,4-diaminotoluene and 3,5-di(methylthio)-2,6-diaminotoluene) to be stored for long periods of time with significantly reduced formation and release of odoriferous sulfur-containing species.

    摘要翻译: 抑制由于含有臭味的含硫物质如二烃基二硫化物的形成和释放而在(烃硫基)芳族胺储存期间的气味形成。 为了实现这一点,将少量的N,N-二烃基羟胺气味抑制剂(例如N,N-二乙基羟胺)与(烃硫基)芳族胺共混。 这使得诸如3,5-二(甲硫基)-2,4-二氨基甲苯和3,5-二(甲硫基)-2,6-二氨基甲苯的混合物的产物能够长时间储存​​,同时显着减少了形成 并释放有气味的含硫物质。