摘要:
A method includes a providing a molten glass fiber core and disposing a plurality of nanoparticles that include a transition metal oxide on the molten glass fiber core at or above the softening temperature of the glass fiber core, thereby forming a nanoparticle-laden glass fiber. The plurality of nanoparticles are embedded at the surface of said glass fiber core. A method includes providing a mixture of molten glass and a plurality of nanoparticles. The plurality of nanoparticles include a transition metal. The method further includes forming nanoparticle-laden glass fibers, in which the plurality of nanoparticles are embedded throughout the glass fibers.
摘要:
A process for preparing supported noble metal catalyst in situ is provided by mixing and crystallizing hexamethylenetetramine, soluble divalent metal salts solution, Al2O3 carriers and soluble noble metal salts solution wherein the hexamethylenetetramine is used as a precipitating agent for preparing hydrotalcite and a reducing agent of noble metal precursor. During the growth process of hydrotalcite, Al3+ on the Al2O3 carrier's surface is directly used as the trivalent metal ions in the laminate structure and the hydrotalcite is obtained on the surface of the Al2O3 carriers by in-situ growth. A supported catalyst Me-LDHs-Al2O3 containing an elementary noble metal is produced wherein the noble metal element particle in the catalyst has a particle size of 10 to 60 nm, and is evenly and stably dispersed on or between slabs of the hydrotalcite.
摘要翻译:通过混合和结晶六亚甲基四胺,可溶性二价金属盐溶液,Al 2 O 3载体和可溶性贵金属盐溶液提供了原位制备负载型贵金属催化剂的方法,其中六亚甲基四胺用作制备水滑石的沉淀剂和贵金属的还原剂 金属前体。 在水滑石生长过程中,Al2O3载体表面的Al3 +直接用作叠层结构中的三价金属离子,并通过原位生长在Al2O3载体表面获得水滑石。 制备含有贵金属的载体催化剂Me-LDHs-Al 2 O 3,其中催化剂中的贵金属元素颗粒具有10至60nm的粒度,并均匀且稳定地分散在水滑石板之间或之间。
摘要:
Supported noble metal-comprising catalysts which can be obtained by a) application of colloidal noble metal in the form of a colloidal solution, optionally in admixture with additives acting as promoters, to a support material, b1) drying of the resulting product at from 150 to 350° C., or b2) drying of the resulting product at from 150 to 350° C. and subsequent calcination at from 350 to 550° C. for epoxidation or oxidative dehydrogenation, a process for producing it, its use and also the use of colloidal noble metal for producing supported catalysts.
摘要:
An exhaust gas purifying catalyst (1) according to the present invention includes noble metal particles (6), a first compound (7) supporting the noble metal particles (6), and a second compound (9) disposed not in contact with the noble metal particles (6) and having an oxygen storage capacity. An average distance between the first compound (7) and the second compound (9) is between 5 nm and 300 nm.
摘要:
An exhaust gas purifying catalyst wherein the catalytic activity can be recovered over a wide temperature range is provided. Also provided are a method for recovering an exhaust gas purifying catalyst, and a catalyst system for exhaust gas purification. The exhaust gas purifying catalyst is characterized by containing an oxide A containing an oxide (A-1) containing an alkaline earth metal and/or a rare earth metal and an inorganic oxide (A-2), and a noble metal B supported by the oxide A. This exhaust gas purifying catalyst is also characterized in that the weight ratio of the oxide (A-1) containing an alkaline earth metal and/or a rare earth metal to the noble metal B is from 1:10 to 1:500.
摘要:
A process for the preparation of a catalyst or catalyst precursor, comprising the steps of: (a) admixing: (i) a catalytically active metal or metal compound (ii) a carrier material (iii) a gluing agent; and (iv) optionally one or more promoters, and/or one or more co-catalysts; (b) forming the mixture of step (a); and (c) drying the product of step (b) for more than 5 hours at a temperature up to 100 C to form the catalyst or catalyst precursor. The catalyst material mixture does not need to be calcined after forming to achieve the required minimum strength for use in a suitable reaction, such as Fischer Tropsch.
摘要:
An apparatus for producing hydrogen, which comprises: a. a heated steam reforming stage (1) with a reforming catalyst to convert gaseous or vaporizable hydrocarbons and water into hydrogen, carbon monoxide and further reformer products; b. at least one stage downstream of the steam reforming stage for the catalytic conversion of the mixture of hydrogen, carbon monoxide and excess steam leaving the steam reforming stage (shift stage) (2); and c. a fine purification stage (3) downstream of the shift stage(s) for the catalytic lowering of the residual carbon monoxide content of the conversion products by selective methanization, is described. In the apparatus, the shift stage (2) and the fine purification stage (3) are configured as a unitary hollow body (exothermic catalyst stage).
摘要:
In a three-way catalyst for purifying exhaust gases from internal combustion engines, scattering of bismuth components can be suppressed by employing a Bi—Ti composite oxide at a predetermined ratio. Accordingly, the effect of suppressing hydrogen sulfide emissions can be retained for a long time. This catalyst comprises a support substrate, and a catalyst layer formed on the support substrate and including a noble metal, a porous oxide, and a Bi—Ti composite oxide, and satisfies 0.3≦R≦1.5, where R is the molar ratio of the Bi content to the Ti content per unit volume of the support substrate.
摘要:
A honeycomb structure includes at least one honeycomb unit a NOx occluding catalyst and a noble metal catalyst. The at least one honeycomb unit includes inorganic particles and an inorganic binder and has a plurality of cell walls extending from one end face to another end face of the at least one honeycomb unit along a longitudinal direction of the at least one honeycomb unit to define a plurality of cells. The NOx occluding catalyst and the noble metal catalyst are provided at the plurality of cell walls. An amount of the noble metal catalyst provided on a surface of at least one of the plurality of cell walls is greater than an amount of the noble metal catalyst provided in a center part along a thickness of the at least one of the plurality of cell walls.
摘要:
A honeycomb structure includes a plurality of honeycomb fired bodies. Each of the plurality of honeycomb fired bodies has a longitudinal direction and cell walls extending along the longitudinal direction to define cells. An adhesive layer is provided between the plurality of honeycomb fired bodies to connect the plurality of honeycomb fired bodies so that each longitudinal direction is substantially in parallel with each other. The plurality of honeycomb fired bodies include at least one center-portion honeycomb fired body located at a center portion of the honeycomb structure and at least one periphery honeycomb fired body surrounding the center-portion honeycomb fired body to form a peripheral face of the honeycomb structure. The periphery honeycomb fired body includes contact faces contacting the adhesive layer. At least one of the contact faces has irregularities.