摘要:
A coating process and apparatus for manufacturing of solid particles with digestive tracts-soluble film by rolling water-containing solid particles at high speed, adding a coating liquid and drying them simultaneously.
WHEREIN R is a polyvalent organic radical, and n and m are each 1-10. They are useful for bonding receptive polymers to ethylenically unsaturated hydrocarbon silane treated glass and, particularly when m 1, for linking together the polymer chains of receptive polymers. Because in the reaction of these compounds with receptive polymers the azidoformate radicals react substantially faster than the azidosulfonyl radicals, linking of receptive polymers with these compounds can be effected in two steps. (1) After forming a blend of receptive polymer and azide of the formula, establishing and maintaining the blend in a temperature range for a period of time selected to permit at least a substantial portion of the azidoformate radicals to react with the polymer with a minimum of the azidosulfonyl radicals having reacted with the polymer, whereby a substantially nonlinked, but reacted, polymer (ankylomeric polymer) is formed, and (2) establishing and maintaining the ankylomeric polymer in a temperature range for a period of time selected to permit at least a substantial portion of the azidosulfonyl radicals to react with the ankylomeric polymer, whereby linking of the polymer chains takes place.
摘要:
1. IN A PROCESS FOR THE PREPARATION OF A POLYMER BY POLYMERIZING IN AN AQUEOUS DISPERSION A MONOMERIC MIXTURE CONSISTING ESSENTIALLY OF ON A WEIGHT PERCENT BASIS, 20-80 OF A CONJUGATED DIOLEFIN, 15-80 OF A VINYL MONOMER, AND 0.5-8 OF A CARBOXYLIC ACID HAVING ETHYLENIC UNSATURATION A TO THE CARBOXY GROUP AND COPOLYMERIZABLE WITH THE VINYL OR CONJUGATED DIENE MONOMER, SAID POLYMERIZATION BEING CONDUCTED AT AN INITIAL PH OF ABOUT 1.5-3.6 AND AT A TREMPERATURE NO GREATER THAN 100*C., AND THEREAFTER REAISING THE PH OF THE POLYMER DISPERSION BY THE ADDITION OF A BASE THERETO, THE IMPROVEMENT WHICH COMPRISES CONDUCTING THE POLYMERIZATION FOR 6-12 HOURS, AFTER THE POLYMERIZATION, NEUTRALIZING FROM 15-55% ONLY OF THE CARBOXYL GROUP OF THE THUS PRODUCED POLYMER WITH THE BASE, AND THEN AGGLOMERATING THE DISPERSION OF PARTIALLY NEUTRALIZED POLYMER, THEREBY PRODUCING A RELATIVELY ODORRLESS, LOW VISCOSITY AQUEOUS POLYMERIC DISPERSION.
摘要:
A process for producing an amphoteric resin which comprises reacting an esterified carboxylic acid type ion exchange resin with a basic amino acid.
摘要:
Polymeric quaternary ammonium betaines; the preparation thereof; and uses therefor. These are illustrated by polymers and copolymers of dicarboxylic anhydrides such as maleic anhydride and copolymers thereof derived from copolymerizable compounds such as olefins, vinyl compounds, etc; a carboxylic acid group of the anhydride polymeric unit being esterified with a quaternary alkanolamine. The polymers are prepared by reacting the anhydride-containing polymer with an alkylene oxide and a tertiary amine to form quaternary alkanolamine esters.
摘要:
SOLID SUPPORT MATERIALS USED IN THE SOLID PHASE SYNTHESIS OF COMPLEX ORGANIC MOLECULES MAY BE MODIFIED BY INTRODUCTION OF A P-OXY-BENZYL ALCOHOL OR A P-OXY-BENZYLOXYCARBONYLHYDRAZIDE LINKING GROUP TO PRODUCE MODIFIED SUPPOETS USEFUL IN SOLID PHASE PREPARATION OF PROTECTED PRODUCT FREE ACIDS AND PROTECTED PRODUCT HYDRAZIDES RESPECTIVELY. THE RESULTING PROTECTED PRODUCTS ARE PARTICULARLY USEFUL IN THE FRAGMENT CONDENSATION APPROACH TO THE SYNTHESIS OF LARGE, COMPLEX ORGANIC MOLECULES.
摘要:
THIS INVENTION COMPRISES WATER-SOLUBLE POLYMERS FROM POLYDIENES HAVING A SUBSTANTIAL AMOUNT OF REPEATING UNITS WITH PENDENT VINYL GROUPS, SUCH AS HIGH-VINYL POLYBUTADIENE, AND THE PROCESS FOR PREPARING SUCH WATER-SOLUBLE POLYMERS. THE PROCESS INVOLVES THE ANTI-MARKOWNIKOFF ADDITION OF HYDROGEN BROMIDE TO THE PENDENT VINYL GROUPS TO GIVE THE PRIMARY BROMIDE DERIVATIVE GROUPS, WHICH UPON THE ADDITION OF A TERTIARY AMINE, GIVE QUATERNARY AMMONIUM GROUPS WHICH IMPART WATER SOLUBILITY TO THE POLYMERS. THESE PRODUCTS ARE PARTICULARLY USEFUL FOR THE FLOCCULATION OF SOLIDS FROM SUSPENSIONS THEREOF, SUCH AS ELUTRIATED SEWAGE.
摘要:
RADIATION (THERMAL AND LIGHT)-SENSITIVE POLYMERS ARE PROVIDED WHICH ARE CHARACTERIZED BY THE RECURRING UNIT OF THE FORMULA:
-(CH(-COO-R2)-CH(-COO-R3)-CH(-R'')-CH2)-
WHEREIN R'' IS LOWER-ALKOXY OR PHENYL; ONE OF R2 AND R3 IS HYDROGEN AND THE OTHER IS
((R")Y,(N3-SO2-)X-PHENYL)-NH-COO-A-
WHEREIN A=ALKYLENE FROM 2 TO 10 CARBON ATOMS HAVING 2 TO 6 CARBON ATOMS BETWEEN VALENCIES, R" =LOWER-ALKYL OR HALOGEN, X IS 1 TO 2, Y IS 0 TO 2, AND X+Y=1 TO 3, WATER SOLUBLE SALTS ALSO DISCLOSED. THE POLYMERS ARE USEFUL FOR CHEMICALLY BONDING BASIC DYESTUFFS TO NON-DYERECEPTIVE SUBSTRATES (E.G.POLYETHYLENE) BY COATING THE SUBSTRATE WITH RADIATION SENSITIVE POLYMER AND EXPOSING THE COATED SUBSTRATE TO IRRADIATION. THE TREATED SUBSTRATE IS THEN CONTACTED WITH A BASIC DYESTUFF WHICH BONDS THERETO VIA THE FREE CARBOXYLIC GROUPS IN THE COATING. THE IRRADIATION CAN BE CARRIED OUT IMAGEWISE TO PRODUCE AN APPROPRIATE IMAGE ON THE SUBSTRATE WHICH IMAGE IS DEVELOPED BY DISSOLVING OUT UNEXPOSED RADIATION-SENSITIVE POLYMER PRIOR RO APPLICATION OF THE DYE. BONDING OF THE RADIATION-SENSITIVE POLYMERS OF THE INVENTION TO SUBSTRATES IN THE ABOVE MANNER CAN BE ALSO BE EMPLOYED AS A MEANS OF RENDERING HYDROPHILIC A VARIETY OF SUBSTRATES WHICH ARE HYDROPHOBIC.
摘要:
POLYARYLENEOXIDE HAVING AT LEAST ONE CHEMICALLY COMBINED ALIPHATICALLY UNSATURATED IMIDO RADICAL IS PROVIDED AND A METHOD FOR MAKING SUCH MATERIALS. BLENDS OF THE IMIDO-SUBSTITUTED POLYARYLENEOXIDE AND A VARIETY OF ALIPHATICALLY UNSATURATED ORGANIC MONOMERS, SUCH AS STYRENE, DIALLYLPHTHALATE, N-PHENYLMALEIMIDE, OR ORGANIC POLYMERS SUCH AS POLYSTYRENE, POLYSULFONE, POLYCARBONATE, POLYPHENYLENEOXIDES, ETC., ALSO ARE PROVIDED. THE IMIDO-SUBSTITUTED COMPOSITIONS OF THE PRESENT INVENTION CAN BE EMPLOYED AS COATINGS, VARNISHES, INJECTION MOLDING COMPOUNDS, LAMINATING COMPOUNDS, ETC.