Photocurable compositions and methods for 3D printing using them

    公开(公告)号:US11492504B2

    公开(公告)日:2022-11-08

    申请号:US16143062

    申请日:2018-09-26

    Abstract: The present disclosure relates generally to photocurable compositions and methods for continuously forming a three-dimensional body from these compositions. More particularly, the present disclosure relates to photocurable compositions comprising a mixture of polysiloxanes capable of being dually cured, i.e., first by UV radiation followed by thermal treatment, or being cured by UV radiation. In one aspect, the disclosure provides a photocurable composition, including: a first polysiloxane comprising at least two acrylate or methacrylate groups per molecule; a second polysiloxane containing at least one (e.g., at least two) Si—H group per molecule; a third polysiloxane containing at least one (e.g., at least two) reactive aliphatic ethylene group per molecule; a free radical photoinitiator in an amount of about 0.01 to about 10 weight % based on the total weight of (meth)acrylate-containing polysiloxane in the composition; and a hydrosilylation catalyst in an amount of about 0.001 to about 10 weight % hydride-containing polysiloxane and vinyl-containing polysiloxane in the composition.

    Heterochain Polymer Composition
    4.
    发明申请

    公开(公告)号:US20190202993A1

    公开(公告)日:2019-07-04

    申请号:US16236608

    申请日:2018-12-30

    CPC classification number: C08G77/14 C09D183/06 C09J183/06

    Abstract: This disclosure relates to polymerizable silicone compositions, methods for polymerizing such compositions, and to polymerized silicone compositions formed thereby. In one embodiment, a polymerizable composition includes one or more first organosiloxanes or organosilanes, each comprising a plurality of silicon hydride functional groups, one or more second organosiloxanes or organosilanes, each comprising a plurality of reactive heterocycloalkyl functional groups; and one or more third organosiloxanes or organosilanes, each comprising at least about one silicon hydride functional group and at least about one reactive heterocycloalkyl functional group; one or more reactive organic compounds, each comprising at least about one reactive heterocycloalkyl functional group; and an effective amount of a borane catalyst, present, for example, in an amount within the range of 0.0005 wt % to about 10 wt %, wherein the ratio of reactive heterocycloalkyl functional groups to reactive silicon hydride functional groups in the composition is in the range of 1:5 to 5:1.

    SILICONE COMPOSITIONS
    5.
    发明申请

    公开(公告)号:US20190031932A1

    公开(公告)日:2019-01-31

    申请号:US16148766

    申请日:2018-10-01

    Abstract: This disclosure relates to polymerizable silicone compositions, methods for polymerizing such compositions, and to polymerized silicone compositions formed thereby. In one embodiment, a polymerizable composition includes one or more first organosiloxanes or organosilanes, each comprising a plurality of silicon hydride functional groups, one or more second organosiloxanes or organosilanes, each comprising a plurality of reactive heterocycloalkyl functional groups; and one or more third organosiloxanes or organosilanes, each comprising at least about one silicon hydride functional group and at least about one reactive heterocycloalkyl functional group; and an effective amount of a borane catalyst, present, for example, in an amount within the range of 0.0005 wt % to about 10 wt %, wherein the ratio of reactive heterocycloalkyl functional groups to reactive silicon hydride functional groups in the composition is in the range of 1:5 to 5:1. The compositions and methods are useful, for example, in adhesive and sealing applications.

    Tubular coupling
    9.
    发明授权

    公开(公告)号:US11590333B2

    公开(公告)日:2023-02-28

    申请号:US16254369

    申请日:2019-01-22

    Abstract: A tubular coupling comprising a first connector comprising a body defining a first passageway portion and a valve area, the valve area comprising a first volume adjacent to an end of the first passageway portion; and a second volume in fluid communication with the first volume; and a first valve disposed in the first volume of the valve area; and a second connector adapted to receive at least a portion of the first connector, the second connector comprising: a body defining a second passageway portion and a valve area, the valve area comprising: a first volume adjacent to an end of the second passageway portion; and a second volume in fluid communication with the first volume; and a second valve disposed in the first volume of the valve area.

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