Abstract:
The disclosure provides a method of purifying a linear alpha olefin product, the method including feeding a linear alpha olefin feed stream comprising the linear alpha olefin product and at least one impurity into a distillation column, the distillation column having a plurality of stacked stages; withdrawing a side stream from at least one of said plurality of stacked stages; feeding the side stream into a reactor containing an isomerization catalyst to convert at least a portion of the at least one impurity from a first isomer to a second isomer, producing a reactor product stream having a reduced content of the first isomer; returning the reactor product stream to a stage of the distillation column; and withdrawing an overhead stream from the distillation column comprising the linear alpha olefin product and having a reduced content of the at least one impurity.
Abstract:
Disclosed is a catalyst capable of producing an olefin from an alkyl halide, the catalyst comprising a silicoaluminophosphate (SAPO) having a chabazite zeolite structure with the following chemical composition (SixAlyPz)O2, where x, y, and z represent the mole fractions of silicon, aluminum, and phosphorus, respectively, present as tetrahedral oxides, x is 0.01 to 0.30 and the sum of x+y+z is 1, and where the catalyst comprises silicon tetrahedral oxides that are connected with three or less aluminum tetrahedral oxide as shown by 29Si magic angle spinning (MAS) nuclear magnetic resonance (NMR) spectroscopy peak(s) with peak(s) maxima between −93 ppm and −115 ppm.
Abstract:
Disclosed are stable catalysts, and methods for their use, that are capable of producing an olefin from an alkyl halide. The catalysts include a phosphorus-treated silicoalummophosphate (SAPO) having a structure of X/SAPO or X/Z-SAPO, where X includes a non-framework phosphorus and Z is one or more elements from Groups 2A, 3A, IVB, VIB, VIIB, VIII, IB of the Periodic Table, or compounds thereof comprised in the SAPO framework.
Abstract:
A method for converting an alkyl halide to an olefin, the method comprising contacting a crystalline zeolite catalyst having an STI framework topology with a feed comprising the alkyl halide under reaction conditions sufficient to produce an olefin product comprising C2 to C5+ olefins, wherein the crystalline zeolite catalyst has a compositional formula: My/n[SixQyO2(x+y)] where M is a cation; n is the charge of the cation, y/n is the number of cations; x/y is equal to or greater than 5; and Q is aluminum, gallium iron, boron, indium, or mixtures thereof.
Abstract translation:其中M是阳离子; n是阳离子的电荷,y / n是阳离子的数量; x / y等于或大于5; Q是铝,镓铁,硼,铟或它们的混合物。
Abstract:
Disclosed is a method for converting an alkyl halide to an olefin. The method includes contacting a silicoaluminophosphate (SAPO) catalyst with a feed that includes an alkyl halide under reaction conditions sufficient to produce an olefin hydrocarbon product that includes C2 to C4 olefins. The SAPO catalyst has bimodal acidity designated as weak acid sites and strong acid sites. The weak acid concentration is less than 0.55 mmol/g-cat and the total acid concentration is less than 1.5 mmol/g-cat.
Abstract:
Disclosed is a method for converting an alkyl halide to an olefin. The method can include contacting a zeolite catalyst comprising HZSM-5 having a silica to alumina (SAR) ratio of at least 30 with a feed that includes an alkyl halide under reaction conditions sufficient to produce an olefin hydrocarbon product comprising C2 to C4 olefins, wherein the selectivity of the C2 to C4 olefins is at least 85% at 20% alkyl halide conversion.
Abstract:
Disclosed herein is a process for preparing a hydrocracking catalyst, comprising (i) combining a zeolite, a binder, water and a hydrogenating metal compound which is a complex or a salt of a hydrogenating metal to obtain a mixture, wherein the zeolite has not been treated with a phosphorus-containing compound and the zeolite has a silica to alumina molar ratio of 5-200; (ii) forming the mixture into a shaped body; and (iii) calcining the shaped body to form the catalyst.
Abstract:
Disclosed herein is a process for preparing a hydrocracking catalyst, comprising (i) combining a zeolite, a binder, water and a hydrogenating metal compound which is a complex or a salt of a hydrogenating metal to obtain a mixture, wherein the zeolite has not been treated with a phosphorus-containing compound and the zeolite has a silica to alumina molar ratio of 5-200; (ii) forming the mixture into a shaped body; and (iii) calcining the shaped body to form the catalyst.
Abstract:
A method for purifying 1-hexene is disclosed. The method can include contacting a first stream containing 1-hexene and 2-ethyl-1-butene with an isomerization catalyst containing an comprising an alumina, silica-alumina, a zeolite, or an ion exchange resin, or any combinations thereof, under conditions sufficient to selectively isomerize at least a portion of 2-ethyl-1-butene into 3-methyl-2-pentene and form a second stream containing 1-hexene and 3-methyl-2-pentene, and separating the second stream into a third stream containing 1-hexene and a fourth stream containing 3-methyl-2-pentene.
Abstract:
A method for preparing a hydrocracking catalyst comprising: (i) providing a shaped body comprising a zeolite and a binder, wherein the shaped body has been obtained by shaping, calcination and cooling, wherein the zeolite is ZSM-5 having a silica (SiO2) to alumina (Al2O3) molar ratio of 25-75; (ii) optionally drying the shaped body at a temperature of 100-300° C. for a period of at least 1 hour; (iii) depositing a hydrogenation metal on the shaped body by an impregnation for a period of at most 2 hours such that the amount of the hydrogenation metal is 0.010-0.30 wt % with respect to the total catalyst; (iv) optionally rinsing the metal deposited shaped body with water; and (v) heat-treating the metal deposited shaped body in air at a temperature of 250-300° C. for a period of 1-5 hours; wherein the catalyst comprises a total of less than 0.05 wt % sodium and cesium.